Metal-organic frameworks for the adsorption of gaseous toluene under ambient temperature and pressure

2017 ◽  
Vol 307 ◽  
pp. 1116-1126 ◽  
Author(s):  
Kowsalya Vellingiri ◽  
Pawan Kumar ◽  
Akash Deep ◽  
Ki-Hyun Kim
Keyword(s):  
Ambient Temperature ◽  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Temperature And Pressure ◽  
Gaseous Toluene

Self-assembly of silver(i)-based high-energy metal–organic frameworks (HE-MOFs) at ambient temperature and pressure: synthesis, structure and superior explosive performance

2017 ◽  
Vol 53 (54) ◽  
pp. 7489-7492 ◽  
Author(s):  
Cheng Shen ◽  
Yang Liu ◽  
Zhong-qin Zhu ◽  
Yuan-gang Xu ◽  
Ming Lu
Keyword(s):  
Ambient Temperature ◽  
Self Assembly ◽  
Metal Organic Frameworks ◽  
High Energy ◽  
Assembly Strategy ◽  
Explosive Performance ◽  
Metal Organic ◽  
Pressure Synthesis ◽  
Temperature And Pressure

Two HE-MOFs, {Ag2(DNMAF)(H2O)2}n (1) and {Ag2(DNMAF)}n (2), were prepared using K2DNMAF in a mild self-assembly strategy.

scholarly journals Benchmark Study of Hydrogen Storage in Metal–Organic Frameworks under Temperature and Pressure Swing Conditions

2018 ◽  
Vol 3 (3) ◽  
pp. 748-754 ◽  
Author(s):  
Paula García-Holley ◽  
Benjamin Schweitzer ◽  
Timur Islamoglu ◽  
Yangyang Liu ◽  
Lu Lin ◽  
...  
Keyword(s):  
Hydrogen Storage ◽  
Metal Organic Frameworks ◽  
Benchmark Study ◽  
Metal Organic ◽  
Temperature And Pressure ◽  
Pressure Swing

scholarly journals Implementing Metal-Organic Frameworks for Natural Gas Storage

Crystals ◽  
2019 ◽  
Vol 9 (8) ◽  
pp. 406 ◽  
Author(s):  
Eyas Mahmoud ◽  
Labeeb Ali ◽  
Asmaa El Sayah ◽  
Sara Awni Alkhatib ◽  
Hend Abdulsalam ◽  
...  
Keyword(s):  
Natural Gas ◽  
Thermal Management ◽  
Active Sites ◽  
Storage Capacity ◽  
Metal Organic Frameworks ◽  
Department Of Energy ◽  
Working Capacity ◽  
Adsorbed Natural Gas ◽  
Metal Organic ◽  
Temperature And Pressure

Methane can be stored by metal-organic frameworks (MOFs). However, there remain challenges in the implementation of MOFs for adsorbed natural gas (ANG) systems. These challenges include thermal management, storage capacity losses due to MOF packing and densification, and natural gas impurities. In this review, we discuss discoveries about how MOFs can be designed to address these three challenges. For example, Fe(bdp) (bdp2− = 1,4-benzenedipyrazolate) was discovered to have intrinsic thermal management and released 41% less heat than HKUST-1 (HKUST = Hong Kong University of Science and Technology) during adsorption. Monolithic HKUST-1 was discovered to have a working capacity 259 cm3 (STP) cm−3 (STP = standard temperature and pressure equivalent volume of methane per volume of the adsorbent material: T = 273.15 K, P = 101.325 kPa), which is a 50% improvement over any other previously reported experimental value and virtually matches the 2012 Department of Energy (Department of Energy = DOE) target of 263 cm3 (STP) cm−3 after successful packing and densification. In the case of natural gas impurities, higher hydrocarbons and other molecules may poison or block active sites in MOFs, resulting in up to a 50% reduction of the deliverable energy. This reduction can be mitigated by pore engineering.

Flexible metal–organic frameworks as superior cathodes for rechargeable sodium-ion batteries

2015 ◽  
Vol 3 (32) ◽  
pp. 16590-16597 ◽  
Author(s):  
Ping Nie ◽  
Laifa Shen ◽  
Gang Pang ◽  
Yaoyao Zhu ◽  
Guiyin Xu ◽  
...  
Keyword(s):  
Ambient Temperature ◽  
Prussian Blue ◽  
Metal Organic Frameworks ◽  
Sodium Ion ◽  
Sodium Ion Batteries ◽  
Prussian Blue Analogues ◽  
Ion Storage ◽  
Metal Organic ◽  
Flexible Metal ◽  
Sodium Ion Storage

Flexible metal–organic frameworks composed of Prussian blue analogues on a highly conductive carbonfiber paper have been synthesized and utilized as attractive hosts for sodium ion storage at ambient temperature.

Hydrogen storage in Co-and Zn-based metal-organic frameworks at ambient temperature

2009 ◽  
Vol 34 (24) ◽  
pp. 9754-9759 ◽  
Author(s):  
Serhiy M. Luzan ◽  
Heejin Jung ◽  
Hyungphil Chun ◽  
A.V. Talyzin
Keyword(s):  
Hydrogen Storage ◽  
Ambient Temperature ◽  
Metal Organic Frameworks ◽  
Metal Organic

Metal Alkoxide Functionalization in Metal−Organic Frameworks for Enhanced Ambient-Temperature Hydrogen Storage

2010 ◽  
Vol 115 (5) ◽  
pp. 2066-2075 ◽  
Author(s):  
Rachel B. Getman ◽  
Jacob H. Miller ◽  
Kenneth Wang ◽  
Randall Q. Snurr
Keyword(s):  
Hydrogen Storage ◽  
Ambient Temperature ◽  
Metal Organic Frameworks ◽  
Metal Alkoxide ◽  
Metal Organic

Cobalt-Based 3D Metal-Organic Frameworks: Useful Candidates for Olefin Epoxidation at Ambient Temperature by H2O2

2013 ◽  
Vol 2013 (29) ◽  
pp. 5103-5109 ◽  
Author(s):  
Rupam Sen ◽  
Debraj Saha ◽  
Dasarath Mal ◽  
Paula Brandão ◽  
Zhi Lin
Keyword(s):  
Ambient Temperature ◽  
Metal Organic Frameworks ◽  
Olefin Epoxidation ◽  
Metal Organic

Stability of zeolitic imidazolate frameworks: effect of forced water intrusion and framework flexibility dynamics

RSC Advances ◽  
2015 ◽  
Vol 5 (109) ◽  
pp. 89498-89502 ◽  
Author(s):  
Yaroslav Grosu ◽  
Sandrine Gomes ◽  
Guillaume Renaudin ◽  
Jean-Pierre E. Grolier ◽  
Valentine Eroshenko ◽  
...  
Keyword(s):  
Synergistic Effect ◽  
Metal Organic Frameworks ◽  
Effect Of Temperature ◽  
Zeolitic Imidazolate Frameworks ◽  
Water Intrusion ◽  
Metal Organic ◽  
Temperature And Pressure

Synergistic effect of temperature and pressure upon forced water intrusion strongly affects metal–organic frameworks stability.

Sign in / Sign up

Export Citation Format

Share Document