Preparation and evaluation of hydrophilic C18 monolithic sorbents for enhanced polar compound retention in liquid chromatography and solid phase extraction

2011 ◽  
Vol 1218 (48) ◽  
pp. 8608-8616 ◽  
Author(s):  
Yun Li ◽  
Xin Xie ◽  
Milton L. Lee ◽  
Jiping Chen
Keyword(s):  
Liquid Chromatography ◽  
Solid Phase Extraction ◽  
Solid Phase ◽  
Phase Extraction ◽  
Polar Compound ◽  
Monolithic Sorbents ◽  
Preparation And Evaluation

Corncob Waste Based Adsorbent for Solid Phase Extraction of Tartrazine in Carbonated Drinks and Analytical Method using Ultra Performance Liquid Chromatography-Mass Spectrometry

2020 ◽  
Vol 16 (7) ◽  
pp. 924-932
Author(s):  
Yasmeen Mutlaq Ghazi Al Shamari ◽  
Saikh Mohammad Wabaidur ◽  
Abdulrahman Abdullah Alwarthan ◽  
Moonis Ali Khan ◽  
Masoom Raza Siddiqui
Keyword(s):  
Mass Spectrometry ◽  
Liquid Chromatography ◽  
Solid Phase Extraction ◽  
Solid Phase ◽  
Cost Effective ◽  
Ultra Performance Liquid Chromatography ◽  
Phase Extraction ◽  
Food Dye ◽  
Hyphenated Technique

Background : A new method has been developed for the determination of food dye tartrazine in soft drinks. Tartrazine is determined by hyphenated technique Ultra Performance Liquid Chromatography coupled with Mass spectrometry. The solid-phase extraction was used for the extraction of tartrazine. Methods: For the LC-MS analysis of tartrazine acetonitrile, water (80:20) was used as a mobile phase whereas, the C-18 column was selected as the stationary phase. The chromatographic run was allowed for 1 min. The adsorbent of the solid-phase extraction was synthesized from the waste corn cob. Results: Method found to be linear in the range of 0.1 mg L-1 - 10 mg L-1, limits of detection and quantitation were found to be 0.0165 mgL-1 and 0.055 mgL-1, respectively. Tartrazine, in the real sample, was found to be 20.39 mgL-1 and 83.26 mgL-1. Conclusion: The developed UPLC-MS method is rapid, simple, precise and can be used for the quantitative analysis of tartrazine. The solid-phase extraction also involves a cost-effective procedure for extraction as it does not involve the commercial cartridge.

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