Reference values of the diffusion-limited current at a microdisk electrode

2004 ◽  
Vol 50 (1) ◽  
pp. 107-113 ◽  
Author(s):  
D. Britz ◽  
K. Poulsen ◽  
J. Strutwolf
Keyword(s):  
Reference Values ◽  
Diffusion Limited ◽  
Limited Current

ANALYTICAL SOLUTION FOR THE STEADY-STATE CHRONOAMPEROMETRIC CURRENT FOR AN EC′ REACTION AT SPHEROIDAL ULTRAMICROELECTRODES

2006 ◽  
Vol 05 (01) ◽  
pp. 11-24 ◽  
Author(s):  
L. RAJENDRAN
Keyword(s):  
Steady State ◽  
Analytical Solution ◽  
Reaction Rates ◽  
Diffusion Limited ◽  
Limited Current ◽  
State Diffusion ◽  
Simulation Results ◽  
Disc Electrodes ◽  
Steady State Diffusion ◽  
Good Agreement

The steady-state chronoamperometric current for an EC′ reactions at spheroidal ultramicroelectrodes is derived from the non-steady-state diffusion limited current. The polynomial expressions pertaining to two extreme limits of reaction rates are combined for all reaction rates. Starting with the result for spheroidal electrode, equations are obtained for the steady-state currents at disc, oblate, hemisphere and prolate electrodes. Tabular compilation of dimensionless current for disc electrodes are reported. A good agreement with previously available simulation results is noticed.

scholarly journals Diffusion-Limited Current in Organic Metal-Insulator-Metal Diodes

2013 ◽  
Vol 111 (18) ◽  
Author(s):  
P. de Bruyn ◽  
A. H. P. van Rest ◽  
G. A. H. Wetzelaer ◽  
D. M. de Leeuw ◽  
P. W. M. Blom
Keyword(s):  
Organic Metal ◽  
Metal Insulator ◽  
Diffusion Limited ◽  
Limited Current ◽  
Metal Insulator Metal
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