Novel synthesis of ZnPc/TiO2 composite particles and carbon dioxide photo-catalytic reduction efficiency study under simulated solar radiation conditions

Author(s):  
Qian Wang ◽  
Wei Wu ◽  
Jianfeng Chen ◽  
Guangwen Chu ◽  
Kai Ma ◽  
...  
Catalysts ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 885
Author(s):  
Aida M. Díez ◽  
Helen E. Valencia ◽  
Maria Meledina ◽  
Joachim Mayer ◽  
Yury V. Kolen'ko

Considering water scarcity, photo-based processes have been presented as a depollution technique, which should be optimized in order to be applied in the future. For that, the addition of an active photocatalyst and the usage of solar radiation are mandatory steps. Thus, Fe3O4–SiO2–TiO2 was synthesized, and its performance was evaluated using simulated solar radiation and methylene blue as a model pollutant. Under optimal conditions, 86% degradation was attained in 1 h. These results were compared to recent published data, and the better performance can be attributed to both the operational conditions selection and the higher photocatalyst activity. Indeed, Fe3O4–SiO2–TiO2 was physico-chemically characterized with techniques such as XRD, N2 isotherms, spectrophotometry, FTIR, electrochemical assays and TEM.


2021 ◽  
Author(s):  
Zuozhong Liang ◽  
Hong-Yan Wang ◽  
Haoquan Zheng ◽  
Wei Zhang ◽  
Rui Cao

The recent progress made on porphyrin-based frameworks and their applications in energy-related conversion technologies (e.g., ORR, OER and CO2RR) and storage technologies (e.g., Zn–air batteries).


Carbon ◽  
2005 ◽  
Vol 43 (12) ◽  
pp. 2621-2624 ◽  
Author(s):  
Marco G. Crestani ◽  
Ivan Puente-Lee ◽  
Luis Rendón-Vazquez ◽  
Patricia Santiago ◽  
Federico del Rio ◽  
...  

2016 ◽  
Vol 99 (3) ◽  
pp. 839-846 ◽  
Author(s):  
Abdelhakim Belkaid ◽  
Ilhami Colak ◽  
Korhan Kayisli

1994 ◽  
pp. 74-81
Author(s):  
T. Hattori ◽  
S. Yamauchi ◽  
M. Endo ◽  
S. Komai ◽  
A. Satsuma ◽  
...  

2012 ◽  
Vol 9 (12) ◽  
pp. 18479-18518
Author(s):  
A. Rain-Franco ◽  
C. Muñoz ◽  
C. Fernandez

Abstract. We investigated the production of ammonium via photodegradation of dissolved organic matter (DOM) in the coastal upwelling system off central Chile (36° S). Photoammonification experiments were carried out using exudates obtained from representative diatom species (Chaetoceros muelleri and Thalassiosira minuscule) and natural marine DOM under simulated solar radiation conditions. Additionally, we evaluated the use of photoproduced ammonium by natural microbial communities and separated ammonium oxidizing archaea and bacteria by using GC-7 as an inhibitor of the archaeal community. We found photoammonification operating at two levels: via the transformation of DOM by UV radiation (abiotic ammonification) and via the simultaneous occurrence of abiotic phototransformation and biological remineralization of DOM into NH4+ (referred as gross photoproduction of NH4+). The maximum rates of abiotic ammonification reached 0.057 μmol L−1 h−1, whereas maximum rates of gross photoproduction reached 0.746 μmol L−1 h−1. Our results also suggest that ammonium oxidizing archaea could dominate the biotic remineralization induced by photodegradation of organic matter and consequently play an important role in the local N cycle. Abiotic ammonium photoproduction in coastal upwelling systems could support between 7 and 50% of the spring-summer phytoplankton NH4+ demand. Surprisingly, gross ammonium photoproduction (remineralization induced by abiotic ammonification) might support 50 to 180% of spring-summer phytoplankton NH4+ assimilation.


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