Quartz crystal microbalance studies on electrochemical behavior of electrodeposited Pd–Ni alloys

2006 ◽  
Vol 51 (11) ◽  
pp. 2221-2229 ◽  
Author(s):  
M. Grdeń ◽  
K. Klimek ◽  
A. Czerwiński
Keyword(s):  
Quartz Crystal Microbalance ◽  
Electrochemical Behavior ◽  
Quartz Crystal ◽  
Ni Alloys

Selenium(IV) Electrochemistry on Silver: A Combined Electrochemical Quartz-Crystal Microbalance and Cyclic Voltammetric Investigation

2003 ◽  
Vol 68 (9) ◽  
pp. 1579-1595 ◽  
Author(s):  
Giovanni Pezzatini ◽  
Francesca Loglio ◽  
Massimo Innocenti ◽  
Maria Luisa Foresti
Keyword(s):  
Cyclic Voltammetry ◽  
Quartz Crystal Microbalance ◽  
Electrochemical Behavior ◽  
Quartz Crystal ◽  
Reduction Process ◽  
Electrochemical Quartz Crystal Microbalance ◽  
Potential Range ◽  
Cyclic Voltammetric ◽  
Scan Rate ◽  
Process Of Se

The electrochemical behavior of Se(IV) on silver was investigated by cyclic voltammetry and electrochemical quartz-crystal microbalance (EQCM) measurements. As already reported in the literature, Se(IV) electrochemistry is always complex, and on silver even more, due to the formation of a compound. Our results confirm that the reduction process of Se(IV) occurs through two reaction paths, Se(IV) → Se(0) and Se(IV) → Se(-II); the product Se(-II) then reacts with Se(IV) through a comproportionation reaction. The latter step leads to red Se that, according to the literature, is the only electroactive form of Se(0). The presence of the electroactive red Se is evident both in the negative range of potentials, through the reduction Se(0) → Se(-II), and in the less negative range of potentials, through the oxidation Se(0) → Se(IV). Moreover, our measurements pointed to the formation of a deposit that never redissolves. This deposit seems to be the electroinactive gray Se. The electrochemical behavior of Se(IV) was investigated in the whole potential range accessible on silver. Our results confirm the occurrence of competitive processes whose predominance depends on the scan rate, as well as on the potential limits of voltammetry. A detailed table with the processes occurring in different potential ranges was drawn up.

Study of hydrogen electrosorption in Pd-Ni alloys by the quartz crystal microbalance

2002 ◽  
Vol 7 (1) ◽  
pp. 43-48 ◽  
Author(s):  
Michał Grdeń ◽  
Krzysztof Kuśmierczyk ◽  
Andrzej Czerwiński
Keyword(s):  
Quartz Crystal Microbalance ◽  
Quartz Crystal ◽  
Ni Alloys ◽  
Hydrogen Electrosorption

Interaction of Clear Flavor Emulsions Containing Lemon Essential Oils with Lipid Bilayers via a Quartz Crystal Microbalance

2019 ◽  
Vol 25 (6) ◽  
pp. 879-884
Author(s):  
Takahiro Sakai ◽  
Hayato Seki ◽  
Shogo Yoshida ◽  
Hayato Hori ◽  
Hisashi Suzuki ◽  
...  
Keyword(s):  
Essential Oils ◽  
Lipid Bilayers ◽  
Quartz Crystal Microbalance ◽  
Quartz Crystal
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