Kinetic study of CO oxidation on step decorated Pt(111) vicinal single crystal electrodes

2011 ◽  
Vol 56 (17) ◽  
pp. 5993-6000 ◽  
Author(s):  
Qing-Song Chen ◽  
Juan M. Feliu ◽  
Antonio Berna ◽  
Victor Climent ◽  
Shi-Gang Sun
Keyword(s):  
Single Crystal ◽  
Co Oxidation ◽  
Kinetic Study

scholarly journals Combining Planar Laser-Induced Fluorescence with Stagnation Point Flows for Small Single-Crystal Model Catalysts: CO Oxidation on a Pd(100)

Catalysts ◽  
2019 ◽  
Vol 9 (5) ◽  
pp. 484 ◽  
Author(s):  
Jianfeng Zhou ◽  
Sebastian Matera ◽  
Sebastian Pfaff ◽  
Sara Blomberg ◽  
Edvin Lundgren ◽  
...  
Keyword(s):  
Single Crystal ◽  
Co Oxidation ◽  
Flow Reactor ◽  
Laser Induced Fluorescence ◽  
Model Catalysts ◽  
Stagnation Flow ◽  
Reaction Conditions ◽  
Planar Laser Induced Fluorescence ◽  
Planar Laser ◽  
Crystal Model

A stagnation flow reactor has been designed and characterized for both experimental and modeling studies of single-crystal model catalysts in heterogeneous catalysis. Using CO oxidation over a Pd(100) single crystal as a showcase, we have employed planar laser-induced fluorescence (PLIF) to visualize the CO2 distribution over the catalyst under reaction conditions and subsequently used the 2D spatially resolved gas phase data to characterize the stagnation flow reactor. From a comparison of the experimental data and the stagnation flow model, it was found that characteristic stagnation flow can be achieved with the reactor. Furthermore, the combined stagnation flow/PLIF/modeling approach makes it possible to estimate the turnover frequency (TOF) of the catalytic surface from the measured CO2 concentration profiles above the surface and to predict the CO2, CO and O2 concentrations at the surface under reaction conditions.

Kinetic study of CO oxidation on copper modified Pt(111)

1998 ◽  
Vol 412-413 ◽  
pp. 447-457 ◽  
Author(s):  
Roderik E.R Colen ◽  
Markus Kolodziejczyk ◽  
Bernard Delmon ◽  
Jochen H Block
Keyword(s):  
Co Oxidation ◽  
Kinetic Study

scholarly journals Kinetic study of CO oxidation on clean and oxidized Pt

2012 ◽  
Vol 82 ◽  
pp. 550-557 ◽  
Author(s):  
Per Kristian Dahlstrøm ◽  
David A. Harrington ◽  
Frode Seland
Keyword(s):  
Co Oxidation ◽  
Kinetic Study
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