scholarly journals New inorganic ionic liquids possessing low melting temperatures and wide electrochemical windows: Ternary mixtures of alkali bis(fluorosulfonyl)amides

2012 ◽  
Vol 66 ◽  
pp. 320-324 ◽  
Author(s):  
Keigo Kubota ◽  
Toshiyuki Nohira ◽  
Rika Hagiwara
2016 ◽  
Vol 221 ◽  
pp. 624-632 ◽  
Author(s):  
Mohsen Hosseinzadeh ◽  
Abdolhossein Hemmati-Sarapardeh ◽  
Forough Ameli ◽  
Fereshteh Naderi ◽  
Mohammadmahdi Dastgahi

2008 ◽  
Vol 80 (6) ◽  
pp. 1325-1335 ◽  
Author(s):  
Shahana A. Chowdhury ◽  
Janet L. Scott ◽  
Douglas R. MacFarlane

Ionic liquids (ILs) and water are both potentially green solvents that are useful in a variety of extraction processes. This report presents the ternary phase diagrams and tie-line data of trihexyl(tetradecyl)phosphonium dicyanamide [P6,6,6,14][DCA], phosphonium bis(2,4,4-trimethylpentyl)phosphinate [P6,6,6,14][((CH3)3C5H8)2PO2], and 1-ethyl-3-methylimidazolium ethylsulfate [emim][C2H5SO4] ILs in organic solvents (ethanol, acetonitrile, toluene) and water. [P6,6,6,14][DCA] and [P6,6,6,14][((CH3)3C5H8)2PO2] tended to yield emulsions when combined with water and ethanol, while [emim][C2H5SO4] combined with toluene and water provided two clear phases of reasonable viscosity. The compositions of the ternary mixtures were determined to obtain the tie-lines. A noticeable difference was observed for the tie-lines of the same IL (e.g., [P6,6,6,14][DCA]) with different organic solvents (ethanol and acetonitrile) and water mixtures. In all cases, the addition of ethanol eventually produced a single phase.


2020 ◽  
Vol 28 (1) ◽  
pp. 198-207 ◽  
Author(s):  
Mohammad Barzegar-Jalali ◽  
Abolghasem Jouyban ◽  
Fleming Martinez ◽  
Hemayat Shekaari ◽  
Seyyedeh Narjes Mirheydari

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