Preparation of glycerol dimethacrylate-based polymer monolith with unusual porous properties achieved via viscoelastic phase separation induced by monodisperse ultra high molecular weight poly(styrene) as a porogen

2006 ◽  
Vol 1119 (1-2) ◽  
pp. 66-79 ◽  
Author(s):  
Hiroshi Aoki ◽  
Takuya Kubo ◽  
Tohru Ikegami ◽  
Nobuo Tanaka ◽  
Ken Hosoya ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Phase Separation ◽  
High Molecular Weight ◽  
Polymer Monolith ◽  
Porous Properties ◽  
Ultra High Molecular Weight ◽  
High Molecular Weight Poly

Stereo-chemical contributions to the glass transition and liquid–liquid phase separation in high molecular weight poly(N-vinyl carbazole)

RSC Advances ◽  
2016 ◽  
Vol 6 (35) ◽  
pp. 29326-29333 ◽  
Author(s):  
Abdul G. Al Lafi ◽  
James N. Hay
Keyword(s):  
Molecular Weight ◽  
Glass Transition ◽  
Phase Separation ◽  
Liquid Phase ◽  
High Molecular Weight ◽  
Structural Properties ◽  
Thermal History ◽  
Liquid Phase Separation ◽  
High Molecular Weight Poly ◽  
Liquid Liquid Phase Separation

Thermal history and purification effects on the structural properties of PVK were investigated. Liquid–liquid phase separation is suggested to occur by separation of isotactic rich segments from a matrix which is predominantly atactic.

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