Electrochemical membrane reactor: Synthesis of quaternary ammonium hydroxide from its halide by in situ ion substitution

2009 ◽  
Vol 54 (5) ◽  
pp. 1630-1637 ◽  
Author(s):  
Mahendra Kumar ◽  
Bijay P. Tripathi ◽  
Arunima Saxena ◽  
Vinod K. Shahi
Keyword(s):  
Quaternary Ammonium ◽  
Membrane Reactor ◽  
Ammonium Hydroxide ◽  
Electrochemical Membrane Reactor ◽  
Ion Substitution

Electro-membrane reactor for separation and in situ ion substitution of glutamic acid from its sodium salt

2009 ◽  
Vol 54 (21) ◽  
pp. 4880-4887 ◽  
Author(s):  
Mahendra Kumar ◽  
Bijay P. Tripathi ◽  
Vinod K. Shahi
Keyword(s):  
Glutamic Acid ◽  
Sodium Salt ◽  
Membrane Reactor ◽  
Ion Substitution

Electrochemical membrane reactor: In situ separation and recovery of chromic acid and metal ions

2007 ◽  
Vol 52 (24) ◽  
pp. 6719-6727 ◽  
Author(s):  
Jeeshan Khan ◽  
Bijay P. Tripathi ◽  
Arunima Saxena ◽  
Vinod K. Shahi
Keyword(s):  
Metal Ions ◽  
Membrane Reactor ◽  
Chromic Acid ◽  
Electrochemical Membrane Reactor ◽  
In Situ Separation

scholarly journals Preparation and Characterization of P(AN-VAc-PMMT) Nanocomposites and Nanofibers

2014 ◽  
Vol 2014 ◽  
pp. 1-4
Author(s):  
Jun Liu ◽  
Yuguo Zhuo ◽  
Qingshan Li ◽  
Wei Hong ◽  
Guangzhong Xing
Keyword(s):  
Emulsion Polymerization ◽  
Quaternary Ammonium ◽  
Ammonium Ion ◽  
Nanofiber Morphology

P(AN-VAc-PMMT) nanocomposites were prepared usingin situemulsion polymerization and further confirmed by FTIR. A polymerizable quaternary ammonium ion monomer was used to modify montmorillonite. XRD testing showed that the quaternary ammonium ion was successfully intercalated into the montmorillonite chip layer. This is the first paper to discuss an investigation of P(AN-VAc-PMMT) nanofiber morphology using SEM. The fibers were prepared through electrospinning.

scholarly journals Understanding the Impact of Hydrogen Activation by SrCe0.8Zr0.2O3−δ Perovskite Membrane Material on Direct Non-Oxidative Methane Conversion

2022 ◽  
Vol 9 ◽  
Author(s):  
Sichao Cheng ◽  
Su Cheun Oh ◽  
Mann Sakbodin ◽  
Limei Qiu ◽  
Yuxia Diao ◽  
...  
Keyword(s):  
Methane Conversion ◽  
Membrane Reactor ◽  
Membrane Reactors ◽  
Fixed Bed Reactor ◽  
Perovskite Oxide ◽  
Oxide Material ◽  
Hydrogen Activation ◽  
Permeable Membrane ◽  
The Impact

Direct non-oxidative methane conversion (DNMC) converts methane (CH4) in one step to olefin and aromatic hydrocarbons and hydrogen (H2) co-product. Membrane reactors comprising methane activation catalysts and H2-permeable membranes can enhance methane conversion by in situ H2 removal via Le Chatelier's principle. Rigorous description of H2 kinetic effects on both membrane and catalyst materials in the membrane reactor, however, has been rarely studied. In this work, we report the impact of hydrogen activation by hydrogen-permeable SrCe0.8Zr0.2O3−δ (SCZO) perovskite oxide material on DNMC over an iron/silica catalyst. The SCZO oxide has mixed ionic and electronic conductivity and is capable of H2 activation into protons and electrons for H2 permeation. In the fixed-bed reactor packed with a mixture of SCZO oxide and iron/silica catalyst, stable and high methane conversion and low coke selectivity in DNMC was achieved by co-feeding of H2 in methane stream. The characterizations show that SCZO activates H2 to favor “soft coke” formation on the catalyst. The SCZO could absorb H2in situ to lower its local concentration to mitigate the reverse reaction of DNMC in the tested conditions. The co-existence of H2 co-feed, SCZO oxide, and DNMC catalyst in the present study mimics the conditions of DNMC in the H2-permeable SCZO membrane reactor. The findings in this work offer the mechanistic understanding of and guidance for the design of H2-permeable membrane reactors for DNMC and other alkane dehydrogenation reactions.

scholarly journals Review on antibiotics treatment by electrochemical membrane reactor

2021 ◽  
Vol 233 ◽  
pp. 01042
Author(s):  
Lei Chao ◽  
Feilong Chen ◽  
Yi Han ◽  
Yafeng Li
Keyword(s):  
Membrane Reactor ◽  
Membrane Filtration ◽  
Electrode Materials ◽  
Degradation Mechanism ◽  
Membrane Reactors ◽  
Membrane Electrode ◽  
Actual Application ◽  
Electrochemical Membrane Reactor ◽  
Antibiotic Degradation ◽  
The Impact

Lower consumption, higher efficiency, environmental protection, and reliability are the development trends for the treatment of antibiotic wastewater in future. To accomplish this, the electrochemical membrane reactor (ECMR) is developed by combining membrane filtration and electrochemical advanced oxidation technology. The device configuration and working mode of the electrochemical membrane reactor are introduced and compared. Besides, the principles of the removal of antibiotics by the reactor are explained with emphasis. Furthermore, the commonly used cathode and anode materials of the reactor in the current research are summarized, and the electrode materials are discussed. The effects of selection and modification on the elimination of antibiotics in the reactor and the impact are analysed. To address the limitations of electrochemical membrane reactors, this review proposes that more research should be done in the aspects of antibiotic degradation mechanism, reduction of membrane electrode R&D costs, and actual application of amplification devices.

scholarly journals The role of urea in the solubility of cellulose in aqueous quaternary ammonium hydroxide

RSC Advances ◽  
2020 ◽  
Vol 10 (10) ◽  
pp. 5919-5929
Author(s):  
Mikayla G. Walters ◽  
Albaraa D. Mando ◽  
W. Matthew Reichert ◽  
Christy W. West ◽  
Kevin N. West ◽  
...  
Keyword(s):  
Quaternary Ammonium ◽  
Ammonium Hydroxide ◽  
Tetrabutylammonium Hydroxide

We examine the role of water and urea in cellulose solubility in tetrabutylammonium hydroxide (TBAH).

Anion conductive poly(arylene ether sulfone)s containing tetra-quaternary ammonium hydroxide on fluorenyl group for alkaline fuel cell application

2012 ◽  
Vol 86 ◽  
pp. 360-365 ◽  
Author(s):  
Dong Wan Seo ◽  
Md. Awlad Hossain ◽  
Dong Hoon Lee ◽  
Young Don Lim ◽  
Soon Ho Lee ◽  
...  
Keyword(s):  
Fuel Cell ◽  
Quaternary Ammonium ◽  
Ammonium Hydroxide ◽  
Alkaline Fuel Cell ◽  
Arylene Ether ◽  
Fuel Cell Application

Reaction induced current generation by butane oxidation in high temperature electrochemical membrane reactor

2007 ◽  
Vol 131 (1-3) ◽  
pp. 15-22 ◽  
Author(s):  
L. Chalakov ◽  
L.K. Rihko-Struckmann ◽  
B. Munder ◽  
H. Rau ◽  
K. Sundmacher
Keyword(s):  
High Temperature ◽  
Membrane Reactor ◽  
Butane Oxidation ◽  
Induced Current ◽  
Current Generation ◽  
Electrochemical Membrane Reactor
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