Improved reversible redox cycles on MTiOx (M = Fe, Co, Ni, and Cu) particles afforded by rapid and stable oxygen carrier capacity for use in chemical looping combustion of methane

2017 ◽  
Vol 309 ◽  
pp. 617-627 ◽  
Author(s):  
Byeong Sub Kwak ◽  
No-Kuk Park ◽  
Si Ok Ryu ◽  
Jeom-In Baek ◽  
Ho-Jung Ryu ◽  
...  
Keyword(s):  
Oxygen Carrier ◽  
Chemical Looping Combustion ◽  
Chemical Looping ◽  
Redox Cycles ◽  
Reversible Redox ◽  
Stable Oxygen

scholarly journals Performance and Stability of Metal (Co, Mn, Cu)-Promoted La2O2SO4 Oxygen Carrier for Chemical Looping Combustion of Methane

Catalysts ◽  
2019 ◽  
Vol 9 (2) ◽  
pp. 147 ◽  
Author(s):  
Stefano Cimino ◽  
Gabriella Mancino ◽  
Luciana Lisi
Keyword(s):  
Oxygen Carrier ◽  
Combustion Process ◽  
Cost Effective ◽  
Oxygen Storage Capacity ◽  
Oxygen Storage ◽  
Chemical Looping Combustion ◽  
Infrared Spectrometry ◽  
Chemical Looping ◽  
Reversible Redox ◽  
Temperature Programmed

Oxygen carrier materials based on La2O2SO4 and promoted by small amounts (1% wt.) of transition metals, namely Co, Mn and Cu, have been synthesized and characterized by means of X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET), Temperature-programmed reduction/oxidation (TPR/TPO) and thermogravimetry-mass-Fourier transform infrared spectrometry (TG-MS-FTIR) experiments under alternating feeds in order to investigate their potential use for the Chemical Looping Combustion process using either hydrogen or methane as the fuel. The chemical looping reactivity is based on the reversible redox cycle of sulfur from S6+ in La2O2SO4 to S2− in La2O2S and entails a large oxygen storage capacity, but it generally requires high temperatures to proceed, challenging material stability and durability. Herein we demonstrate a remarkable improvement of lattice oxygen availability and activity during the reduction step obtained by cost-effective metal doping in the order Co > Mn > Cu. Notably, the addition of Co or Mn has shown a significant beneficial effect to prevent the decomposition of the oxysulfate releasing SO2, which is identified as the main cause of progressive deactivation for the unpromoted La2O2SO4.

Reactivity of a NiO/Al2O3 oxygen carrier prepared by impregnation for chemical-looping combustion

Fuel ◽  
2010 ◽  
Vol 89 (11) ◽  
pp. 3399-3409 ◽  
Author(s):  
Cristina Dueso ◽  
Alberto Abad ◽  
Francisco García-Labiano ◽  
Luis F. de Diego ◽  
Pilar Gayán ◽  
...  
Keyword(s):  
Oxygen Carrier ◽  
Chemical Looping Combustion ◽  
Chemical Looping

scholarly journals Development of CuFeMnAlO4+δ oxygen carrier with high attrition resistance and 50-kWth methane/air chemical looping combustion tests

2021 ◽  
Vol 286 ◽  
pp. 116507
Author(s):  
Ranjani Siriwardane ◽  
Jarrett Riley ◽  
William Benincosa ◽  
Samuel Bayham ◽  
Michael Bobek ◽  
...  
Keyword(s):  
Oxygen Carrier ◽  
Chemical Looping Combustion ◽  
Chemical Looping ◽  
Combustion Tests ◽  
Attrition Resistance

scholarly journals Effect of the oxygen carrier ilmenite on NOX formation in chemical-looping combustion

2021 ◽  
Vol 222 ◽  
pp. 106962
Author(s):  
Stefan Mayrhuber ◽  
Fredrik Normann ◽  
Duygu Yilmaz ◽  
Henrik Leion
Keyword(s):  
Oxygen Carrier ◽  
Chemical Looping Combustion ◽  
Chemical Looping ◽  
Nox Formation

scholarly journals Characteristic Study of Briquette Cyanobacteria as Fuel in Chemical Looping Combustion with Hematite as Oxygen Carrier

2021 ◽  
Vol 11 (10) ◽  
pp. 4388
Author(s):  
Haifeng Zhang ◽  
Laihong Shen ◽  
Huijun Ge ◽  
Hongcun Bai
Keyword(s):  
Large Scale ◽  
Oxygen Carrier ◽  
Compressive Load ◽  
Phosphorus Recovery ◽  
Chemical Looping Combustion ◽  
Chemical Looping ◽  
Carbon Conversion ◽  
Nitrogen And Phosphorus ◽  
Liquid Products ◽  
Lower Temperature

Due to the more and more serious cyanobacteria bloom problem, it is particularly urgent to find a technology suitable for large-scale disposal and the efficient recovery of abundant nitrogen and phosphorus resources in cyanobacteria. The combination of chemical looping combustion (CLC) and biomass densification technology is thought to be a promising utilization selection. Based on the experimental results, the mechanical strength and energy density of briquette cyanobacteria are evidently increased with the compressive load; whereas, 10% is the optimal moisture content in the densification process. A higher heating rate in TGA would result in the damage of the internal structure of the briquette cyanobacteria, which are conducive to the carbon conversion efficiency. The presence of a hematite oxygen carrier would enhance the carbon conversion and catalyzed crack liquid products. CO2 yield is increased 25 percent and CH4 yield is decreased 50 percent at 900 °C in the CLC process. In addition, the lower temperature and reduction atmosphere in CLC would result in a lower NO emission concentration. The reactivity and porous property of hematite OC in CLC also increased during 10 redox cycle experiments. The CLC process accelerates the generation of CaH2P2O7 and CaHPO4 in cyanobacteria ash, which is more conducive to phosphorus recovery.

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