scholarly journals Ordinary Portland Cement composition for the optimization of the synergies of supplementary cementitious materials of ternary binders in hydration processes

2018 ◽  
Vol 89 ◽  
pp. 238-250 ◽  
Author(s):  
Á. Fernández ◽  
J.L. García Calvo ◽  
M.C. Alonso
Keyword(s):  
Portland Cement ◽  
Ordinary Portland Cement ◽  
Cementitious Materials ◽  
Supplementary Cementitious Materials

scholarly journals A Review of the Mechanical Properties and Durability of Ecological Concretes in a Cold Climate in Comparison to Standard Ordinary Portland Cement-Based Concrete

Materials ◽  
2020 ◽  
Vol 13 (16) ◽  
pp. 3467
Author(s):  
Ankit Kothari ◽  
Karin Habermehl-Cwirzen ◽  
Hans Hedlund ◽  
Andrzej Cwirzen
Keyword(s):  
Carbon Dioxide ◽  
Portland Cement ◽  
Ordinary Portland Cement ◽  
Cementitious Materials ◽  
Cold Climate ◽  
Supplementary Cementitious Materials ◽  
Short Exposure ◽  
Chemical Admixtures ◽  
Composite Cements ◽  
Alkali Activated

Most of the currently used concretes are based on ordinary Portland cement (OPC) which results in a high carbon dioxide footprint and thus has a negative environmental impact. Replacing OPCs, partially or fully by ecological binders, i.e., supplementary cementitious materials (SCMs) or alternative binders, aims to decrease the carbon dioxide footprint. Both solutions introduced a number of technological problems, including their performance, when exposed to low, subfreezing temperatures during casting operations and the hardening stage. This review indicates that the present knowledge enables the production of OPC-based concretes at temperatures as low as −10 °C, without the need of any additional measures such as, e.g., heating. Conversely, composite cements containing SCMs or alkali-activated binders (AACs) showed mixed performances, ranging from inferior to superior in comparison with OPC. Most concretes based on composite cements require pre/post heat curing or only a short exposure to sub-zero temperatures. At the same time, certain alkali-activated systems performed very well even at −20 °C without the need for additional curing. Chemical admixtures developed for OPC do not always perform well in other binder systems. This review showed that there is only a limited knowledge on how chemical admixtures work in ecological concretes at low temperatures and how to accelerate the hydration rate of composite cements containing high amounts of SCMs or AACs, when these are cured at subfreezing temperatures.

scholarly journals Synthesis and Characterization of a Hybrid Cement Based on Fly Ash, Metakaolin and Portland Cement Clinker

Materials ◽  
2020 ◽  
Vol 13 (5) ◽  
pp. 1084 ◽  
Author(s):  
Adriagni C. Barboza-Chavez ◽  
Lauren Y. Gómez-Zamorano ◽  
Jorge L. Acevedo-Dávila
Keyword(s):  
Fly Ash ◽  
Portland Cement ◽  
Ordinary Portland Cement ◽  
Cementitious Materials ◽  
Cement Industry ◽  
Supplementary Cementitious Materials ◽  
Cement Clinker ◽  
Dense Matrix ◽  
X Ray ◽  
Reduction Of Co2

Hybrid cement has become one of the most viable options in the reduction of CO2 emissions to the environment that are generated by the cement industry. This could be explained by the reduction of the content of clinker in the final mixture and substitution of the remaining percentage with supplementary cementitious materials with the help of an alkaline activation. Following that, properties that are provided by an Ordinary Portland Cement and of a geopolymer are mixed in this type of hybrid material and could be achieved at room temperature. Thereafter, the main objective of this research was to synthesize hybrid cements reducing the clinker content of Portland Cement up to 20% and use metakaolin and fly ash as supplementary cementitious materials in different proportions. The mixtures were alkaline activated with a mixture of sodium silicate and sodium hydroxide, calculating the amounts according to the percentage of Na2O that is present in each of the activators. The samples were then characterized using Compressive strength, X-ray diffraction, Fourier Transform Infrared Spectroscopy, and Scanning Electron Microscopy with energy-dispersive X-ray spectroscopy. The results indicated that the hybrid cements have similar mechanical properties than an Ordinary Portland Cement, and they resulted in a dense matrix of hydration products similar to those that are generated by cements and geopolymers.

Evaluation of strength of concrete on different initial exposure condition

2020 ◽  
Vol 13 ◽  
Author(s):  
Sri Ram Krishna Mishra ◽  
Pradeep Kumar Ghosh ◽  
Manoj Kulshreshtha
Keyword(s):  
Portland Cement ◽  
High Strength ◽  
Cementitious Materials ◽  
General Purpose ◽  
Supplementary Cementitious Materials ◽  
Exposure Condition ◽  
Portland Cement Concrete ◽  
Initial Exposure ◽  
Skilled Manpower ◽  
Standard Practices

Background: The previous studies have focused curing effect of mainly on high strength concrete, where strict supervision is maintained. This study is based upon general purpose concreting work for commercial and residential construction in absence of skilled manpower and supervision. Objective: The objective of this study is to establish a thumb rule to provide 7 days initial curing for maintaining quality for unsupervised concreting irrelevant to type of cement and grading. Methods: In this study concrete samples made with locally available commercial cements were cured for various initial exposure. Results: The results shows that concrete cured after a gap of 4 days from the time of de-moulding have given lowest strength as compared to concrete cured in standard practices i.e. where proper curing protocol had been followed. Conclusion: Initial curing is most important aspect of gaining desired strength. The findings after this study shows that curing affects the strength of concrete in variable grading. Initial curing has great importance for concrete with all types of Portland cement. Concrete with supplementary cementitious materials gives lowest strength initially but results higher strength after 28 days as compared to Portland cement.

scholarly journals Special Issue: Supplementary Cementitious Materials in Concrete, Part I

Materials ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2291
Author(s):  
Alessandro P. Fantilli ◽  
Daria Jóźwiak-Niedźwiedzka
Keyword(s):  
Environmental Impact ◽  
Portland Cement ◽  
Building Materials ◽  
Cementitious Materials ◽  
Supplementary Cementitious Materials ◽  
Special Issue ◽  
Cement Production ◽  
Concrete Part

The environmental impact of the Portland cement production and the large use of cement-based building materials is a growing problem [...]

Research Progress on the Hydration of Portland Cement with Calcined Clay and Limestone

2021 ◽  
Vol 1036 ◽  
pp. 240-246
Author(s):  
Jin Tang ◽  
Su Hua Ma ◽  
Wei Feng Li ◽  
Hui Yang ◽  
Xiao Dong Shen
Keyword(s):  
Mechanical Properties ◽  
Portland Cement ◽  
Cementitious Materials ◽  
Supplementary Cementitious Materials ◽  
Research Progress ◽  
Hydration Reaction ◽  
Hydration Products ◽  
Early Hydration ◽  
Calcined Clay ◽  
Dense Microstructure

The use of calcined clay and limestone as supplementary cementitious materials, can have a certain influence on the hydration of Portland cement. This paper reviewed the influence of limestone and calcined clay and the mixture of limestone and calcined clay on the hydration of cement. Both limestone and calcined clay accelerate the hydration reaction in the early hydration age and enhance the properties of cement. Limestone reacts with C3A to form carboaluminate, which indirectly stabilized the presence of ettringite, while calcined clay consumed portlandite to form C-(A)-S-H gel, additional hydration products promote the densification of pore structure and increase the mechanical properties. The synergistic effect of calcined clay and limestone stabilize the existence of ettringite and stimulate the further formation of carboaluminate, as well as the C-(A)-S-H gel, contributed to a dense microstructure.

scholarly journals The Potentials of Iron and Steel Slags as Supplementary Cementitious Materials in the Nigerian Construction Industry: A Review

2018 ◽  
Vol 2 (2) ◽  
pp. 208-218
Author(s):  
O. R. Ogirigbo ◽  
J. O. Ukpata ◽  
I. Inerhunwa
Keyword(s):  
Portland Cement ◽  
Construction Industry ◽  
Waste Product ◽  
Steel Production ◽  
Cementitious Materials ◽  
Supplementary Cementitious Materials ◽  
Partial Replacement ◽  
Iron And Steel ◽  
Tropical Environments ◽  
Iron And Steel Production

Ground Granulated Blast Furnace Slag (GGBS) is a type of Supplementary Cementitious Material (SCM) that is currently being used extensively in the global construction industry. SCMs are cheaper than Portland cement, help to improve certain properties of concrete and also help to reduce the environmental footprint associated with the production of Portland cement. GGBS is readily available in most parts of the world as a waste product from iron and steel production. However, its use as a SCM in some countries has not been fully maximized. This is primarily because of lack of documented studies on the properties of GGBS that influences its suitability as a SCM, especially in tropical environments. This paper reviewed the use of GGBS as a SCM for the partial replacement of Portland cement, with particular emphasis on its potential use in tropical warm environments such as Nigeria and other similar countries.

Quaternary blended cement mortars containing wood ash, glass and slag powders

2021 ◽  
Author(s):  
Eethar Thanon Dawood ◽  
Marwa Saadi Mhmood
Keyword(s):  
Compressive Strength ◽  
Portland Cement ◽  
Ordinary Portland Cement ◽  
Glass Powder ◽  
Steel Slag ◽  
Wood Ash ◽  
Supplementary Cementitious Materials ◽  
Partial Replacement ◽  
Slag Powder ◽  
Steel Slag Powder

AbstractA quaternary supplementary cementitious materials as partial replacement of ordinary Portland cement decreases CO2 emission. This paper has investigated the properties of mortars made from different quaternary blends of wood ash, steel slag powder and glass powder with ordinary Portland cement at different replacement levels of 0, 24, 25, and 30% by weight of the binder. The blended mortar mixtures tested for flow, compressive strength and density. The results showed that the flow of mortars is decreased with the combined use of steel slag powder, glass powder, and wood ash compared with control mix. Compressive strength reduced with the combination of steel slag powder, glass powder and wood ash but this reduction effects is acceptable especially at 24% replacement contain super-plasticizer compared with the ecological benefit.

Performance of Impure Calcined Clay as a Pozzolan in Concrete

2020 ◽  
pp. 036119812095314
Author(s):  
Khashayar Jafari ◽  
Farshad Rajabipour
Keyword(s):  
Portland Cement ◽  
Drying Shrinkage ◽  
Cementitious Materials ◽  
Supplementary Cementitious Materials ◽  
Strength Development ◽  
Natural Pozzolan ◽  
Quartz Content ◽  
Calcined Clay ◽  
Air Content ◽  
Sand And Gravel

Supplementary cementitious materials (SCMs) are natural or industrial by-product materials which are used to improve the performance, durability, and sustainability of concrete mixtures. Motivated by the recent reports on shortage of conventional SCMs, impure calcined clays (CCs) are receiving attention as abundant alternative pozzolans for concrete. In this study, a clay slurry resulting from washing aggregates in a commercial sand and gravel pit was investigated. This source clay was dried and calcined, and the properties and pozzolanic performance of the resulting CC was evaluated. It was observed that despite having a large (>50%wt.) inert quartz content, the CC met all ASTM C618-19 (AASHTO M295) requirements for natural pozzolan. A pavement-grade concrete mixture containing 20%CC as a cement replacement (by weight) produced desired workability and fresh and hardened air content. Strength development was slightly below the control. The use of CC improved the durability of concrete with respect to chloride penetration, alkali–silica reaction, and drying shrinkage in comparison with a control (100% Portland cement) mixture. In addition, ternary limestone-calcined clay–cement and slag-calcined clay–cement mortar mixtures showed excellent strength development while replacing nearly 50% of the Portland cement.

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