An optimization method for formulating model-based jet fuel surrogate by emulating physical, gas phase chemical properties and threshold sooting index (TSI) of real jet fuel under engine relevant conditions

2018 ◽  
Vol 193 ◽  
pp. 192-217 ◽  
Author(s):  
Wenbin Yu ◽  
Wenming Yang ◽  
Kunlin Tay ◽  
Feiyang Zhao
Keyword(s):  
Gas Phase ◽  
Chemical Properties ◽  
Optimization Method ◽  
Jet Fuel ◽  
Model Based ◽  
Fuel Surrogate ◽  
Phase Chemical

Chemical Properties of Zwitterionic Imidazolium Alkanecarboxylates Studied in Gas-Phase by Electrospray Ionization – Collision-Induced Dissociation / Cviterjonu Tipa Imidazolija Alkānkarboksilātu Ķīmiskās Īpašības Gāzes Fāzē, Kas Pētītas Ar Elektroizsmidzināšanas Jonizāciju – Sadursmju Inducēto Disociāciju

2012 ◽  
Vol 51 (3) ◽  
pp. 249-256
Author(s):  
A. Podjava ◽  
P. Mekss ◽  
A. Zicmanis ◽  
S. Krasnov
Keyword(s):  
Gas Phase ◽  
Chemical Properties ◽  
Collision Induced Dissociation ◽  
Potassium Ions ◽  
Hydrogen Deuterium Exchange ◽  
Carboxylate Group ◽  
Hydrogen Deuterium ◽  
Ionization Mode ◽  
Sodium And Potassium ◽  
Phase Chemical

Gas-phase chemical properties of several (1-methylimidazol-3-io)-alkane-1-carboxylates (alkane=ethane, propane and butane) have been investigated in this study. These substances are synthesized using classical transformations and analyzed in positive ionization mode using collision-induced dissociation (0-50 eV). These experiments were carried out in both deuterated and undeuterated solvent media. The data obtained in this study show, that carboxylate group weakly influences fragmentation of zwitterionic imidazolium carboxylates in positive electrospray mode. On the other hand, these compounds exert a tendency to form various adducts with sodium and potassium ions and to participate in hydrogen/deuterium exchange in the gas phase.

scholarly journals The periodic table – an experimenter’s guide to transactinide chemistry

2019 ◽  
Vol 107 (9-11) ◽  
pp. 865-877 ◽  
Author(s):  
Robert Eichler
Keyword(s):  
Research And Development ◽  
Gas Phase ◽  
Periodic Table ◽  
Chemical Properties ◽  
Superheavy Elements ◽  
Experimental Results ◽  
Chemical Studies ◽  
Phase Chemical

Abstract The fundamental principles of the periodic table guide the research and development of the challenging experiments with transactinide elements. This guidance is elucidated together with experimental results from gas phase chemical studies of the transactinide elements with the atomic numbers 104–108 and 112–114. Some deduced chemical properties of these superheavy elements are presented here in conjunction with trends established by the periodic table. Finally, prospects are presented for further chemical investigations of transactinides based on trends in the periodic table.

scholarly journals On-line gas chromatographic studies of Rf, Zr, and Hf bromides

2000 ◽  
Vol 88 (12) ◽  
Author(s):  
E.R. Sylwester ◽  
K.E. Gregorich ◽  
D.M. Lee ◽  
B. Kadkhodayan ◽  
A. Türler ◽  
...  
Keyword(s):  
Gas Phase ◽  
Heavy Element ◽  
Chemical Properties ◽  
Monte Carlo Code ◽  
Enthalpy Of Adsorption ◽  
Group 4 ◽  
On Line ◽  
Simple Extrapolation ◽  
Isothermal Gas ◽  
Phase Chemical

The Heavy Element Volatility Instrument (HEVI), an on-line isothermal gas chromatography system, has been used to separate the volatile bromide compounds of the group 4 elements Zr and Hf and the transactinide Rf according to their volatilities, and to provide data on the gas phase chemical properties of very short-lived isotopes in amounts as low as a few atoms. For these studiesA Monte Carlo code was used to deduce the enthalpy of adsorption (ΔHVolatilities of the group 4 bromides support the conclusion from previous results for the group 4 chlorides that Rf deviates from the trend expected by simple extrapolation of the properties of its lighter homologs in the periodic table. The group 4 bromides are also observed to be less volatile than their respective chlorides, as predicted by relativistic calculations.

Optimization of a Shock Absorber Design Using Model-Based Approach

2012 ◽  
Vol 452-453 ◽  
pp. 1351-1355 ◽  
Author(s):  
Grzegorz Wszołek ◽  
Piotr Czop ◽  
Dawid Jakubowski ◽  
Damian Slawik
Keyword(s):  
Automotive Industry ◽  
Shock Absorber ◽  
Flow Characteristic ◽  
Optimization Method ◽  
Design Parameters ◽  
Coupled Models ◽  
Model Based ◽  
Noise Evaluation ◽  
Optimal Values ◽  
Application Scope

The aim of this paper is to demonstrate a possibility to optimize a shock absorber design to minimize level of vibrations with the use of model-based approach. The paper introduces a proposal of an optimization method that allows to choose the optimal values of the design parameters using a shock absorber model to minimize the level of vibrations. A model-based approach is considered to obtain the optimal pressure-flow characteristic by simulations conducted with the use of coupled models, including the damper and the servo-hydraulic tester model. The presence of the tester model is required due to high non-linear coupling of the tested object (damper) and the tester itself to be used for noise evaluation. This kind of evaluation is used in the automotive industry to investigate dampers, as an alternative to vehicle-level tests. The paper provides numerical experimental case studies to show application scope of the proposed method

Synthesis of polymorphic titanium oxide nanoparticles by a rapid gas-phase chemical reaction

2016 ◽  
Vol 26 (2) ◽  
pp. 157-159 ◽  
Author(s):  
Ning Luo ◽  
Hong Wen Jing ◽  
Zhan Guo Ma ◽  
Weidong Liu ◽  
Liangchi Zhang ◽  
...  
Keyword(s):  
Gas Phase ◽  
Titanium Oxide ◽  
Chemical Reaction ◽  
Oxide Nanoparticles ◽  
Titanium Oxide Nanoparticles ◽  
Phase Chemical

XPS analysis of NH3 plasma-treated polystyrene films utilizing gas phase chemical modification

1988 ◽  
Vol 26 (2) ◽  
pp. 559-572 ◽  
Author(s):  
Youichi Nakayama ◽  
Takayuki Takahagi ◽  
Fusami Soeda ◽  
Kenji Hatada ◽  
Shoji Nagaoka ◽  
...  
Keyword(s):  
Chemical Modification ◽  
Gas Phase ◽  
Xps Analysis ◽  
Phase Chemical

Time-resolved IR chemiluminescence in gas-phase chemical kinetics

1999 ◽  
Vol 68 (3) ◽  
pp. 171-181 ◽  
Author(s):  
Evgenii N Chesnokov ◽  
Viktor N Panfilov
Keyword(s):  
Gas Phase ◽  
Chemical Kinetics ◽  
Time Resolved ◽  
Phase Chemical
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