Electrochemical degradation of 2,4-dichlorophenol on a palladium modified gas-diffusion electrode

2008 ◽  
Vol 53 (22) ◽  
pp. 6402-6409 ◽  
Author(s):  
Hui Wang ◽  
Jianlong Wang
Keyword(s):  
Gas Diffusion ◽  
Gas Diffusion Electrode ◽  
Electrochemical Degradation

Electrochemical Degradation of Tartrazine Dye in Aqueous Solution Using a Modified Gas Diffusion Electrode

2014 ◽  
Vol 161 (9) ◽  
pp. H438-H442 ◽  
Author(s):  
Willyam R. P. Barros ◽  
Suellen A. Alves ◽  
Poliana C. Franco ◽  
Juliana R. Steter ◽  
Robson S. Rocha ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Gas Diffusion ◽  
Gas Diffusion Electrode ◽  
Electrochemical Degradation

Electrochemical degradation of pentachlorophenol on a palladium modified gas-diffusion electrode

2009 ◽  
Vol 59 (9) ◽  
pp. 1759-1767 ◽  
Author(s):  
H. Wang ◽  
J. L. Wang
Keyword(s):  
Removal Efficiency ◽  
Photoelectron Spectroscopy ◽  
High Performance ◽  
Hydrogen Reduction ◽  
Amorphous Structure ◽  
Gas Diffusion ◽  
Gas Diffusion Electrode ◽  
Hydrogen Gas ◽  
Electrochemical Degradation ◽  
X Ray

Pd/C catalyst was prepared by a hydrogen reduction method and used for making a Pd/C gas-diffusion electrode. It was fully characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), and cyclic voltammetry (CV). In the catalyst, Pd particles with an average size of 4.0 nm were highly dispersed in the activated carbon with an amorphous structure; Pd content on the surface of the Pd/C catalyst reached 1.3 at% (atomic concentration). The Pd/C gas-diffusion electrode was then used as the cathode to investigate the electrochemical degradation of pentachlorophenol (PCP) in a diaphragm electrolysis device, feeding firstly with hydrogen gas then with air, compared with the carbon/polytetrafluoroethylene (C/PTFE) gas-diffusion cathode. The Pd/C gas-diffusion cathode can not only reductively dechlorinate PCP by feeding hydrogen gas, but also accelerate the two-electron reduction of O2 to hydrogen peroxide (H2O2) by feeding air. Therefore, both the removal efficiency and the dechlorination degree of PCP exceeded 80% after 100 min, and the average removal efficiency of PCP in terms of total organic carbon (TOC) was more than 75% after 200 min by using Pd/C gas-diffusion cathode, which was better than that of the C/PTFE gas-diffusion cathode. Phenol was identified as the dechorination product using high-performance liquid chromatography (HPLC).

scholarly journals Investigation of Gas Diffusion Electrode Systems for the Electrochemical CO2 Conversion

Catalysts ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 482
Author(s):  
Hilmar Guzmán ◽  
Federica Zammillo ◽  
Daniela Roldán ◽  
Camilla Galletti ◽  
Nunzio Russo ◽  
...  
Keyword(s):  
Carbon Capture ◽  
Active Sites ◽  
Co2 Reduction ◽  
Gas Diffusion ◽  
Gas Diffusion Electrode ◽  
Catalyst Loading ◽  
Co2 Conversion ◽  
Atmospheric Conditions ◽  
Electrochemical Co2 Reduction ◽  
Liquid Products

Electrochemical CO2 reduction is a promising carbon capture and utilisation technology. Herein, a continuous flow gas diffusion electrode (GDE)-cell configuration has been studied to convert CO2 via electrochemical reduction under atmospheric conditions. To this purpose, Cu-based electrocatalysts immobilised on a porous and conductive GDE have been tested. Many system variables have been evaluated to find the most promising conditions able to lead to increased production of CO2 reduction liquid products, specifically: applied potentials, catalyst loading, Nafion content, KHCO3 electrolyte concentration, and the presence of metal oxides, like ZnO or/and Al2O3. In particular, the CO productivity increased at the lowest Nafion content of 15%, leading to syngas with an H2/CO ratio of ~1. Meanwhile, at the highest Nafion content (45%), C2+ products formation has been increased, and the CO selectivity has been decreased by 80%. The reported results revealed that the liquid crossover through the GDE highly impacts CO2 diffusion to the catalyst active sites, thus reducing the CO2 conversion efficiency. Through mathematical modelling, it has been confirmed that the increase of the local pH, coupled to the electrode-wetting, promotes the formation of bicarbonate species that deactivate the catalysts surface, hindering the mechanisms for the C2+ liquid products generation. These results want to shine the spotlight on kinetics and transport limitations, shifting the focus from catalytic activity of materials to other involved factors.

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