scholarly journals Vacuum ultraviolet absorption spectroscopy in combination with comprehensive two-dimensional gas chromatography for the monitoring of volatile organic compounds in breath gas: A feasibility study

2016 ◽  
Vol 1464 ◽  
pp. 141-146 ◽  
Author(s):  
Beate Gruber ◽  
Thomas Groeger ◽  
Dale Harrison ◽  
Ralf Zimmermann
Keyword(s):  
Gas Chromatography ◽  
Volatile Organic Compounds ◽  
Organic Compounds ◽  
Feasibility Study ◽  
Absorption Spectroscopy ◽  
Vacuum Ultraviolet ◽  
Ultraviolet Absorption ◽  
Two Dimensional ◽  
Volatile Organic ◽  
Ultraviolet Absorption Spectroscopy

scholarly journals Emissions of non-methane volatile organic compounds from combustion of domestic fuels in Delhi, India

2020 ◽  
Author(s):  
Gareth J. Stewart ◽  
W. Joe F. Acton ◽  
Beth S. Nelson ◽  
Adam R. Vaughan ◽  
James R. Hopkins ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Gas Chromatography ◽  
Volatile Organic Compounds ◽  
Organic Compounds ◽  
Time Of Flight ◽  
Emission Factors ◽  
Two Dimensional ◽  
Flight Mass Spectrometry ◽  
Volatile Organic ◽  
Tof Ms

Abstract. 29 different fuel types used in residential dwellings in northern India were collected from across New Delhi (76 samples in total). Emission factors of a wide range of non-methane volatile organic compounds (NMVOCs) (192 compounds in total) were measured during controlled burning experiments using dual-channel gas chromatography with flame ionisation detection (DC-GD-FID), two-dimensional gas chromatography (GC×GC-FID), proton-transfer-reaction time-of-flight mass spectrometry (PTR-ToF-MS) and solid-phase extraction two-dimensional gas chromatography with time-of-flight mass spectrometry (SPE-GC×GC-ToF-MS). 94 % quantification was achieved on average across all fuel types. The largest contributors to emissions from most fuel types were small non-aromatic oxygenated species, phenolics and furanics. The emission factors (in g kg−1) for total gas-phase NMVOCs were: fuel wood (18.7, 4.3–96.7), cow dung cake (62.0, 35.3–83.0), crop residue (37.9, 8.9–73.8), charcoal (5.4, 2.4–7.9), sawdust (72.4, 28.6–115.5), municipal solid waste (87.3, 56.6–119.1) and liquified petroleum gas (5.7, 1.9–9.8). The emission factors measured in this study allow for better characterisation, evaluation and understanding of the air quality impacts of residential solid fuel combustion in India.

New approaches to monitor semi-volatile organic compounds released during coffee roasting using flow-through/active sampling and comprehensive two-dimensional gas chromatography

2019 ◽  
Vol 119 ◽  
pp. 349-358 ◽  
Author(s):  
Fábio Junior Moreira Novaes ◽  
Ademário Iris da Silva Junior ◽  
Chadin Kulsing ◽  
Yada Nolvachai ◽  
Humberto Ribeiro Bizzo ◽  
...  
Keyword(s):  
Gas Chromatography ◽  
Volatile Organic Compounds ◽  
Organic Compounds ◽  
Two Dimensional ◽  
Active Sampling ◽  
New Approaches ◽  
Volatile Organic ◽  
Flow Through ◽  
Coffee Roasting

scholarly journals Emissions of non-methane volatile organic compounds from combustion of domestic fuels in Delhi, India

2021 ◽  
Vol 21 (4) ◽  
pp. 2383-2406 ◽  
Author(s):  
Gareth J. Stewart ◽  
W. Joe F. Acton ◽  
Beth S. Nelson ◽  
Adam R. Vaughan ◽  
James R. Hopkins ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Gas Chromatography ◽  
Volatile Organic Compounds ◽  
Organic Compounds ◽  
Time Of Flight ◽  
Emission Factors ◽  
Two Dimensional ◽  
Flight Mass Spectrometry ◽  
Volatile Organic ◽  
Tof Ms

Abstract. Twenty-nine different fuel types used in residential dwellings in northern India were collected from across Delhi (76 samples in total). Emission factors of a wide range of non-methane volatile organic compounds (NMVOCs) (192 compounds in total) were measured during controlled burning experiments using dual-channel gas chromatography with flame ionisation detection (DC-GC-FID), two-dimensional gas chromatography (GC × GC-FID), proton-transfer-reaction time-of-flight mass spectrometry (PTR-ToF-MS) and solid-phase extraction two-dimensional gas chromatography with time-of-flight mass spectrometry (SPE-GC × GC–ToF-MS). On average, 94 % speciation of total measured NMVOC emissions was achieved across all fuel types. The largest contributors to emissions from most fuel types were small non-aromatic oxygenated species, phenolics and furanics. The emission factors (in g kg−1) for total gas-phase NMVOCs were fuelwood (18.7, 4.3–96.7), cow dung cake (62.0, 35.3–83.0), crop residue (37.9, 8.9–73.8), charcoal (5.4, 2.4–7.9), sawdust (72.4, 28.6–115.5), municipal solid waste (87.3, 56.6–119.1) and liquefied petroleum gas (5.7, 1.9–9.8). The emission factors measured in this study allow for better characterisation, evaluation and understanding of the air quality impacts of residential solid-fuel combustion in India.

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