Hierarchically porous carbons derived from nonporous metal-organic frameworks: Synthesis and influence of struts

2015 ◽  
Vol 180 ◽  
pp. 651-657 ◽  
Author(s):  
Ying Yang ◽  
Shijie Hao ◽  
Hairui Zhao ◽  
Yue Wang ◽  
Xin Zhang
Keyword(s):  
Metal Organic Frameworks ◽  
Porous Carbons ◽  
Hierarchically Porous ◽  
Metal Organic

scholarly journals Porphyrin MOF-Derived Porous Carbons: Preparation and Applications

2021 ◽  
Vol 7 (2) ◽  
pp. 47
Author(s):  
Flávio Figueira ◽  
Filipe A. Almeida Paz
Keyword(s):  
Chemical Composition ◽  
Carbon Material ◽  
Metal Organic Frameworks ◽  
Electrochemical Reactions ◽  
Porous Carbon Material ◽  
Important Class ◽  
Porous Carbons ◽  
Preparation Methods ◽  
Crystalline Materials ◽  
Metal Organic

Metal–organic frameworks (MOFs) are crystalline materials with permanent porosity, composed of metal nodes and organic linkers whose well-ordered arrangement enables them to act as ideal templates to produce materials with a uniform distribution of heteroatom and metal elements. The hybrid nature of MOFs, well-defined pore structure, large surface area and tunable chemical composition of their precursors, led to the preparation of various MOF-derived porous carbons with controlled structures and compositions bearing some of the unique structural properties of the parent networks. In this regard, an important class of MOFs constructed with porphyrin ligands were described, playing significant roles in the metal distribution within the porous carbon material. The most striking early achievements using porphyrin-based MOF porous carbons are here summarized, including preparation methods and their transformation into materials for electrochemical reactions.

Bimetallic MOF-templated synthesis of alloy nanoparticle-embedded porous carbons for oxygen evolution and reduction reactions

2019 ◽  
Vol 48 (37) ◽  
pp. 13953-13959 ◽  
Author(s):  
Zakary Lionet ◽  
Shun Nishijima ◽  
Tae-Ho Kim ◽  
Yu Horiuchi ◽  
Soo Wohn Lee ◽  
...  
Keyword(s):  
Metal Nanoparticles ◽  
Oxygen Evolution ◽  
Porous Carbon ◽  
Metal Organic Frameworks ◽  
Carbon Matrix ◽  
Porous Carbons ◽  
Reduction Reactions ◽  
Templated Synthesis ◽  
Metal Organic

Pyrolysis of metal–organic frameworks (MOFs) to produce metal nanoparticles embedded inside a porous carbon matrix (M@PC) has drawn a lot of attention in recent years.

Polysaccharide templated biomimetic growth of hierarchically porous metal-organic frameworks

2020 ◽  
Vol 306 ◽  
pp. 110429 ◽  
Author(s):  
Nisrine Hammi ◽  
Samir El Hankari ◽  
Nadia Katir ◽  
Nathalie Marcotte ◽  
Khalid Draoui ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Porous Metal ◽  
Hierarchically Porous ◽  
Metal Organic

Hierarchically porous metal–organic frameworks: rapid synthesis and enhanced gas storage

Soft Matter ◽  
2018 ◽  
Vol 14 (47) ◽  
pp. 9589-9598 ◽  
Author(s):  
Chongxiong Duan ◽  
Hang Zhang ◽  
Feier Li ◽  
Jing Xiao ◽  
Shaojuan Luo ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Porous Metal ◽  
Gas Storage ◽  
Organic Amine ◽  
Rapid Synthesis ◽  
Hierarchically Porous ◽  
Adsorption Capacities ◽  
Metal Organic ◽  
Diffusion Rates ◽  
Enhanced Adsorption

A simple, rapid and versatile method was developed to increase the pore sizes and pore volumes of microporous MOFs (HKUST-1, ZIF-8, ZIF-67, and ZIF-90) by employing organic amine as the template. The resultant hierarchically porous HKUST-1 exhibited significantly enhanced adsorption capacities and faster diffusion rates for CH4 and CO2 gas storage.

Ultrafast room-temperature synthesis of hierarchically porous metal–organic frameworks with high space–time yields

CrystEngComm ◽  
2020 ◽  
Vol 22 (15) ◽  
pp. 2675-2680 ◽  
Author(s):  
Chongxiong Duan ◽  
Yi Yu ◽  
Feier Li ◽  
Ying Wu ◽  
Hongxia Xi
Keyword(s):  
Room Temperature ◽  
Metal Organic Frameworks ◽  
Porous Metal ◽  
Space Time ◽  
Ambient Conditions ◽  
Temperature Synthesis ◽  
Hierarchically Porous ◽  
Room Temperature Synthesis ◽  
Metal Organic ◽  
High Space

We developed a facile and general approach to rapidly synthesize four hierarchically porous MOFs (HKUST-1, ZIF-8, ZIF-61, and ZIF-90) under ambient conditions.

scholarly journals Calix[4]arene-based metal–organic frameworks: towards hierarchically porous materials

2012 ◽  
Vol 48 (40) ◽  
pp. 4824 ◽  
Author(s):  
Sean P. Bew ◽  
Andrew D. Burrows ◽  
Tina Düren ◽  
Mary F. Mahon ◽  
Peyman Z. Moghadam ◽  
...  
Keyword(s):  
Porous Materials ◽  
Metal Organic Frameworks ◽  
Hierarchically Porous ◽  
Hierarchically Porous Materials ◽  
Metal Organic
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