Intrinsic properties and reactivities of mononuclear nonheme iron–oxygen complexes bearing the tetramethylcyclam ligand

2013 ◽  
Vol 257 (2) ◽  
pp. 381-393 ◽  
Author(s):  
Sam P. de Visser ◽  
Jan-Uwe Rohde ◽  
Yong-Min Lee ◽  
Jaeheung Cho ◽  
Wonwoo Nam
Keyword(s):  
Nonheme Iron ◽  
Intrinsic Properties ◽  
Oxygen Complexes

God's Being Is in Becoming: An Essay in Theological Idealism

2016 ◽  
Vol 8 (3) ◽  
pp. 145-157
Author(s):  
Hartmut Von Sass
Keyword(s):  
Intrinsic Properties

God’s being is becoming – the title is the thesis. The first section of this paper will be dedicated to the problem of radical historicity in sketching three dogmatic approaches dealing with the relation between God and history. After critically introducing the concept of relational – in contrast to intrinsic – properties in the second section I will apply a revised version of this concept theologically in integrating it into the architecture of Trinitarian thinking. Accordingly, and on that basis, the last section can address the ambivalent as well as precarious question in which sense God’s ultimate being is in real (be) coming.

Quantitative Conditions and Convergent Operations That Are Compatible With the Universe as a Persistent Generator of Successive Simulations

2016 ◽  
Vol 12 (1) ◽  
pp. 4178-4187
Author(s):  
Michael A Persinger ◽  
Stanley A Koren
Keyword(s):  
Structural Organization ◽  
Total Duration ◽  
Human Cognition ◽  
Intrinsic Properties ◽  
Basic Assumptions ◽  
Electron Orbit ◽  
Quantitative Analyses ◽  
Massive Information ◽  
The Universe

                The capacity for computer-like simulations to be generated by massive information processing from electron-spin potentials supports Bostrom’s hypothesis that matter and human cognition might reflect simulations. Quantitative analyses of the basic assumptions indicate the universe may display properties of a simulation where photons behave as pixels and gravitons control the structural organization. The Lorentz solution for the square of the light and entanglement velocities converges with the duration of a single electron orbit that ultimately defines properties of matter. The approximately one trillion potential states within the same space with respect to the final epoch of the universe indicate that a different simulation, each with intrinsic properties, has been and will be generated as a type of tractrix defined by ±2 to 3 days (total duration 5 to 6 days). It may define the causal limits within a simulation. Because of the intrinsic role of photons as the pixel unit, phenomena within which flux densities are enhanced, such as human cognition (particularly dreaming) and the cerebral regions associated with those functions, create the conditions for entanglement or excess correlations between contiguous simulations. The consistent quantitative convergence of operations indicates potential validity for this approach. The emergent solutions offer alternative explanations for the limits of predictions for multivariate phenomena that could be coupled to more distal simulations.

Fluorescence of BODIPY Dyes in Gas Phase at near Ambient Conditions

2020 ◽  
Author(s):  
Kseniya A. Mariewskaya ◽  
Denis Larkin ◽  
Yuri Samoilichenko ◽  
Vladimir Korshun ◽  
Alex Ustinov
Keyword(s):  
Gas Phase ◽  
Molecular Interactions ◽  
Atmospheric Pressure ◽  
Fluorescence Spectra ◽  
Visible Range ◽  
Intrinsic Properties ◽  
Ambient Conditions ◽  
Ideal Model ◽  
Molecular Fluorescence ◽  
Tesla Coil

Molecular fluorescence is a phenomenon that is usually observed in condensed phase. It is strongly affected by molecular interactions. The study of fluorescence spectra in the gas phase can provide a nearly-ideal model for the evaluation of intrinsic properties of the fluorophores. Unfortunately, most conventional fluorophores are not volatile enough to allow study of their fluorescence in the gas phase. Here we report very bright gas phase fluorescence of simple BODIPY dyes that can be readily observed at atmospheric pressure using conventional fluorescence instrumentation. To our knowledge, this is the first example of visible range gas phase fluorescence at near ambient conditions. Evaporation of the dye in vacuum allowed us to demonstrate organic molecular electroluminescence in gas discharge excited by electric field produced by a Tesla coil.

Biocomposites from Starch-based Biopolymer and Rape Fibers. Part I: Interfacial Analysis and Intrinsic Properties of Rape Fibers

2013 ◽  
Vol 17 (15) ◽  
pp. 1633-1640 ◽  
Author(s):  
Eva Espigule ◽  
Fabiola Vilaseca ◽  
Xavier Puigvert ◽  
Nour-Eddine Mansouri ◽  
Francesc-Xavier Espinach ◽  
...  
Keyword(s):  
Intrinsic Properties ◽  
Interfacial Analysis

Progress and Prospects in Translating Nanobiotechnology in Medical Theranostics

2020 ◽  
Vol 16 (5) ◽  
pp. 685-707 ◽  
Author(s):  
Amna Batool ◽  
Farid Menaa ◽  
Bushra Uzair ◽  
Barkat Ali Khan ◽  
Bouzid Menaa
Keyword(s):  
Biological Properties ◽  
Chemical Characteristics ◽  
Intrinsic Properties ◽  
The Past ◽  
Profound Influence ◽  
Functionalized Nanomaterials ◽  
Physico Chemical ◽  
Properties Of Materials ◽  
Targeted Drug ◽  
And Performance

: The pace at which nanotheranostic technology for human disease is evolving has accelerated exponentially over the past five years. Nanotechnology is committed to utilizing the intrinsic properties of materials and structures at submicroscopic-scale measures. Indeed, there is generally a profound influence of reducing physical dimensions of particulates and devices on their physico-chemical characteristics, biological properties, and performance. The exploration of nature’s components to work effectively as nanoscaffolds or nanodevices represents a tremendous and growing interest in medicine for various applications (e.g., biosensing, tunable control and targeted drug release, tissue engineering). Several nanotheranostic approaches (i.e., diagnostic plus therapeutic using nanoscale) conferring unique features are constantly progressing and overcoming all the limitations of conventional medicines including specificity, efficacy, solubility, sensitivity, biodegradability, biocompatibility, stability, interactions at subcellular levels. : This review introduces two major aspects of nanotechnology as an innovative and challenging theranostic strategy or solution: (i) the most intriguing (bare and functionalized) nanomaterials with their respective advantages and drawbacks; (ii) the current and promising multifunctional “smart” nanodevices.

Chitosan Nanoparticles: An Approbative System for the Delivery of Herbal Bioactives

2020 ◽  
Vol 10 ◽  
Author(s):  
Sapna Saini ◽  
Sanju Nanda ◽  
Anju Dhiman
Keyword(s):  
Drug Delivery ◽  
Drug Delivery Systems ◽  
State Of The Art ◽  
Chitosan Nanoparticles ◽  
Delivery Systems ◽  
Intrinsic Properties ◽  
Amino Groups ◽  
Suitable Candidate ◽  
Film Forming ◽  
Novel Drug

: Chitosan, a natural biodegradable polymer obtained from deacetylation of chitin, has been used as an approbative macromolecule for the development of various novel drug delivery systems. It is one of the most favorable biodegradable carriers for nanoparticulate drug delivery due to its intrinsic properties, such as biocompatibility, biodegradability, non-toxicity, availability of free reactive amino groups, and ease of chemical modification into different active derivatives. Furthermore, interesting physical properties (film-forming, gelling and thickening) make it a suitable candidate for formulations, such as films, microcapsules, beads, nanoparticles, nanofibres, nanogel and so on. Researchers have reported that chitosan nanoparticles act as a promising vehicle for herbal actives as they provide a superior alternative to traditional carriers and improve pharmaceutical efficiency. As no review of chitosan nanoparticles encapsulating herbal extracts and bioactives has been published till date, a maiden effort has been made to collate and review the use of chitosan nanoparticles for the entrapment of phytoconstituents to yield stable, efficient and safe drug delivery systems. Additionally, the paper presents a comprehensive account of the state-of the-art in fabricating herbal chitosan nanoparticles and their current pharmacological status. A list of patents on chitosan nanoparticles of herbal actives has also been included. This review is intended to serve as a didactic discourse for the formulation scientists endeavoring to develop advanced delivery systems for herbal actives.

Theoretical Approaches to the Functions of Indefinite Pronouns

2017 ◽  
Author(s):  
Martin Haspelmath
Keyword(s):  
Semantic Features ◽  
Semantic Change ◽  
Intrinsic Properties ◽  
Theoretical Approaches ◽  
Mental Spaces ◽  
Logical Semantics ◽  
The Relationship ◽  
Indefinite Pronouns

This chapter focuses on various theoretical approaches to the semantic and syntactic functions of indefinite pronouns. It begins with a discussion of structuralist semantics, which suggests that language is a system whose parts must be defined and described on the basis of their place in the system and their relation to each other, rather than on the basis of their own intrinsic properties. It then considers some of the problems associated with structuralist semantics, including the unclear status of the semantic features; significant overlap of the functions of grammatical items in many areas, including indefinite pronouns; and structuralist semantics makes wrong predictions about semantic change. The chapter proceeds by analysing logical semantics and the issues raised by this approach, along with syntactic approaches, the theory of mental spaces, pragmatic scales and scale reversal. Finally, it explains the relationship between focusing and sentence accent.

Edwin Denby’s Objectivist Modernism and the New York School

2017 ◽  
Author(s):  
Andrea Harris
Keyword(s):  
New York ◽  
New York School ◽  
Intrinsic Properties ◽  
Dance History ◽  
Art And Politics ◽  
Objectivist Theory ◽  
Biographical Approach

Whereas chapter 2 examines the emergence of a social modernist theory of ballet in the 1930s, chapter 3 illustrates a new ballet modernism arising in the 1940s through the contributions of Edwin Denby. Denby’s primary innovation to American ballet theory was to reassign dance meaning from social or political themes to the intrinsic properties of the movement itself. This chapter takes a biographical approach to Denby’s criticism to situate this theoretical shift in ballet within the interdisciplinary New York School, in which he was extensively involved, and in which similar challenges to the relation of art and politics were being made by painters, photographers, and composers. This chapter demonstrates that Denby was the architect of a new objectivist theory of dance, which relocates the emergence of objectivism to a much earlier point in dance history, and in a different genre, than previously acknowledged. More than any other critic, Denby was responsible for connecting this objectivist theory of dance to Balanchine’s American neoclassicism, formulating the set of aesthetic principles that still shapes our idea of American ballet to date.

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