scholarly journals A review and analysis of electrical percolation in carbon nanotube polymer composites

2009 ◽  
Vol 69 (10) ◽  
pp. 1486-1498 ◽  
Author(s):  
Wolfgang Bauhofer ◽  
Josef Z. Kovacs
Polymers ◽  
2021 ◽  
Vol 13 (9) ◽  
pp. 1355
Author(s):  
Astrid Diekmann ◽  
Marvin C. V. Omelan ◽  
Ulrich Giese

Incorporating nanofillers into elastomers leads to composites with an enormous potential regarding their properties. Unfortunately, nanofillers tend to form agglomerates inhibiting adequate filler dispersion. Therefore, different carbon nanotube (CNT) pretreatment methods were analyzed in this study to enhance the filler dispersion in polydimethylsiloxane (PDMS)/CNT-composites. By pre-dispersing CNTs in solvents an increase in electrical conductivity could be observed within the sequence of tetrahydrofuran (THF) > acetone > chloroform. Optimization of the pre-dispersion step results in an AC conductivity of 3.2 × 10−4 S/cm at 1 Hz and 0.5 wt.% of CNTs and the electrical percolation threshold is decreased to 0.1 wt.% of CNTs. Optimum parameters imply the use of an ultrasonic finger for 60 min in THF. However, solvent residues cause a softening effect deteriorating the mechanical performance of these composites. Concerning the pretreatment of CNTs by physical functionalization, the use of surfactants (sodium dodecylbenzenesulfonate (SDBS) and polyoxyethylene lauryl ether (“Brij35”)) leads to no improvement, neither in electrical conductivity nor in mechanical properties. Chemical functionalization enhances the compatibility of PDMS and CNT but damages the carbon nanotubes due to the oxidation process so that the improvement in conductivity and reinforcement is superimposed by the CNT damage even for mild oxidation conditions.


Nanoscale ◽  
2019 ◽  
Vol 11 (6) ◽  
pp. 2779-2786 ◽  
Author(s):  
Jing Li ◽  
Santiago Orrego ◽  
Junjie Pan ◽  
Peisheng He ◽  
Sung Hoon Kang

We report a facile sacrificial casting–etching method to synthesize nanoporous carbon nanotube/polymer composites for ultra-sensitive and low-cost piezoresistive pressure sensors.


2015 ◽  
Vol 117 (21) ◽  
pp. 214306 ◽  
Author(s):  
Richard J. Castellano ◽  
Cevat Akin ◽  
Gabriel Giraldo ◽  
Sangil Kim ◽  
Francesco Fornasiero ◽  
...  

2014 ◽  
Vol 15 (6) ◽  
pp. 1242-1250 ◽  
Author(s):  
Ke Peng ◽  
Yan-Jun Wan ◽  
Dong-You Ren ◽  
Qing-Wen Zeng ◽  
Long-Cheng Tang

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