Effect of W/B ratios on pozzolanic reaction of biomass ashes in Portland cement matrix

2012 ◽  
Vol 34 (1) ◽  
pp. 94-100 ◽  
Author(s):  
V. Sata ◽  
J. Tangpagasit ◽  
C. Jaturapitakkul ◽  
P. Chindaprasirt
Keyword(s):  
Portland Cement ◽  
Pozzolanic Reaction ◽  
Cement Matrix ◽  
Biomass Ashes

scholarly journals Effect of nano-silica on Portland cement matrix

2019 ◽  
Vol 12 (6) ◽  
pp. 1383-1389 ◽  
Author(s):  
T. M. MENDES ◽  
W. L. REPETTE
Keyword(s):  
Portland Cement ◽  
Size Distribution ◽  
Mechanical Performance ◽  
Current Trend ◽  
Pozzolanic Reaction ◽  
High Specific Surface Area ◽  
Nano Particles ◽  
Cement Matrix ◽  
Nano Silica ◽  
Main Effects

Abstract The use of nano-particles is a current trend that may play an important role for improving the mechanical performance of Portland cement. The aim of this study is to evaluate the effect of nano-silica on Portland cement matrix. The particle size distribution of Portland cement matrix was modified by the incorporation of 11, 6.2, 3.1, 1.7, 0.85 and 0.42 wt.% of nano-silica. The water demand and the consumption of dispersant were adjusted, and the rheological properties of suspensions were analyzed through rotational rheometry. The mechanical performance of studied mixtures was evaluated by the compressive strength. The pore size distribution was measured by mercury intrusion porosimetry (MIP), and the hydration was analyzed through X-ray diffractometry. The rheological behavior presented a considerable changed, as a consequence of high specific surface area of nano-particles. The optimum content of nano-silica, or the smaller quantity of nano-particles, that leads to the maximum strength gain, varied according to the water to solids ratio. An increasing on the hydration and a pore refinement were obtained due to the use of silica nanoparticles. The particle’s packing and the pozzolanic reaction were the two main effects of nano-silica on the microstructure of Portland cement matrix.

Mechanism of Cement Paste with Different Particle Sizes of Bottom Ash as Partial Replacement in Portland Cement

2017 ◽  
Vol 68 (10) ◽  
pp. 2367-2372 ◽  
Author(s):  
Ng Hooi Jun ◽  
Mirabela Georgiana Minciuna ◽  
Mohd Mustafa Al Bakri Abdullah ◽  
Tan Soo Jin ◽  
Andrei Victor Sandu ◽  
...  
Keyword(s):  
Portland Cement ◽  
Construction Material ◽  
Bottom Ash ◽  
High Volume ◽  
Cement Composite ◽  
Pozzolanic Reaction ◽  
High Specific Surface Area ◽  
Partial Replacement ◽  
Natural Aggregates ◽  
Pozzolanic Properties

Manufacturing of Portland cement consists of high volume of natural aggregates which depleted rapidly in today construction field. New substitutable material such as bottom ash replace and target for comparable properties with hydraulic or pozzolanic properties as Portland cement. This study investigates the replacement of different sizes of bottom ash into Portland cement by reducing the content of Portland cement and examined the mechanism between bottom ash (BA) and Portland cement. A cement composite developed by 10% replacement with 1, 7, 14, and 28 days of curing and exhibited excellent mechanical strength on day 28 (34.23 MPa) with 63 mm BA. The porous structure of BA results in lower density as the fineness particles size contains high specific surface area and consume high quantity of water. The morphology, mineralogical, and ternary phase analysis showed that pozzolanic reaction of bottom ash does not alter but complements and integrates the cement hydration process which facilitate effectively the potential of bottom ash to act as construction material.

Low Cement/High Fly Ash Concretes: Their Properties and Response to Chemical Admixtures

1987 ◽  
Vol 113 ◽  
Author(s):  
V. H. Dodson
Keyword(s):  
Fly Ash ◽  
Portland Cement ◽  
Calcium Hydroxide ◽  
Pozzolanic Reaction ◽  
Portland Cement Concrete ◽  
Cement Concrete ◽  
Fly Ashes ◽  
Chemical Admixtures ◽  
Reaction With Water

ABSTRACTIn practice, the amount of fly ash added to portland cement concrete varies depending upon the desired end properties of the concrete. Generally, when a given portland cement concrete is redesigned to include fly ash, between 10 and 50% of the cement is replaced by a volume of fly ash equal to that of the cement. Sometimes as much as twice the volume of the cement replaced, although 45.4 kg (100 lbs) of cement will only produce enough calcium hydroxide during its reaction with water to react with about 9 kg (20 lbs) of a typical fly ash. The combination of large amounts of certain fly ashes with small amounts of portland cement in concrete has been found to produce surprisingly high compressive strengths, which cannot be accounted for by the conventional “pozzolanic reaction”. Ratios of cement to fly ash as high as 1:15 by weight can produce compressive strengths of 20.7 MPa (3,000 psi) at I day and over 41.4 MPa (6,000 psi) at 28 days. Methods of identifying these “hyperactive” fly ashes along with some of the startling results, with and without chemical admixtures are described.

scholarly journals INFLUENCE OF LIGHTWEIGHT FILLERS ON THE PERFORMANCE OF CEMENT-BASED SKIM COAT

2020 ◽  
Vol 12 (1) ◽  
pp. 5-11
Author(s):  
MARCIN KUPIŃSKI ◽  
KAROLINA STOBIENIECKA ◽  
KAROL SKOWERA
Keyword(s):  
Thermal Conductivity ◽  
Thermal Conductivity Coefficient ◽  
Pozzolanic Reaction ◽  
Vapor Condensation ◽  
Cement Matrix ◽  
Capillary Absorption ◽  
Mold Growth ◽  
Expanded Perlite ◽  
Water Vapor Condensation ◽  
Effective Additive

Lightweight fillers are used in dry-mixed building mortars in order to improve thermal insulation properties, yield, and workability. In the case of thin layer products, used as a finishing layer, reduced thermal conductivity coefficient enables to restrain of water vapor condensation on walls – which inhibits mold growth. The aim of the study was to determine the influence of 4 types of lightweight fillers on the performance of cement-based skim coat – with emphasis on the economic aspect. Formulas reflecting typical commercial products were used. The dosage of different components -such as expanded perlite, glass and polymeric bubbles or expanded glass – was optimized for sufficient yield and workability, keeping the constant price of 1 kg of the final product. Mechanical parameters, capillary absorption coefficient, and thermal conductivity coefficient were determined. Observations by Scanning Electron Microscope revealed poor incorporation of polymer microspheres in the cement matrix, leading to loss of mechanical strength. With the addition of expanded glass, an increase of flexural and compressive strength thanks to the pozzolanic reaction was observed. Glass bubbles were found the most effective additive.

scholarly journals Properties of cement composites based on limestone depending on their granulometric composition

Vestnik MGSU ◽  
2020 ◽  
pp. 999-1006
Author(s):  
Svetlana V. Samchenko ◽  
Olga V. Alexandrova ◽  
Anton Yu. Gurkin
Keyword(s):  
Composite Materials ◽  
Portland Cement ◽  
Granulometric Composition ◽  
Coarse Grained ◽  
Cement Matrix ◽  
Cement Composites ◽  
Construction Costs ◽  
Initial Strength ◽  
Fine Grained ◽  
Additional Formation

Introduction. The use of limestone in cement compositions as an additional cementing agent solves both environmental and economic problems, namely, reduction of construction costs. In this regard, the study of the properties of the granulometric composition and volumetric content of cement composites, containing limestone, becomes increasingly important. The mission of this research is to optimize the properties of composite materials containing Portland cement and limestone by changing the granulometric composition of flour limestone. Materials and methods. Limestone, having three different Blaine milling fineness values of 250, 300 and 450 m2/kg, was used; its content reached 10, 15, 25 and 35 %. Cement and sand mortars were applied for testing purposes. The influence of the granulometric composition of limestone on the workability and compressive strength of composite cement was determined. Results. The effect of limestone on the limit shear stress becomes more pronounced when the amount of limestone increases to 25 and 35 %. This is most noticeable for limestone with a high content of fine fractions of 5–20 µm. The use of finely milled limestone increases the initial strength of the composite material. By adding 10 and 15 % of such limestone we can increase the strength by 16–20 %, and supplementary 25–35 % of limestone increases strength by 5–8 %. Strength enhancement is due to the reactivity of limestone and formation of calcium hydrocarbon aluminate 3CaO∙Al2O3∙СаСО3∙12H2O, which promotes formation of the crystal framework of the cement matrix. Additional formation of crystalline hydrates in the initial coagulation structure deteriorates the mortar workability, but increases its strength. Conclusions. The use of coarse-grained limestone significantly improves mortar workability, while the use of fine-grained limestone increases its content without reducing its strength. The granulometric composition of ground limestone shall be as close as possible to the granulometric composition of cement for the properties of composite materials containing Portland cement and limestone to be optimized.

scholarly journals AN EFFECTIVE WAY TO RECYCLE 3D PRINTING CONCRETE SCRAP

2021 ◽  
Vol 4 (2) ◽  
pp. 12-18
Author(s):  
D.A. Tolypin ◽  
N. Tolypina
Keyword(s):  
Compressive Strength ◽  
3D Printing ◽  
Portland Cement ◽  
Quartz Sand ◽  
Raw Materials ◽  
Electricity Consumption ◽  
Cement Matrix ◽  
Fine Aggregate ◽  
Fine Grained ◽  
Control Samples

the article proposes a rational method for processing 3D printing concrete scrap using vibration equipment, which allows obtaining a multicomponent building material with minimal electricity consumption. As a crite-rion for the degree of grinding of concrete scrap, it is proposed to use the specific surface area of the finely dispersed part of concrete scrap, which should correspond to 400-500 m2/kg. The possibility of reusing the resulting product instead of the traditional fine aggregate of quartz sand is shown. It was found that the con-crete scrap without the addition of Portland cement hardens, reaching up to 48% of the compressive strength of the control samples by 28 days. When 10% of the binder CEM I 42.5 N was added to the concrete scrap processing product, the compressive strength of fine-grained concrete increased by 106.6%, and 20% of Portland cement - by 112.2 %, compared to the strength of control samples of a similar composition on tra-ditional quartz sand after 28 days of hardening. It is noted that this is primarily due to the weak contact zone of quartz sand and the cement matrix of concrete. The use of the product of processing concrete scrap al-lows obtaining building composites based on it with the complete exclusion of natural raw materials

Pozzolanic reaction in portland cement, silica fume, and fly ash mixtures

1997 ◽  
Vol 24 (5) ◽  
pp. 754-760 ◽  
Author(s):  
J K Weng ◽  
B W Langan ◽  
M A Ward
Keyword(s):  
Fly Ash ◽  
Portland Cement ◽  
Silica Fume ◽  
Pozzolanic Reaction

scholarly journals Dielectric Dissipation of Fibre-modified Hydraulic Concretes

1998 ◽  
Vol 7 (6) ◽  
pp. 096369359800700
Author(s):  
J.B. Hernández ◽  
F.A. Aguirre ◽  
J.L. Martínez ◽  
C. E. Caballero ◽  
L. Pérez-Rea ◽  
...  
Keyword(s):  
Portland Cement ◽  
Dielectric Behavior ◽  
Hydration Process ◽  
Cement Matrix ◽  
Polypropylene Fibers ◽  
Polypropylene Fibres ◽  
Polar Surfaces ◽  
Definitive Role

Dielectric behavior of Portland cement-based concretes, modified with either polyester or polypropylene fibers was studied by measuring their dissipation factors at different frequencies. The results show that the fibers with non-polar surfaces (polyester) do not influence the hydration process of the cement matrix, whereas polypropylene fibres, with polar surfaces, have a definitive role on the curing properties of the composites.

Bonding Calcium Chloride and Calcium Nitrate into Stable Hydration Portland Cement Products: Stability Conditions of Calcium Hydrochloraluminates and Calcium Hydronitroaluminates

2018 ◽  
Vol 36 ◽  
pp. 69-73 ◽  
Author(s):  
Andrii A. Plugin ◽  
Raisa F. Runova
Keyword(s):  
Portland Cement ◽  
Calcium Chloride ◽  
Thermodynamic Analysis ◽  
Calcium Nitrate ◽  
Cement Matrix ◽  
Stability Conditions ◽  
Decomposition Reactions ◽  
Tricalcium Aluminate

A thermodynamic analysis of the reactions of calcium chloride and calcium nitrate with tricalcium aluminate when used as a hardening accelerator for portland cement, as well as decomposition reactions of calcium hydrochloraluminate (CHChA) and calcium hydronitroalyuminate (CHNA) formed during the hardening was performed. The conditions of stable existence of CHChA and CHNA in the cement matrix were established.

Soundness in Mortars of Portland Cement with Substitutions Using Cactus (Opuntia ficus-indica) and Corn Starch

2018 ◽  
Vol 789 ◽  
pp. 150-154
Author(s):  
Victor Hugo Blancas-Herrera ◽  
Jorge Alberto Pacheco-Segovia ◽  
Wilfrido Martínez-Molina ◽  
Hugo Luis Chávez García ◽  
Mauricio Arreola-Sanchez ◽  
...  
Keyword(s):  
Portland Cement ◽  
Corn Starch ◽  
Weight Ratio ◽  
Physical And Mechanical Properties ◽  
Ultrasonic Pulse Velocity ◽  
Ultrasonic Pulse ◽  
Pulse Velocity ◽  
Electric Resistivity ◽  
Cement Matrix ◽  
Opuntia Ficus Indica

The use of dehydrated fibres of cactus, Opuntia ficus-indica (FN), and starch (corn starch,Zea Mays (MZ)) as partial substitutes for the total mass of Portland Cement (CP) in the making ofmortar, aims at modifying its physical and mechanical properties, reducing the amount of cementand the CO2 emission. Four mixtures of CP mortar were designed incorporating a superplasticizeradditive with a water/cement weight ratio of 0.68. To compare the results, there was a controlmortar; two mixtures with partial substitutions using fibres of FN, 0.5 and 1.5% (in weight of CP)respectively; and a substituted mixture with 2% of corn starch plus 0.5% of cactus fibre (MZ - FN).The test age was 180 days. The specimens were subjected to an accelerated attack of sodiumsulphate, quantifying the electric resistivity (ER) and the ultrasonic pulse velocity (UPV). Theresults indicate that the substitution of the materials, remarkably densify the cement matrix, whichresults in the improvement of the physical properties and the durability.

Sign in / Sign up

Export Citation Format

Share Document