Electrocatalytic properties of Au electrodes decorated with Pt submonolayers by galvanic displacement of copper adatoms

2014 ◽  
Vol 130 ◽  
pp. 351-360 ◽  
Author(s):  
B.I. Podlovchenko ◽  
Yu. M. Maksimov ◽  
K.I. Maslakov
2012 ◽  
Vol 48 (4) ◽  
pp. 467-473 ◽  
Author(s):  
V. V. Kuznetsov ◽  
K. V. Kavyrshina ◽  
B. I. Podlovchenko

Nanomaterials ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 340
Author(s):  
Hehe Qian ◽  
Jianzhou Wu ◽  
Yongsheng Guo ◽  
Wenjun Fang

The functions of heterogeneous metallic nanocrystals (HMNCs) can be undoubtedly tuned by controlling their morphologies and compositions. As a less-studied kind of HMNCs, corner-satellite multi-metallic nanocrystals (CSMNCs) have great research value in structure-related electrocatalytic performance. In this work, PdAgPt corner-satellite nanocrystals with well-controlled morphologies and compositions have been developed by temperature regulation of a seed-mediated growth process. Through the seed-mediated growth, the morphology of PdAgPt products evolves from Pd@Ag cubes to PdAgPt corner-satellite cubes, and eventually to truncated hollow octahedra, as a result of the expansion of {111} facets in AgPt satellites. The growth of AgPt satellites exclusively on the corners of central cubes is realized with the joint help of Ag shell and moderate bromide, and hollow structures form only at higher reaction temperatures on account of galvanic displacement promoted by the Pd core. In view of the different performances of Pd and Pt toward formic acid oxidation (FAO), this structure-sensitive reaction is chosen to measure electrocatalytic properties of PdAgPt HMNCs. It is proven that PdAgPt CSMNCs display greatly improved activity toward FAO in direct oxidation pathway. In addition, with the help of AgPt heterogeneous shells, all PdAgPt HMNCs exhibit better durability than Pd cubes and commercial Pt.


2011 ◽  
Vol 651 (1) ◽  
pp. 30-37 ◽  
Author(s):  
B.I. Podlovchenko ◽  
U.E. Zhumaev ◽  
Yu. M. Maksimov

2021 ◽  
Vol 9 (5) ◽  
pp. 2754-2763
Author(s):  
Kenya Kani ◽  
Hyunsoo Lim ◽  
Andrew E. Whitten ◽  
Kathleen Wood ◽  
Anya J. E. Yago ◽  
...  

The mesoporous RhNi alloy films are synthesized by controlling the concentration of Rh precursor, applied potentials, and pH via the electrochemical co-deposition method with self-assembled polymeric micelles templates for enhancing electrocatalytic properties.


Nanoscale ◽  
2021 ◽  
Author(s):  
Lu Zhang ◽  
Zhuo Wang ◽  
Wenxiao Chen ◽  
Ruiwen Yuan ◽  
Ke Zhan ◽  
...  

Ti3C2Tx as a novel member of the two-dimensional material family holds great promise for electrochemical energy storage and catalysis, however, the electrochemical performance of Ti3C2Tx is largely limited by the...


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