Degradation behavior of a polymer electrolyte membrane fuel cell employing metallic bipolar plates under reverse current condition

2012 ◽  
Vol 78 ◽  
pp. 324-330 ◽  
Author(s):  
KwangSup Eom ◽  
EunAe Cho ◽  
Suk-Woo Nam ◽  
Tae-Hoon Lim ◽  
Jong Hyun Jang ◽  
...  
Energies ◽  
2020 ◽  
Vol 13 (1) ◽  
pp. 235
Author(s):  
Nadine Pilinski ◽  
Claudia Käding ◽  
Anastasia Dushina ◽  
Thorsten Hickmann ◽  
Alexander Dyck ◽  
...  

In this work, different methods and electrochemical set-ups were investigated in order to study the corrosion behaviour of bipolar plates (BPP) for high temperature (HT) polymer electrolyte membrane fuel cell application. Using confocal and scanning electron microscopy, it was shown that chemical and electrochemical aging significantly increases surface roughness as well as morphology changes, confirming material degradation. Identical electrochemical corrosion behaviour was observed for both set-ups with typical quinone/hydroquinone peaks in the potential range ~0.6–0.7 V versus reversible hydrogen electrode (RHE). The appearance of the peaks and an increase of double layer capacitance can be related to the oxidation of carbon surface and, consequently, material corrosion. Simultaneously, an optimised corrosion set-up was introduced and verified regarding suitability. Both investigated set-ups and methods are useful to analyse the oxidation behaviour and corrosion resistance.


Fuel Cells ◽  
2015 ◽  
Vol 16 (1) ◽  
pp. 39-45 ◽  
Author(s):  
P. Alnegren ◽  
J. G. Grolig ◽  
J. Ekberg ◽  
G. Göransson ◽  
J.-E. Svensson

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