Brønsted acidic ionic liquid catalyzed highly efficient synthesis of chromeno pyrimidinone derivatives and their antimicrobial activity

2012 ◽  
Vol 23 (9) ◽  
pp. 1015-1018 ◽  
Author(s):  
Janardhan Banothu ◽  
Rajitha Bavanthula
2017 ◽  
Vol 7 (10) ◽  
pp. 2065-2073 ◽  
Author(s):  
Jie Deng ◽  
Bao-Hua Xu ◽  
Yao-Feng Wang ◽  
Xian-En Mo ◽  
Rui Zhang ◽  
...  

A highly efficient synthesis of isosorbide from sorbitol was developed using Brønsted acidic ionic liquids (BILs) as the catalyst for the first time.


2018 ◽  
Vol 263 ◽  
pp. 1-7 ◽  
Author(s):  
Wen-Sen He ◽  
Ling-Ling Li ◽  
Qiu-Jin Huang ◽  
Ji Yin ◽  
Xue-Chen Cao

2005 ◽  
Vol 83 (10) ◽  
pp. 1746-1751 ◽  
Author(s):  
Ganesan Karthikeyan ◽  
Paramasivan T Perumal

A facile enamination of 1,3-dicarbonyl compounds with amines has been developed that affords good to excellent yields of β-enamino esters and β-enaminones using Brønsted acidic ionic liquid 1-methylimidazolium trifluoroacetate ([Hmim]+Tfa–) at room temperature. This methodology has been extended for the synthesis of substituted pyridines in excellent yield by a one-pot, three-component reaction of 1,3-dicarbonyl compounds, ammonium acetate, and alkynone in the presence of [Hmim]+Tfa–.Key words: ionic liquid, β-enaminones, β-enamino esters, 1,3-dicarbonyl compounds, amines, pyridines.


Author(s):  
Atefeh Saadat ◽  
Abdolkarim Zare ◽  
Fatemeh Jamadi ◽  
Maasoomeh Abdolalipour-Saretoli

In this work, a novel Brønsted acidic ionic liquid namely triethylaminium-N-sulfonic acid trifluoroacetate {[TEASA][TFA]} has been synthesized by the reaction of NEt3 with ClSO3H, and then with CF3CO2H. The ionic liquid has been characterized by studying its spectroscopic data (1H and 13C NMR, FT-IR, and mass spectra). Afterward, it has been utilized as a highly effective and general catalyst to promote the following organic reactions in solvent-free conditions: (i) the production of 1-thioamidoalkyl-2-naphthols from arylaldehydes, 2-naphthol and thioacetamide, and (ii) the preparation of 14-aryl-14H-dibenzo[a,j]xanthenes from arylaldehydes and 2-naphthol. It is noteworthy that [TEASA][TFA] has catalyzed the reactions under milder conditions relative to most of the reported methods. Moreover, it afforded the both products in higher yields with respect to most of the previous works. Copyright © 2018 BCREC Group. All rights reservedReceived: 21st June 2017; Revised: 6th October 2017; Accepted: 9th October 2017; Available online:  11st June 2018; Published regularly: 1st August 2018How to Cite: Saadat, A., Zare, A., Jamadi, F., Abdolalipour-Saretoli, M. (2018). Highly Efficient Synthesis of 1-Thioamidoalkyl-2-naphthols and 14-Aryl-14H-dibenzo[a,j]xanthenes using a Novel Ionic Liquid: Catalyst Preparation, Characterization and Performing the Reactions. Bulletin of Chemical Reaction Engineering & Catalysis, 13 (2): 204-212 (doi:10.9767/bcrec.13.2.1280.204-212) 


2014 ◽  
Vol 55 (44) ◽  
pp. 6060-6064 ◽  
Author(s):  
Narsidas J. Parmar ◽  
Bhagyashri D. Parmar ◽  
Tushar R. Sutariya ◽  
Rajni Kant ◽  
Vivek K. Gupta

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