Preparation of halloysite-derived mesoporous silica nanotube with enlarged specific surface area for enhanced dye adsorption

2016 ◽  
Vol 132-133 ◽  
pp. 114-121 ◽  
Author(s):  
Zhu Shu ◽  
Yun Chen ◽  
Jun Zhou ◽  
Tiantian Li ◽  
Zimo Sheng ◽  
...  
2020 ◽  
Vol 1 (9) ◽  
pp. 3556-3564
Author(s):  
Lan She ◽  
Miao Sun ◽  
Xinfang Li ◽  
Anfeng Kang ◽  
Feng Yang ◽  
...  

Results indicated that the effect of MSNRs on cell viability and cellular oxidative stress was related to specific surface area.


2019 ◽  
Vol 280 ◽  
pp. 133-143 ◽  
Author(s):  
Laura M. Henning ◽  
Diego Díaz Cubas ◽  
Maria G. Colmenares ◽  
Johannes Schmidt ◽  
Maged F. Bekheet ◽  
...  

1998 ◽  
Vol 13 (10) ◽  
pp. 2888-2895 ◽  
Author(s):  
Weiping Cai ◽  
Lide Zhang ◽  
Huicai Zhong ◽  
Guoliang He

Influences of annealing on the structure of mesoporous silica loaded with silver (Ag) nanoparticles, and on the coarsening of Ag particles within pores of the host were investigated from isothermal sorption. Doping a small amount of Ag nanoparticles into pores of silica and subsequent annealing decreases the measured values of specific surface area and pore volume of porous silica significantly. This is attributed to the presence and coarsening of Ag particles within pores or channels between pores, which result in more and more isolated and unmeasured free spaces. The measured value of a specific surface area for the doped samples cannot represent the real value, which is, in fact, unable to be measured directly. During additional annealing, Ag particles within silica coarsen mainly according to the mechanism of formation of Ag adatoms on pore wall and diffusion of the adatoms along with pore walls. Only the larger particles located in the larger pores can continuously grow. The smaller particles and those located in the channels or pores with smaller dimension will disappear. The activation energy of the ripening process was estimated to be about 0.60 eV, and the migration barrier of Ag adatom on the pore wall of silica is about 0.10 eV.


2016 ◽  
Vol 123 ◽  
pp. 76-82 ◽  
Author(s):  
Zhu Shu ◽  
Tiantian Li ◽  
Jun Zhou ◽  
Yun Chen ◽  
Zimo Sheng ◽  
...  

2021 ◽  
Author(s):  
Qiang Chen ◽  
Kai Chen ◽  
Feng Yu ◽  
Aixia Guo ◽  
Siqing Zou ◽  
...  

Abstract High surface area mesoporous silica (SiO2) nanospheres has been considered an ideal material for the catalytic, adsorption and drug delivery. However, synthesis of ultra-high specific surface area mesoporous silica nanoparticles with well-defined sphere structure and small particle size (< 200 nm) is still challenging. Here, a two-stream confined jet impingement continuous microchannel reactor is proposed to produce novel mesoporous silica nanospheres (MSNs) with ultra-high specific surface area (SSA) and abundant worm-like meso-porosity. The as-obtained MSNs with worm-like mesoporous structure were produced with average particle diameter of 142 ~ 207 nm, high SSA of 1347 ~ 1854 m2/g, total pore volume of 0.86 ~ 1.23 cm3/g and pore diameter of 2.6 ~ 3.3nm. Moreover, the shear force field in the microchannel reactor on the mesoscopic structure of MSNs was simulated by mesoscopic kinetics. Additionally, MSNs was used as the silicon source to synthesize lithium silicate (Li4SiO4), which enhanced carbon dioxide (CO2) adsorption of 27.18 wt% at 650 ℃.


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