Solid-solid phase transition of (1-C 14 H 29 NH 3 ) 2 ZnCl 4 in nanopores of silica gel for thermal energy storage

2017 ◽  
Vol 28 (1) ◽  
pp. 49-54 ◽  
Author(s):  
Qi-Feng Li ◽  
Chao Wang ◽  
Xiao-Zheng Lan
Keyword(s):  
Phase Transition ◽  
Energy Storage ◽  
Silica Gel ◽  
Thermal Energy ◽  
Thermal Energy Storage ◽  
Solid Phase ◽  
Solid Phase Transition

scholarly journals The Li2SO4–Na2SO4 System for Thermal Energy Storage

Materials ◽  
2019 ◽  
Vol 12 (22) ◽  
pp. 3658 ◽  
Author(s):  
Stefania Doppiu ◽  
Jean-Luc Dauvergne ◽  
Angel Serrano ◽  
Elena Palomo del Barrio
Keyword(s):  
Phase Transition ◽  
Energy Storage ◽  
Solid State ◽  
Theoretical Analysis ◽  
Thermal Energy ◽  
Thermal Energy Storage ◽  
Solid Phase ◽  
Eutectoid Reaction ◽  
Durability Analysis ◽  
Solid Phase Transition

In this paper, the system Li2SO4–Na2SO4 is proposed as a candidate material for thermal energy storage applications at high temperatures (450–550 °C). Depending on the composition, the thermal energy can be stored by using a eutectoid reaction and solid–solid phase transition. In these types of systems, all the components (reagent and products) are in the solid state. This work includes the theoretical analysis (based on the Calphad method) of the system selected obtaining all the theoretical parameters (for example, enthalpies of reaction, transition temperatures, volume expansion, and the heat capacities) necessary to determine the theoretical performance in terms of thermal energy storage. The theoretical analysis allowed to identify two compositions (Li2SO4/Na2SO4 79/21 and 50/50) in the phase diagram with the most promising theoretical enthalpy of transformation (270 J/g and 318 J/g, respectively) corresponding to a eutectoid reaction and a solid–solid phase transition (stoichiometric compound LiNaSO4). The experimental analysis carried out allowed to confirm the great potential of this system for TES application even if some discrepancies with the theoretical calculation have been observed experimentally (energy densities lower than expected). For the two compositions studied, 79/21 and 50/50, the enthalpies of reaction are 185 J/g and 160 J/g, respectively. The reactivity of the system was tested under different experimental conditions preparing materials with a different degree of nanocrystallization to favor the diffusion in the solid state, testing the reactivity of the materials under controlled atmosphere and under air, and performing preliminary durability analysis (cycling behavior up to 20 cycles) to test the stability and reversibility.

Preparation and properties of shape-stabilized phase change material cellulose benzoate-g-polyoxyethylene (2) hexadecyl ether with potential for thermal energy storage

2018 ◽  
Vol 89 (8) ◽  
pp. 1512-1521
Author(s):  
Na Han ◽  
Wenxin Zhang ◽  
Xiufang Wang ◽  
Xingxiang Zhang ◽  
Wei Li ◽  
...  
Keyword(s):  
Phase Transition ◽  
Energy Storage ◽  
Phase Change ◽  
Thermal Energy ◽  
Thermal Energy Storage ◽  
Solid Phase ◽  
Resonance Spectroscopy ◽  
Thermal Reliability ◽  
Scanning Calorimetry ◽  
Chemical Structures

It is a worldwide challenge to efficiently use renewable resources to solve the current energy shortage. The existing cellulose-based material is incapable of proper power storage. In this study, a series of cellulose benzoate-g-polyoxyethylene (2) hexadecyl ether (CB-g-E2C16) solid–solid phase change materials were synthesized with cellulose as the skeleton and polyoxyethylene (2) hexadecyl ether (E2C16) as a functional side chain. The skeleton cellulose and benzoyl chloride restrict the free movement of the molecular chains of E2C16 above the phase transition temperature, leading to a solid–solid phase change. Fourier transform infrared spectroscopy and nuclear magnetic resonance spectroscopy were performed to investigate the chemical structures. The thermal energy-storage properties, thermal reliability and thermal stability of the CB-g-E2C16 were investigated by differential scanning calorimetry and thermogravimetry (TG) methods. The analysis results indicated that the E2C16 chains were successfully grafted onto the cellulose benzoate (CB) backbone and the copolymers exhibited typical solid–solid phase transition behavior. The enthalpy and degree of substitution of graft copolymers CB-g-E2C16 could be adjusted by changing the feeding ratio of the raw materials, reaction temperature and post-processing methods of CB. TG analysis results showed that the CB-g-E2C16 copolymers possessed good thermostability and they keep their stability up to 278℃. Compared with pure cellulose, CB-g-E2C16 copolymers could be dissolved in dimethyl sulfoxide and most of them could be dissolved in N, N-dimethylformamide.

scholarly journals Study of the Phase Transitions in the Binary System NPG-TRIS for Thermal Energy Storage Applications

Materials ◽  
2020 ◽  
Vol 13 (5) ◽  
pp. 1162 ◽  
Author(s):  
Sergio Santos-Moreno ◽  
Stefania Doppiu ◽  
Gabriel A. Lopez ◽  
Nevena Marinova ◽  
Ángel Serrano ◽  
...  
Keyword(s):  
Phase Transition ◽  
Phase Transitions ◽  
Transition Temperature ◽  
Energy Storage ◽  
Binary System ◽  
Thermal Energy ◽  
Thermal Energy Storage ◽  
Solid Phase ◽  
High Enthalpy ◽  
Pure Compounds

Neopentylglycol (NPG) and tris(hydroxymethyl)aminomethane (TRIS) are promising phase change materials (PCMs) for thermal energy storage (TES) applications. These molecules undergo reversible solid-solid phase transitions that are characterized by high enthalpy changes. This work investigates the NPG-TRIS binary system as a way to extend the use of both compounds in TES, looking for mixtures that cover transition temperatures different from those of pure compounds. The phase diagram of NPG-TRIS system has been established by thermal analysis. It reveals the existence of two eutectoids and one peritectic invariants, whose main properties as PCMs (transition temperature, enthalpy of phase transition, specific heat and density) have been determined. Of all transitions, only the eutectoid at 392 K shows sufficiently high enthalpy of solid-solid phase transition (150–227 J/g) and transition temperature significantly different from that of the solid-state transitions of pure compounds (NPG: 313 K; TRIS: 407 K). Special attention has also been paid to the analysis of metastability issues that could limit the usability of NPG, TRIS and their mixtures as PCMs. It is proven that the addition of small amounts of expanded graphite microparticles contributes to reduce the subcooling phenomena that characterizes NPG and TRIS and solve the reversibility problems observed in NPG/TRIS mixtures.

scholarly journals Thermal Energy Storage Performance of Tetrabutylammonium Acrylate Hydrate as Phase Change Materials

2021 ◽  
Vol 11 (11) ◽  
pp. 4848
Author(s):  
Hitoshi Kiyokawa ◽  
Hiroki Tokutomi ◽  
Shinichi Ishida ◽  
Hiroaki Nishi ◽  
Ryo Ohmura
Keyword(s):  
Energy Storage ◽  
Heat Exchanger ◽  
Thermal Energy ◽  
Thermal Energy Storage ◽  
Phase Change Materials ◽  
Heat Storage ◽  
Solid Phase ◽  
Agitation Rate ◽  
Mechanical Agitation ◽  
External Forces

Kinetic characteristics of thermal energy storage (TES) using tetrabutylammonium acrylate (TBAAc) hydrate were experimentally evaluated for practical use as PCMs. Mechanical agitation or ultrasonic vibration was added to detach the hydrate adhesion on the heat exchanger, which could be a thermal resistance. The effect of the external forces also was evaluated by changing their rotation rate and frequency. When the agitation rate was 600 rpm, the system achieved TES density of 140 MJ/m3 in 2.9 hours. This value is comparable to the ideal performance of ice TES when its solid phase fraction is 45%. UA/V (U: thermal transfer coefficient, A: surface area of the heat exchange coil, V: volume of the TES medium) is known as an index of the ease of heat transfer in a heat exchanger. UA/V obtained in this study was comparable to that of other common heat exchangers, which means the equivalent performance would be available by setting the similar UA/V. In this study, we succeeded in obtaining practical data for heat storage by TBAAc hydrate. The data obtained in this study will be a great help for the practical application of hydrate heat storage in the future.

Solid-Solid Phase Transitions for Thermal Energy Storage

1981 ◽  
pp. 309-324 ◽  
Author(s):  
V. Busico ◽  
P. Corradini ◽  
M. Vacatello ◽  
F. Fittipaldi ◽  
L. Nicolais
Keyword(s):  
Phase Transitions ◽  
Energy Storage ◽  
Thermal Energy ◽  
Thermal Energy Storage ◽  
Solid Phase
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