Spatially Resolved Analysis of Screen Printed Photoanodes of Dye-Sensitized Solar Cells by Scanning Electrochemical Microscopy

2016 ◽  
Vol 222 ◽  
pp. 735-746 ◽  
Author(s):  
Ina Schmidt ◽  
Inka Plettenberg ◽  
Daniel Kimmich ◽  
Hanna Ellis ◽  
Julia Witt ◽  
...  
2014 ◽  
Vol 118 (30) ◽  
pp. 16912-16918 ◽  
Author(s):  
Colin J. Martin ◽  
Biljana Bozic-Weber ◽  
Edwin C. Constable ◽  
Thilo Glatzel ◽  
Catherine E. Housecroft ◽  
...  

2014 ◽  
Vol 119 ◽  
pp. 86-91 ◽  
Author(s):  
Colin J. Martin ◽  
Biljana Bozic-Weber ◽  
Edwin C. Constable ◽  
Thilo Glatzel ◽  
Catherine E. Housecroft ◽  
...  

2021 ◽  
pp. 51929
Author(s):  
Pavol Gemeiner ◽  
Michaela Pavličková ◽  
Michal Hatala ◽  
Matej Hvojnik ◽  
Tomáš Homola ◽  
...  

Electrochem ◽  
2020 ◽  
Vol 1 (3) ◽  
pp. 329-343
Author(s):  
Sabina Scarabino ◽  
Kazuteru Nonomura ◽  
Nick Vlachopoulos ◽  
Anders Hagfeldt ◽  
Gunther Wittstock

The dye regeneration in dye-sensitized solar cells (DSSCs) is improved by optimizing the charge separation at the level of the sensitized semiconductor treatment of the mesoporous electrode by TiCl4 that passivates the surface for back electron transfer reactions. The dye-regeneration kinetics is analyzed for DN216- and D358-sensitized porous TiO2 electrodes with and without a TiCl4 treatment by means of scanning electrochemical microscopy (SECM). Different mass transport limitation of the [Co(bpy)3]3+ mediator through the porous electrode is found for the comparison of the structurally similar dyes but cannot be detected for the thin layer introduced by the TiCl4 treatment. Phototransient measurements are conducted directly in the SECM cell without any intermediated sample manipulation. The results from those measurements corroborate the findings from steady state SECM measurements.


2013 ◽  
Vol 19 (5) ◽  
pp. 1464-1469 ◽  
Author(s):  
Mateja Hočevar ◽  
Urša Opara Krašovec ◽  
Matevž Bokalič ◽  
Marko Topič ◽  
Welmoed Veurman ◽  
...  

2019 ◽  
Vol 256 ◽  
pp. 116148 ◽  
Author(s):  
Pavol Gemeiner ◽  
Jaroslav Kuliček ◽  
Tomáš Syrový ◽  
Aleš Ház ◽  
Viera Khunová ◽  
...  

2014 ◽  
Vol 922 ◽  
pp. 356-359
Author(s):  
Ji Sun Kim ◽  
Seong Cheol Shim ◽  
Tae Hwan Hwang ◽  
Won Youl Choi

Hybrid structure of TiO2nanofiber and nanoparticle as a photoelectrode was very attractive in dye-sensitized solar cells (DSCs) because TiO2nanoparticle provided a high specific surface area to adsorb the N719 dye and TiO2nanofiber was a direct path to transfer photoelectron from dye to electrode. TiO2nanofiber film was prepared with titanium-tetraisopropoxide (TTIP) and polyvinylpyrrolidone (PVP) based precursor by electro-spinning process. To fabricate the hybrid structure, TiO2nanoparticular paste was screen printed on the TiO2nanofiber film. Electrospun TiO2nanofiber film and screen printed TiO2nanoparticular film were combined in layer by layer method. These films were observed as an anatase phase by X-ray diffraction pattern. Thickness and diameter of TiO2nanofibers were ~5μm and ~400nm, respectively. Thickness and particle size of TiO2particles were ~5μm and ~20nm, respectively. Compared to conventional DSCs, higher short circuit current densities (Jsc) of 6.47 mA/cm2and higher power conversion efficiency of 3.06 % were measured in DSCs having hybrid structure of TiO2nanofiber and nanoparticle. Electrochemical impedance spectroscopy (EIS) was observed to understand an electron transfer and life time.


Solar Energy ◽  
2019 ◽  
Vol 190 ◽  
pp. 28-33 ◽  
Author(s):  
D. Kishore Kumar ◽  
Srinivasa R. Popuri ◽  
Sanjay Kumar Swami ◽  
Obinna R. Onuoha ◽  
Jan-Willem G. Bos ◽  
...  

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