scholarly journals Interfaces in heterogeneous catalytic reactions: Ambient pressure XPS as a tool to unravel surface chemistry

Author(s):  
Robert M. Palomino ◽  
Rebecca Hamlyn ◽  
Zongyuan Liu ◽  
David C. Grinter ◽  
Iradwikanari Waluyo ◽  
...  
2019 ◽  
Vol 9 (15) ◽  
pp. 3851-3867 ◽  
Author(s):  
Liping Zhong ◽  
Dingkai Chen ◽  
Spyridon Zafeiratos

The rich surface chemistry of Fe, Co, Ni and Cu during heterogeneous catalytic reactions from the perspective of NAP-XPS studies.


2018 ◽  
Vol 455 ◽  
pp. 1019-1028 ◽  
Author(s):  
Dorota Flak ◽  
Qianli Chen ◽  
Bongjin Simon Mun ◽  
Zhi Liu ◽  
Mieczysław Rękas ◽  
...  

2016 ◽  
Vol 59 (5-7) ◽  
pp. 574-582 ◽  
Author(s):  
Wesley T. Hong ◽  
Kelsey A. Stoerzinger ◽  
Ethan J. Crumlin ◽  
Eva Mutoro ◽  
Hyoungjeen Jeen ◽  
...  

Materials ◽  
2019 ◽  
Vol 12 (22) ◽  
pp. 3674 ◽  
Author(s):  
Zhang ◽  
Sun ◽  
Shen ◽  
Hu ◽  
Hu ◽  
...  

: Surface science is an interdisciplinary field involving various subjects such as physics, chemistry, materials, biology and so on, and it plays an increasingly momentous role in both fundamental research and industrial applications. Despite the encouraging progress in characterizing surface/interface nanostructures with atomic and orbital precision under ultra-high-vacuum (UHV) conditions, investigating in situ reactions/processes occurring at the surface/interface under operando conditions becomes a crucial challenge in the field of surface catalysis and surface electrochemistry. Promoted by such pressing demands, high-pressure scanning tunneling microscopy (HP-STM) and ambient pressure X-ray photoelectron spectroscopy (AP-XPS), for example, have been designed to conduct measurements under operando conditions on the basis of conventional scanning tunneling microscopy (STM) and photoemission spectroscopy, which are proving to become powerful techniques to study various heterogeneous catalytic reactions on the surface. This report reviews the development of HP-STM and AP-XPS facilities and the application of HP-STM and AP-XPS on fine investigations of heterogeneous catalytic reactions via evolutions of both surface morphology and electronic structures, including dehydrogenation, CO oxidation on metal-based substrates, and so on. In the end, a perspective is also given regarding the combination of in situ X-ray photoelectron spectroscopy (XPS) and STM towards the identification of the structure–performance relationship.


2016 ◽  
Vol 18 (25) ◽  
pp. 16621-16628 ◽  
Author(s):  
Zongyuan Liu ◽  
Tomáš Duchoň ◽  
Huanru Wang ◽  
David C. Grinter ◽  
Iradwikanari Waluyo ◽  
...  

In situ investigation of the surface chemistry of ethanol steam reforming & metal-oxide interactions over Ni–CeOx(111).


Author(s):  
I. G. Wenten ◽  
K. Khoiruddin ◽  
R. R. Mukti ◽  
W. Rahmah ◽  
Z. Wang ◽  
...  

Coupling chemical reaction with membrane separation or known as membrane reactor (MR) has been demonstrated by numerous studies and showed that this strategy has successfully addressed the goal of process intensification.


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