Influence of nano-clay compounding on thermo-oxidative stability and mechanical properties of a thermoset polymer system

2013 ◽  
Vol 84 ◽  
pp. 8-14 ◽  
Author(s):  
Priyank Upadhyaya ◽  
Samit Roy ◽  
Mohammad H. Haque ◽  
Hongbing Lu
Keyword(s):  
Mechanical Properties ◽  
Oxidative Stability ◽  
Polymer System ◽  
Nano Clay ◽  
Thermoset Polymer

Morphology and Mechanical Properties of Polyethylene Terephthalate/Ethylene Propylene Diene Monomer (PET/EPDM) in the Presence of Nanoclay

2020 ◽  
Vol 57 (3) ◽  
pp. 249-259
Author(s):  
Baifen Liu ◽  
Mohammad Mirjalili ◽  
Peiman Valipour ◽  
Sajad Porzal ◽  
shirin Nourbakhsh
Keyword(s):  
Mechanical Properties ◽  
Impact Strength ◽  
Thermal Destruction ◽  
Processing Temperature ◽  
Tem Analysis ◽  
Maximum Stiffness ◽  
Cloisite 30B ◽  
Nano Clay ◽  
The Matrix ◽  
Sample Maximum

This research deals with the mechanical properties, microstructure, and interrelations of triple nanocomposite based on PET/EPDM/Nanoclay. These properties were examined in different percentages of PET/EPDM blend with compatibilizer (Styrene-Ethylene/Butylene-Styrene)-G-(Maleic anhydrate) (SEBS-g-MAH). Results showed that the addition of 15% SEBS-g-MAH improved the toughness and impact strength of this nanocomposite. SEM micrographs indicated the most stable fuzzy microstructure in a 50/50 mixture of scattered phases of EPDM/SEBS-g-MAH. The effects of percentages of 1, 3, 5, 7 nanoclay Cloisite 30B (C30B) on the improvement of the properties were evaluated. With the addition of nano clay, the toughness and impact strength was reduced. Thermal destruction of nanoclay in processing temperature led to the decreasing dispersion of clay plates in the matrix and a reduction in the distances of nano clay plates in the composite compared to pure nano clay. XRD and TEM analysis was used to demonstrate the results. By adding 1% of nanoclay to the optimal sample, maximum stiffness, and Impact strength, among other nanocomposites, was achieved.

Polyimide Copolymers Containing Various Levels Of The 6F Moiety For High Temperature And Microelectronic Applications

1991 ◽  
Vol 227 ◽  
Author(s):  
M. Haider ◽  
E. Chenevey ◽  
R. H. Vora ◽  
W. Cooper ◽  
M. Glick ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
High Temperature ◽  
Electrical Properties ◽  
Oxidative Stability ◽  
Trifluoromethyl Group ◽  
Thermal And Mechanical Properties

ABSTRACTTrifluoromethyl group-containing polyimides not only show extraordinary electrical properties, but they also exhibit excellent long-term thermo-oxidative stability. Among the most thermomechanically stable structural polyimides are those from 6F dianhydride (6FDA) and 6F diamines. The effects of substituting non-fluorine containing monomers such as BTDA, mPDA and 4,4′-DADPS for the hexafluoroisopropylidene monomers on the dielectric, thermo-oxidative, thermal and mechanical properties of the copolymers were studied.

Effect of Nano Clay on Mechanical Behavior of Bamboo Fiber Reinforced Polyester Composites

2018 ◽  
Vol 877 ◽  
pp. 294-298 ◽  
Author(s):  
Kundan Patel ◽  
Jay Patel ◽  
Piyush Gohil ◽  
Vijaykumar Chaudhary
Keyword(s):  
Mechanical Properties ◽  
Composite Materials ◽  
Clay Content ◽  
Weight Fraction ◽  
Industrial Applications ◽  
Vital Role ◽  
Bamboo Fiber ◽  
Nano Clay ◽  
Different Types ◽  
Polyester Composite

Composite materials play a vital role in many industrial applications. Researchers are working on fabrication of new composite materials worldwide to enhance the applicability of these materials. The present study aimed to investigate the effect of Nano clay loading as filler on the mechanical properties of the bamboo fiber yarn reinforced polyester composite. Five different types of composite specimen were prepared with Nano clay loadings of 0 to 4 % weight fraction using hand lay-up technique. It was observed that the composite sheet with 1 wt % nano clay content exhibited the optimized tensile and flexural strength. However the mechanical properties tend to decrease with addition of nano clay content from 2 to 4 wt %. In spite of that the values of mechanical properties with 2 and 3 wt % nano clay content is higher than 0 wt % nano clay content.

scholarly journals SiO2 particles effect on the mechanical properties of the starch/PVA blends

2018 ◽  
Vol 16 (36) ◽  
pp. 153-171
Author(s):  
Nahida J. H.
Keyword(s):  
Mechanical Properties ◽  
Glass Transition ◽  
Transition Temperature ◽  
Glass Transition Temperature ◽  
Ultimate Strength ◽  
Thermo Gravimetric Analysis ◽  
Polymer System ◽  
Optical Microscope ◽  
Gravimetric Analysis ◽  
Ratio Increase

The present work studies the mechanical properties of SiO2 μPs, and NPs in St/PVA blends. The samples were prepared by casting method as PVA, St/PVA blends at different concentrations (30, 40, 50, and 60 %). DSC and TGA tests were carried out to the samples evolved. The result showed a single glass transition temperature (Tg) for all St /PVA blends that was attributed to the good miscibility of the blends involved. It was found that (Tg) decrease with starch ratio increase. It was seen that (PVA) of (Tg=105 oC); The glass transition temperature which was decrease with starch ratio that was attributed to glass transition relaxation process due to micro-Brownian motion of the main chain back bond. The endothermic peak at 200 oC was attributed to melting point of (PVA). Thermal properties of PVA; and St /PVA blends at different concentration (30, 40, 50, and 60 %) were evaluated by thermo gravimetric analysis (TGA). The analyses were carried out from 20 to 600 oC at 10 oC)/min heating rate in air oxygen atmosphere. The weight loss stages depended on polymer system. The starch addition causing shifting in the second degradation temperature to the higher temperature; which result in overlapping between the two main degradation steps, these result was attributed to the St/ PVA blend compatibility. The mechanical properties results showed a decrease in ultimate strength with starch ratio increase. The ultimate strength of (PVA) was (47 MPa), whereas the ultimate strength of 60 %St/PVA was (11 MPa) and for 30 %St/PVA was the highest ultimate strength of blends involved (26 MPa). SiO2μPs (753.7 nm), and NPs (263.1 nm) were added at different concentrations (1.5, 2, and 2.5 %). 1.5% SiO2μPs, and NPs of the best ultimate strength (69 MPa), (86 MPa) respectively then it was decreased by SiO2μPs, and NPs increase. Optical microscope of the samples involved was investigated. It was concluded the prepared samples were suggested to be used as packaging materials for agriculture application and its ultimate strength could be controlled by SiO2μPs, and NPs addition.

scholarly journals Mechanical properties of bulk Sylgard 184 and its extension with silicone oil

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
R. Moučka ◽  
M. Sedlačík ◽  
J. Osička ◽  
V. Pata
Keyword(s):  
Mechanical Properties ◽  
Tensile Test ◽  
Ambient Temperature ◽  
Oil Content ◽  
Silicone Oil ◽  
Polymer System ◽  
Industrial Applications ◽  
Curing Temperature ◽  
Rotational Rheometer ◽  
Oil Concentration

AbstractDue to its simple curing and very good mechanical properties, Sylgard 184 belongs to the most widely and frequently used silicones in many industrial applications such as microfluidics and microengineering. On top of that its mechanical properties are further controllable through the curing temperature, which may vary from ambient temperature up to 200 °C; the lower the curing temperature the lower the mechanical properties (Johnston et al. in J Micromech Microeng 24:7, 2014. 10.1088/0960-1317/24/3/035017). However, certain specialised application may require even a softer binder than the low curing temperature allows for. In this study we show that this softening can be achieved with the addition of silicone oil into the Sylgard 184 system. To this end a series of Sylgard 184 samples with varying silicone oil concentrations were prepared and tested (tensile test, rotational rheometer) in order to determine how curing temperature and silicone oil content affect mechanical properties. Curing reaction of the polymer system was found to observe 2nd order kinetics in all cases, regardless the oil concentration used. The results suggest that within the tested concentration range the silicone oil addition can be used to soften commercial silicone Sylgard 184.

scholarly journals 3D-printable zwitterionic nano-composite hydrogel system for biomedical applications

2020 ◽  
Vol 11 ◽  
pp. 204173142096729
Author(s):  
Nathalie Sällström ◽  
Andrew Capel ◽  
Mark P Lewis ◽  
Daniel S Engstrøm ◽  
Simon Martin
Keyword(s):  
Mechanical Properties ◽  
Biomedical Applications ◽  
Culture Medium ◽  
Careful Selection ◽  
Nano Composite ◽  
Significant Difference ◽  
Nano Clay ◽  
Hydrogel Surface ◽  
Selection Of ◽  
Hydrogel System

Herein, the cytotoxicity of a novel zwitterionic sulfobetaine hydrogel system with a nano-clay crosslinker has been investigated. We demonstrate that careful selection of the composition of the system (monomer to Laponite content) allows the material to be formed into controlled shapes using an extrusion based additive manufacturing technique with the ability to tune the mechanical properties of the product. Moreover, the printed structures can support their own weight without requiring curing during printing which enables the use of a printing-then-curing approach. Cell culture experiments were conducted to evaluate the neural cytotoxicity of the developed hydrogel system. Cytotoxicity evaluations were conducted on three different conditions; a control condition, an indirect condition (where the culture medium used had been in contact with the hydrogel to investigate leaching) and a direct condition (cells growing directly on the hydrogel). The result showed no significant difference in cell viability between the different conditions and cells were also found to be growing on the hydrogel surface with extended neurites present.

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