Kinetic modeling of carboxylation of propylene oxide to propylene carbonate using ion-exchange resin catalyst in a semi-batch slurry reactor

2017 ◽  
Vol 168 ◽  
pp. 189-203 ◽  
Author(s):  
Xin Jin ◽  
Pallavi Bobba ◽  
Nicolas Reding ◽  
Ziwei Song ◽  
Prem S. Thapa ◽  
...  
AIChE Journal ◽  
1984 ◽  
Vol 30 (1) ◽  
pp. 1-7 ◽  
Author(s):  
R. Jaganathan ◽  
R. V. Chaudhari ◽  
P. A. Ramachandran

2017 ◽  
Vol 34 (4) ◽  
pp. 987-996 ◽  
Author(s):  
Vishal Suresh Chandane ◽  
Ajit Pralhad Rathod ◽  
Kailas Lachchhuram Wasewar ◽  
Shriram Shaligram Sonawane

2012 ◽  
Vol 8 ◽  
pp. 227-233 ◽  
Author(s):  
Nan Wang ◽  
Ronghua Wang ◽  
Xia Shi ◽  
Gang Zou

A clean process has been developed for the synthesis of 2-adamantylphenol derivatives through adamantylation of substituted phenols with adamantanols catalyzed by commercially available and recyclable ion-exchange sulfonic acid resin in acetic acid. The sole byproduct of the adamantylation reaction, namely water, could be converted into the solvent acetic acid by addition of a slight excess of acetic anhydride during the work-up procedure, making the process waste-free except for regeneration of the ion-exchange resin, and facilitating the recycling of the resin catalyst. The ion-exchange sulfonic acid resin catalyst could be readily recycled by filtration and directly reused at least ten times without a significant loss of activity. The key intermediate of adapalene, 2-(1-adamantyl)-4-bromophenol, could be produced by means of this waste-free process.


2016 ◽  
Vol 49 (7) ◽  
pp. 668-672 ◽  
Author(s):  
Kota Yamazaki ◽  
Naomi Shibasaki-Kitakawa ◽  
Kazunori Nakashima ◽  
Toshikuni Yonemoto

2008 ◽  
Vol 25 (6) ◽  
pp. 1350-1354 ◽  
Author(s):  
Ji-Yeon Park ◽  
Deog-Keun Kim ◽  
Zhong-Ming Wang ◽  
Joon-Pyo Lee ◽  
Soon-Chul Park ◽  
...  

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