Yolk−shell Prussian blue analogues hierarchical microboxes: Controllably exposing active sites toward enhanced cathode performance for lithium ion batteries

2019 ◽  
Vol 319 ◽  
pp. 237-244 ◽  
Author(s):  
Wenjin Ye ◽  
Lin Yu ◽  
Ming Sun ◽  
Gao Cheng ◽  
Shuchai Fu ◽  
...  
Keyword(s):  
Prussian Blue ◽  
Lithium Ion Batteries ◽  
Active Sites ◽  
Lithium Ion ◽  
Prussian Blue Analogues

Prussian blue analogues Mn[Fe(CN)6]0.6667·nH2O cubes as an anode material for lithium-ion batteries

2015 ◽  
Vol 44 (38) ◽  
pp. 16746-16751 ◽  
Author(s):  
Peixun Xiong ◽  
Guojin Zeng ◽  
Lingxing Zeng ◽  
Mingdeng Wei
Keyword(s):  
Prussian Blue ◽  
Lithium Ion Batteries ◽  
Anode Material ◽  
Coulombic Efficiency ◽  
Rate Capability ◽  
Lithium Ion ◽  
Prussian Blue Analogues ◽  
Li Ion ◽  
Ion Intercalation ◽  
Good Rate Capability

Prussian blue analogues, Mn[Fe(CN)6]0.6667·nH2O cubes, were synthesized and exhibited a large capacity, good rate capability and cycling stability with a high Coulombic efficiency for Li-ion intercalation.

K1−Mn1+/2[Fe(CN)6]·yH2O Prussian blue analogues as an anode material for lithium-ion batteries

2018 ◽  
Vol 444 ◽  
pp. 650-660 ◽  
Author(s):  
Feng-Chen Zhou ◽  
Yan-Hui Sun ◽  
Jie-Qiong Li ◽  
Jun-Min Nan
Keyword(s):  
Prussian Blue ◽  
Lithium Ion Batteries ◽  
Anode Material ◽  
Lithium Ion ◽  
Prussian Blue Analogues

Prussian blue analogues: a new class of anode materials for lithium ion batteries

2014 ◽  
Vol 2 (16) ◽  
pp. 5852-5857 ◽  
Author(s):  
Ping Nie ◽  
Laifa Shen ◽  
Haifeng Luo ◽  
Bing Ding ◽  
Guiyin Xu ◽  
...  
Keyword(s):  
Prussian Blue ◽  
Lithium Ion Batteries ◽  
Anode Materials ◽  
Organic Liquid ◽  
Lithium Ion ◽  
Chemical Formula ◽  
Prussian Blue Analogues ◽  
New Class

Herein, we demonstrate that nanoparticles of cobalt hexacyanocobaltate and manganese hexacyanocobaltate, typical Prussian blue analogues with the chemical formula M3II[CoIII(CN)6]2·nH2O (M = Co, Mn), can be operated as novel battery anodes in an organic liquid-carbonate electrolyte.

scholarly journals Simple One-Pot Synthesis of Hexagonal ZnO Nanoplates as Anode Material for Lithium-Ion Batteries

2016 ◽  
Vol 2016 ◽  
pp. 1-6 ◽  
Author(s):  
Haipeng Li ◽  
Yaqiong Wei ◽  
Yan Zhao ◽  
Yongguang Zhang ◽  
Fuxing Yin ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Active Sites ◽  
Hydrothermal Reaction ◽  
Strain Relaxation ◽  
Lithium Ion ◽  
Lithium Ions ◽  
One Pot ◽  
Large Contact Area ◽  
Physical And Chemical ◽  
Microstructure Of The Material

Hexagonal ZnO nanoplates were synthesizedviasimple one-pot hydrothermal reaction of Zn(CH3COO)2and CO(NH2)2. XRD, SEM, and HRTEM were used to investigate the composition and microstructure of the material. Together with the facile strain relaxation during structure and volume change upon cycling, this plate-like structure of ZnO is favorable for physical and chemical interactions with lithium ions because of its large contact area with the electrolyte, providing more active sites and short diffusion distances. The resulting hexagonal ZnO nanoplates electrode exhibited good cyclability and delivered a reversible discharge capacity of 368 mAh g−1after 100 cycles at 0.1 C.

scholarly journals Nitrogen-Doped Porous Co3O4/Graphene Nanocomposite for Advanced Lithium-Ion Batteries

Nanomaterials ◽  
2019 ◽  
Vol 9 (9) ◽  
pp. 1253 ◽  
Author(s):  
Huihui Zeng ◽  
Baolin Xing ◽  
Lunjian Chen ◽  
Guiyun Yi ◽  
Guangxu Huang ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Anode Material ◽  
Self Assembly ◽  
Active Sites ◽  
Large Scale ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Co3o4 Nanoparticles ◽  
Nitrogen Doped ◽  
Novel Approach

A novel approach is developed to synthesize a nitrogen-doped porous Co3O4/anthracite-derived graphene (Co3O4/AG) nanocomposite through a combined self-assembly and heat treatment process using resource-rich anthracite as a carbonaceous precursor. The nanocomposite contains uniformly distributed Co3O4 nanoparticles with a size smaller than 8 nm on the surface of porous graphene, and exhibits a specific surface area (120 m2·g−1), well-developed mesopores distributed at 3~10 nm, and a high level of nitrogen doping (5.4 at. %). These unique microstructure features of the nanocomposite can offer extra active sites and efficient pathways during the electrochemical reaction, which are conducive to improvement of the electrochemical performance for the anode material. The Co3O4/AG electrode possesses a high reversible capacity of 845 mAh·g−1 and an excellent rate capacity of 587 mAh·g−1. Furthermore, a good cyclic stability of 510 mAh·g−1 after 100 cycles at 500 mA·g−1 is maintained. Therefore, this work could provide an economical and effective route for the large-scale application of a Co3O4/AG nanocomposite as an excellent anode material in lithium-ion batteries.

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