DFT study of cobalt porphyrin complex for living radical polymerization of olefins

2012 ◽  
Vol 1001 ◽  
pp. 51-59 ◽  
Author(s):  
Huilong Dong ◽  
Tingjun Hou ◽  
Yaguang Zhao ◽  
Xuefeng Fu ◽  
Youyong Li
Keyword(s):  
Radical Polymerization ◽  
Living Radical Polymerization ◽  
Dft Study ◽  
Cobalt Porphyrin ◽  
Porphyrin Complex

Dispersion polymerization of acrylamide with living character and controlled morphologies initiated and mediated by cobalt porphyrin

RSC Advances ◽  
2016 ◽  
Vol 6 (68) ◽  
pp. 63519-63524 ◽  
Author(s):  
Liying Wang ◽  
Huanqin Zhao ◽  
Baolong Wang ◽  
Junmin Sun ◽  
Yongfeng Zhang ◽  
...  
Keyword(s):  
Radical Polymerization ◽  
Dispersion Polymerization ◽  
Living Radical Polymerization ◽  
Cobalt Porphyrin ◽  
Alcohol Water

Dispersion polymerization of acrylamide (AM) catalyzed by cobalt porphyrin [cobalt tetramethoxyphenylporphyrin, (TMOP)Co(ii)] with the feature of living radical polymerization (LRP) in alcohol/water or dimethylformamide (DMF)/water is described.

scholarly journals Dispersion and soap-free emulsion polymerization of tert-butyl acrylate with the living character and controlled particle size mediated by cobalt porphyrin

RSC Advances ◽  
2017 ◽  
Vol 7 (17) ◽  
pp. 10124-10131 ◽  
Author(s):  
Huanqin Zhao ◽  
Baolong Wang ◽  
Qingpan Li ◽  
Liying Wang ◽  
Junmin Sun ◽  
...  
Keyword(s):  
Particle Size ◽  
Emulsion Polymerization ◽  
Radical Polymerization ◽  
Butyl Acrylate ◽  
Living Radical Polymerization ◽  
Cobalt Porphyrin ◽  
Tert Butyl ◽  
Soap Free Emulsion Polymerization

Living radical polymerization (LRP) of tert-butyl acrylate (tBA) was carried out via the dispersion and soap-free emulsion polymerization mediated by cobalt porphyrin [cobalt tetramethoxyphenylporphyrin, (TMOP)Co(ii)].

scholarly journals One-pot synthesis for gradient copolymers via concurrent tandem living radical polymerization: mild and selective transesterification of methyl acrylate through Al(acac)3 with common alcohols

RSC Advances ◽  
2021 ◽  
Vol 11 (42) ◽  
pp. 26049-26055
Author(s):  
Tam Thi-Thanh Huynh ◽  
Si Eun Kim ◽  
Soon Cheon Kim ◽  
Jin Chul Kim ◽  
Young Il Park ◽  
...  
Keyword(s):  
Radical Polymerization ◽  
Methyl Acrylate ◽  
Living Radical Polymerization ◽  
One Pot ◽  
Gradient Copolymers ◽  
One Pot Synthesis

The acrylate based gradient copolymers were successfully synthesized by concurrent tandem living radical polymerization using Al(acac)3 as cocatalyst with common alcohols.

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