Poly(3-methylthiophene)/Vertically Aligned Multi-walled Carbon Nanotubes: Electrochemical Synthesis, Characterizations and Electrochemical Storage Properties in Ionic Liquids

2014 ◽  
Vol 130 ◽  
pp. 754-765 ◽  
Author(s):  
Sébastien Lagoutte ◽  
Pierre-Henri Aubert ◽  
Mathieu Pinault ◽  
François Tran-Van ◽  
Martine Mayne-L’Hermite ◽  
...  
Polymers ◽  
2018 ◽  
Vol 10 (10) ◽  
pp. 1099 ◽  
Author(s):  
Qiuping Li

Ionogels refer to an emerging composite material made from the confinement of ionic liquids within some specific cross-linked network matrices. They have potential applications in areas such as electrochemical and optical-electric materials. Incorporation of lanthanide (Eu3+, Tb3+) complexes covalently functionalized multi-walled carbon nanotubes (MWCNTs) in ionogels provide new ideas to design and synthesize novel luminescent hybrid materials that have excellent characteristics of luminescence and ionic conductivity. Here, the multifunctional ionogels were synthesized by confining an ionic liquid and the rare earth functionalized MWCNTs in the cross-linked polymethyl methacrylate (PMMA) networks, resulting in a novel optical/electric multifunctional hybrid material. The SEM images and digital photographs suggest that the lanthanide functionalized MWCNTs are evenly dispersed in the hybrid matrices, thus leading to a certain transparency bulky gel. The resulting ionogels exhibit certain viscosity and flexibility, and display an intense red/green emission under UV-light irradiation. The intrinsic conductibility of the embedded ionic liquids and carbon nanotubes in conjunction with the outstanding photoluminescent properties of lanthanide complexes makes the soft hybrid gels a material with great potential and valuable application in the field of optical-electric materials.


2012 ◽  
Vol 05 ◽  
pp. 704-711
Author(s):  
SIAVASH KHABAZIAN ◽  
SOHRAB SANJABI

Multi-walled carbon nanotubes films formed randomly aligned laterally by electrophoresis. Multi-walled carbon nanotubes with lengths of about 10 μ was shortened and functionalized by a mixture of sulfuric and nitric acid. The functional groups on carbon nanotubes were elaborated by FT-IR. Chemically shortened MWCNTs disperse in organic and aqueous solvent and deposited on electrode vertically-aligned by applying a constant DC electric field. The alignment of MWCNTs was observed by scanning electron microscopy. It also the effect of various substrates on alignment of multi-walled carbon nanotubes was investigated.


2019 ◽  
Vol 95 (1) ◽  
pp. 273-282
Author(s):  
Michail Olegovich Danilov ◽  
Igor A Rusetskii ◽  
Galina I Dovbeshko ◽  
Andrii Nikolenko ◽  
Sergii Fomanyuk ◽  
...  

2010 ◽  
Vol 654-656 ◽  
pp. 2843-2846
Author(s):  
Sima Aminorroaya ◽  
Hua Kun Liu

The hydrogen storage performance of ball-milled sample of cast Mg-6 wt% Ni alloy was investigated. Morphology and microstructure of the cast sample and achieved powders were evaluated by high-resolution scanning electron microscopy. The activation characteristics of ball-milled alloy are compared with those of the materials obtained by ball-milling of 5 wt% multi-walled carbon nanotubes (MWCNTs) for 2 hours. MWCNTs enhanced the absorption kinetics considerably. The hydrogen content of modified powder by MWCNTs reached to the maximum hydrogen capacity within two minutes of exposure to hydrogen at 370°C and 2MPa pressure. The evidence is provided that nucleation and growth of hydrides accelerate drastically by homogenously distribution of MWCNTs on the surface of ball-milled powders.


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