Effect of metal coil on product distribution of highly upgraded bio-oil produced by microwave-metal interaction pyrolysis of biomass

Author(s):  
N. Bashir ◽  
K. Hussain ◽  
Z. Hussain ◽  
M.Y. Naz ◽  
K.A. Ibrahim ◽  
...  
2020 ◽  
Vol 14 (2) ◽  
pp. 178-185 ◽  
Author(s):  
Shuangxia Yang ◽  
Xiaodong Zhang ◽  
Feixia Yang ◽  
Baofeng Zhao ◽  
Lei Chen ◽  
...  

The objective of this study is to catalytically upgrade fast pyrolysis vapors of sawdust using various Fe-based catalysts for producing phenolic-rich bio-oil by analytical pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS) technique. A variety of parameters, including support characteristic, calcination temperature, pyrolysis temperature, as well as the catalyst-to-biomass ratio during the pyrolysis process were evaluated for their effects on product distribution of bio-oil. GC-MS analysis showed that compared to Fe–Mg and Fe–Al catalysts, the developed Fe–Ca catalyst significantly promoted the formation of phenols and its derivatives. The phenolic concentration declined with increasing calcination temperature and pyrolysis temperature, while increased monotonically along with increasing catalyst-to-biomass ratio. The phenolics concentration was high upto 81% (peak area) under optimum conditions of calcination temperature of 500 °C, pyrolysis temperature of 600 °C and catalyst-to-biomass ratio of 10. At higher catalyst-to-biomass ratio of 20, phenolics (88.03% in peak area) and hydrocarbons (including 7.86% of aromatics and 4.1% aliphatics) were the only two components that can be detected, with all the acids, aldehydes and ketones completely eliminated. This indicated the excellent capability of developed Fe–Ca catalyst in promoting the decomposition of lignin in biomass to generate phenolic compounds and meanwhile inhibiting the devolatilization of holocellulose.


2018 ◽  
Vol 15 (12) ◽  
pp. 758-765 ◽  
Author(s):  
K. Hussain ◽  
N. Bashir ◽  
Z. Hussain ◽  
M. Y. Naz ◽  
S. A. Sulaiman ◽  
...  

2013 ◽  
Vol 14 (2) ◽  
Author(s):  
Noor Fachrizal

Biomass such as agriculture waste and urban waste are enormous potency as energy resources instead of enviromental problem. organic waste can be converted into energy in the form of liquid fuel, solid, and syngas by using of pyrolysis technique. Pyrolysis process can yield higher liquid form when the process can be drifted into fast and flash response. It can be solved by using microwave heating method. This research is started from developing an experimentation laboratory apparatus of microwave-assisted pyrolysis of biomass energy conversion system, and conducting preliminary experiments for gaining the proof that this method can be established for driving the process properly and safely. Modifying commercial oven into laboratory apparatus has been done, it works safely, and initial experiments have been carried out, process yields bio-oil and charcoal shortly, several parameters are achieved. Some further experiments are still needed for more detail parameters. Theresults may be used to design small-scale continuous model of productionsystem, which then can be developed into large-scale model that applicable for comercial use.


2021 ◽  
Vol 121 ◽  
pp. 255-264
Author(s):  
Honggang Fan ◽  
Jing Gu ◽  
Yazhuo Wang ◽  
Haoran Yuan ◽  
Yong Chen ◽  
...  

2021 ◽  
Vol 341 ◽  
pp. 125874
Author(s):  
Nichaboon Chaihad ◽  
Aisikaer Anniwaer ◽  
Aghietyas Choirun Az Zahra ◽  
Yutaka Kasai ◽  
Prasert Reubroycharoen ◽  
...  

2012 ◽  
Vol 26 (5) ◽  
pp. 2962-2967 ◽  
Author(s):  
Chih-Chiang Chang ◽  
Seng-Rung Wu ◽  
Chi-Cheng Lin ◽  
Hou-Peng Wan ◽  
Hom-Ti Lee

RSC Advances ◽  
2021 ◽  
Vol 11 (43) ◽  
pp. 26763-26772
Author(s):  
Jian Yang ◽  
Chen Hong ◽  
Yi Xing ◽  
Zixuan Zheng ◽  
Zaixing Li ◽  
...  

In this study, the antibiotic residue was used as a raw material to catalyze hydrothermal liquefaction (HTL) in an ethanol–water system to prepare bio-oil.


2017 ◽  
Author(s):  
Mohammad Nurul Islam ◽  
Mohamed Hairol Md Ali ◽  
Miftah Haziq

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