Enhanced microbial electrosynthesis with three-dimensional graphene functionalized cathodes fabricated via solvothermal synthesis

2016 ◽  
Vol 217 ◽  
pp. 117-122 ◽  
Author(s):  
Nabin Aryal ◽  
Arnab Halder ◽  
Pier-Luc Tremblay ◽  
Qijin Chi ◽  
Tian Zhang
Keyword(s):  
Solvothermal Synthesis ◽  
Three Dimensional ◽  
Microbial Electrosynthesis

scholarly journals V2O2F4(H2O)2·H2O: a new V4+layer structure related to VOF3

2016 ◽  
Vol 72 (1) ◽  
pp. 80-83 ◽  
Author(s):  
Cameron Black ◽  
Philip Lightfoot
Keyword(s):  
Ionic Liquids ◽  
Title Compound ◽  
Solvothermal Synthesis ◽  
Layer Structure ◽  
Three Dimensional ◽  
Water Molecules ◽  
Frustrated Magnets ◽  
Two Dimensional ◽  
Triangular Lattices ◽  
Solvothermal Conditions

VIVoxyfluorides are of interest as frustrated magnets. The successful synthesis of two-dimensionally connected vanadium(IV) oxyfluoride structures generally requires the use of ionic liquids as solvents. During solvothermal synthesis experiments aimed at producing two- and three-dimensional vanadium(IV) selenites with triangular lattices, the title compound, diaquatetra-μ-fluorido-dioxidodivanadium(IV) monohydrate, V2O2F4(H2O)2·H2O, was discovered and features a new infinite V4+-containing two-dimensional layer comprised of fluorine-bridged corner- and edge-sharing VOF4(H2O) octahedral building units. The synthesis was carried out under solvothermal conditions. The V4+centre exhibits a typical off-centring, with a short V=O bond and an elongatedtrans-V—F bond. Hydrogen-bonded water molecules occur between the layers. The structure is related to previously reported vanadium oxyfluoride structures, in particular, the same layer topology is seen in VOF3.

Solvothermal synthesis of cobalt nickel layered double hydroxides with a three-dimensional nano-petal structure for high-performance supercapacitors

2020 ◽  
Vol 4 (1) ◽  
pp. 337-346 ◽  
Author(s):  
Hailiang Chu ◽  
Ying Zhu ◽  
Tingting Fang ◽  
Junqiang Hua ◽  
Shujun Qiu ◽  
...  
Keyword(s):  
Layered Double Hydroxides ◽  
Solvothermal Synthesis ◽  
High Performance ◽  
Three Dimensional ◽  
Rate Performance ◽  
Supercapacitor Electrode ◽  
Long Term Stability ◽  
Cobalt Nickel ◽  
Double Hydroxides

CoNi LDH-6 with a nano-petal structure was prepared, which exhibited excellent rate performance and long-term stability as a supercapacitor electrode.

scholarly journals A novel carbon nanotube modified scaffold as an efficient biocathode material for improved microbial electrosynthesis

2014 ◽  
Vol 2 (32) ◽  
pp. 13093-13102 ◽  
Author(s):  
Ludovic Jourdin ◽  
Stefano Freguia ◽  
Bogdan C. Donose ◽  
Jun Chen ◽  
Gordon G. Wallace ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Carbon Nanotube ◽  
Three Dimensional ◽  
Microbial Electrosynthesis

Enhanced performance for the bioelectrosynthesis of acetate from carbon dioxide is achieved with a new three-dimensional CNT-modified scaffold electrode.

Expanding uranyl dicyanoaurate coordination polymers into the second and third dimensions

2020 ◽  
Vol 98 (7) ◽  
pp. 365-372
Author(s):  
Matthew L. Brown ◽  
Daniel B. Leznoff
Keyword(s):  
Coordination Polymer ◽  
Single Crystal ◽  
Coordination Polymers ◽  
Solvothermal Synthesis ◽  
Linear Chain ◽  
Three Dimensional ◽  
Synthesis And Characterization ◽  
Crystal Transformation ◽  
System A

The solvothermal synthesis and characterization of a three-dimensional, interpenetrated uranyl dicyanoaurate coordination polymer, K2(UO2)2(UO2)2(Au(CN)2)2(O)2(NO3)4, from UO2(NO3)2·6H2O and KAu(CN)2 is described. The structure contains a three-dimensional (3D) lattice of planar tetranuclear uranyl–oxo–nitrate clusters connected by dicyanoaurate linkers, with the rotation of the clusters providing the increased dimensionality. The material undergoes a reversible single-crystal to single-crystal transformation on exposure to water vapour, which is taken up in the channels of the 3D system. A second uranyl dicyanoaurate coordination polymer of the form [UO2(DMSO)3(H2O)(Au(CN)2)][Au(CN)2] was structurally characterized as a linear chain of dicyanoaurate units connected by gold–gold bonds with pendant uranyl–water–DMSO adducts that are hydrogen bonded into a two-dimensional sheet. Both materials exhibit emission arising from both the uranyl moiety and the gold(I) centre and represent the first multidimensional uranyl–dicyanoaurate coordination polymers.

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