Syntheses of hydrido selenophenolato iron(II) complexes and their catalytic application in hydrosilylation of aldehydes and ketones

2018 ◽  
Vol 115 ◽  
pp. 1-5 ◽  
Author(s):  
Yangyang Wang ◽  
Shishuai Ren ◽  
Wenbo Zhang ◽  
Benjing Xue ◽  
Xinghao Qi ◽  
...  
2019 ◽  
Vol 475 ◽  
pp. 110460 ◽  
Author(s):  
Peigen Su ◽  
Chao Fan ◽  
Heng Yu ◽  
Wanqin Wang ◽  
Xin Jia ◽  
...  

RSC Advances ◽  
2015 ◽  
Vol 5 (64) ◽  
pp. 52000-52006 ◽  
Author(s):  
Benjing Xue ◽  
Hongjian Sun ◽  
Xiaoyan Li

Four hydrido iron(ii) complexes (1–4) with [P,S]-chelating ligands were synthesized by the reactions of (2-diphenylphosphanyl)thiophenols, C6H3(1-SH) (2-PPh2) (4-R1) (6-R2), abbreviated as (P^SH), with Fe(PMe3)4.


2018 ◽  
Vol 17 (06) ◽  
pp. 1850008 ◽  
Author(s):  
Asghar Zamani ◽  
Ahmad Poursattar Marjani ◽  
Khadijeh Alimoradlu

Ceria (CeO2) nanoparticles (NPs) have been produced from cerium nitrate and walnut shell as a worthless agricultural waste by a thermal decomposition method followed by open air calcination. These NPs further were characterized using powder X-ray diffraction, transmission electron microscopy (TEM), scanning electron microscopy, energy dispersive X-ray spectroscope and Fourier transform infrared spectroscopy. Moreover, particle sizes can be tuned by changing cerium source/biomass ratio. To test the catalytic activity of cerium NPs as a heterogeneous catalyst, we selected three-component synthesis of 3,4-dihydroquinoxalin-2-amine. Also, the efficiency of CeO2 NPs as a support for palladium NPs and subsequent use in aerobic oxidation of alcohols has been investigated. TEM image of a recovered catalyst indicates the formation of 12 nm sized palladium NPs within the cerium oxide NPs. The catalyst is quite effective for the oxidation of primary and secondary benzylic alcohols into their corresponding aldehydes and ketones under atmospheric pressure of air. Oxidation of secondary aliphatic alcohols is performed in oxygen atmosphere.


2018 ◽  
Vol 42 (20) ◽  
pp. 16583-16590 ◽  
Author(s):  
Xinghao Qi ◽  
Hua Zhao ◽  
Hongjian Sun ◽  
Xiaoyan Li ◽  
Olaf Fuhr ◽  
...  

The catalytic performance of [PPP]-pincer hydrido Fe, Ni and Co complexes for the hydrosilylation of aldehydes and ketones was explored.


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