Caesium −Methyl Ammonium Mixed-Cation Lead Iodide Perovskite Crystals: Analysis and Application for Perovskite Solar Cells

2017 ◽  
Vol 257 ◽  
pp. 267-280 ◽  
Author(s):  
Govindhasamy Murugadoss ◽  
Rangasamy Thangamuthu ◽  
Saranyan Vijayaraghavan ◽  
Hiroyuki Kanda ◽  
Seigo Ito
Keyword(s):  
Solar Cells ◽  
Perovskite Solar Cells ◽  
Lead Iodide ◽  
Mixed Cation

scholarly journals Influence of the mixed organic cation ratio in lead iodide based perovskite on the performance of solar cells

2016 ◽  
Vol 18 (39) ◽  
pp. 27148-27157 ◽  
Author(s):  
Manuel Salado ◽  
Laura Calio ◽  
Rüdiger Berger ◽  
Samrana Kazim ◽  
Shahzada Ahmad
Keyword(s):  
Solar Cells ◽  
Organic Cation ◽  
Perovskite Solar Cells ◽  
Lead Iodide ◽  
Mixed Cation ◽  
Cation Ratio

Perovskite solar cells were fabricated using the mixed organic cation of formamidinium and methylammonium. The mixed cation having the composition MA0.6FA0.4PbI3 shows almost negligible I–V hysteresis and better photostability than pure MAPbI3 and FAPbI3.

A mixed-cation lead iodide MA1−EA PbI3 absorber for perovskite solar cells

2018 ◽  
Vol 27 (1) ◽  
pp. 215-218 ◽  
Author(s):  
Yong Wang ◽  
Taiyang Zhang ◽  
Ge Li ◽  
Feng Xu ◽  
Tian Wang ◽  
...  
Keyword(s):  
Solar Cells ◽  
Perovskite Solar Cells ◽  
Lead Iodide ◽  
Mixed Cation

Differential Space‐Limited Crystallization of Mixed‐Cation Lead Iodide Single‐Crystal Micro‐Plates Enhances the Performance of Perovskite Solar Cells

Solar RRL ◽  
2019 ◽  
Vol 3 (10) ◽  
pp. 1900130 ◽  
Author(s):  
Hsin-Hung Sung ◽  
Chien-Chen Kuo ◽  
Hung-Sheng Chiang ◽  
Hong-Lin Yue ◽  
Fang-Chung Chen
Keyword(s):  
Solar Cells ◽  
Single Crystal ◽  
Perovskite Solar Cells ◽  
Lead Iodide ◽  
Mixed Cation ◽  
Micro Plates ◽  
Iodide Single Crystal

Ferroelectric domains in methylammonium lead iodide perovskite solar cells

2018 ◽  
Author(s):  
Holger Röhm ◽  
Tobias Leonhard ◽  
Michael J. Hoffmann ◽  
Alexander Colsmann
Keyword(s):  
Solar Cells ◽  
Perovskite Solar Cells ◽  
Lead Iodide ◽  
Ferroelectric Domains ◽  
Methylammonium Lead Iodide

Fundamental Efficiency Limit of Lead Iodide Perovskite Solar Cells

2018 ◽  
Author(s):  
Luis Pazos-Outon ◽  
T. Patrick Xiao ◽  
Eli Yablonovitch
Keyword(s):  
Solar Cells ◽  
Perovskite Solar Cells ◽  
Lead Iodide

scholarly journals Effects of 5-Ammonium Valeric Acid Iodide as Additive on Methyl Ammonium Lead Iodide Perovskite Solar Cells

Nanomaterials ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 2512
Author(s):  
Daming Zheng ◽  
Changheng Tong ◽  
Tao Zhu ◽  
Yaoguang Rong ◽  
Thierry Pauporté
Keyword(s):  
Solar Cells ◽  
Perovskite Solar Cells ◽  
Single Crystal Silicon ◽  
Mesoporous Structure ◽  
Valeric Acid ◽  
Electrical Impedance Spectroscopy ◽  
Lead Iodide ◽  
Crystal Silicon ◽  
Time Resolved ◽  
Hole Transporting

During the past decade, the power conversion efficiency (PCE) of perovskite solar cells (PSCs) has risen rapidly, and it now approaches the record for single crystal silicon solar cells. However, these devices still suffer from a problem of stability. To improve PSC stability, two approaches have been notably developed: the use of additives and/or post-treatments that can strengthen perovskite structures and the use of a nontypical architecture where three mesoporous layers, including a porous carbon backcontact without hole transporting layer, are employed. This paper focuses on 5-ammonium valeric acid iodide (5-AVAI or AVA) as an additive in methylammonium lead iodide (MAPI). By combining scanning electron microscopy (SEM), X-ray diffraction (XRD), time-resolved photoluminescence (TRPL), current–voltage measurements, ideality factor determination, and in-depth electrical impedance spectroscopy (EIS) investigations on various layers stacks structures, we discriminated the effects of a mesoscopic scaffold and an AVA additive. The AVA additive was found to decrease the bulk defects in perovskite (PVK) and boost the PVK resistance to moisture. The triple mesoporous structure was detrimental for the defects, but it improved the stability against humidity. On standard architecture, the PCE is 16.9% with the AVA additive instead of 18.1% for the control. A high stability of TiO2/ZrO2/carbon/perovskite cells was found due to both AVA and the protection by the all-inorganic scaffold. These cells achieved a PCE of 14.4% in the present work.

Construction and mechanistic understanding of high-performance all-air-processed perovskite solar cells via mixed-cation engineering

2021 ◽  
Author(s):  
Wenyuan Zhang ◽  
Lang He ◽  
Yuanchao Li ◽  
Dongyan Tang ◽  
Xin Li ◽  
...  
Keyword(s):  
Solar Cells ◽  
High Performance ◽  
Low Cost ◽  
Perovskite Solar Cells ◽  
Manufacturing Processes ◽  
Mixed Cation ◽  
Mechanistic Understanding

All-air-processed perovskite solar cells (PSCs) have attracted increasing attention due to low cost and simplified manufacturing processes. At present, to fabricate efficient and stable PSCs in the air is expected....

scholarly journals Fundamental Efficiency Limit of Lead Iodide Perovskite Solar Cells

2018 ◽  
Vol 9 (7) ◽  
pp. 1703-1711 ◽  
Author(s):  
Luis M. Pazos-Outón ◽  
T. Patrick Xiao ◽  
Eli Yablonovitch
Keyword(s):  
Solar Cells ◽  
Perovskite Solar Cells ◽  
Lead Iodide

Design of surface termination for high-performance perovskite solar cells

2021 ◽  
Author(s):  
Yan Yang ◽  
Wangen Zhao ◽  
Tengteng Yang ◽  
Jiali Liu ◽  
Jingru Zhang ◽  
...  
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
High Performance ◽  
Perovskite Solar Cells ◽  
Lead Iodide ◽  
Surface Termination ◽  
Guanidinium Thiocyanate

Guanidinium thiocyanate was selected to modify the surface terminations of methylamine lead iodide (MAPbI3) perovskite films and a 21.26% PCE was acquired for a solar cell based on the MAPbI3 system, and the voltage deficit is reduced to 0.426 V.

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