Novel heterogeneous Rh-incorporated graphitic-carbon nitride for liquid-phase carbonylation of methanol to acetic acid

2017 ◽  
Vol 99 ◽  
pp. 141-145 ◽  
Author(s):  
Ji Su Nam ◽  
A. Rong Kim ◽  
Da Mi Kim ◽  
Tae Sun Chang ◽  
Beom Sik Kim ◽  
...  
Keyword(s):  
Acetic Acid ◽  
Liquid Phase ◽  
Carbon Nitride ◽  
Graphitic Carbon ◽  
Graphitic Carbon Nitride

Synthesis of Cu Single Atoms Supported on Mesoporous Graphitic Carbon Nitride and Their Application in Liquid-Phase Aerobic Oxidation of Cyclohexene

ACS Catalysis ◽  
2021 ◽  
pp. 7863-7875
Author(s):  
Julia Büker ◽  
Xiubing Huang ◽  
Johannes Bitzer ◽  
Wolfgang Kleist ◽  
Martin Muhler ◽  
...  
Keyword(s):  
Liquid Phase ◽  
Carbon Nitride ◽  
Aerobic Oxidation ◽  
Graphitic Carbon ◽  
Graphitic Carbon Nitride ◽  
Single Atoms

Cu2+ coordinated graphitic carbon nitride (Cu-g-C3N4) nanosheets from melamine for the liquid phase hydroxylation of benzene and VOCs

2017 ◽  
Vol 398 ◽  
pp. 43-55 ◽  
Author(s):  
Lingeswarran Muniandy ◽  
Farook Adam ◽  
Abdul Rahman Mohamed ◽  
Anwar Iqbal ◽  
Nur Ruzaina Abdul Rahman
Keyword(s):  
Liquid Phase ◽  
Carbon Nitride ◽  
Graphitic Carbon ◽  
Graphitic Carbon Nitride ◽  
Hydroxylation Of Benzene

scholarly journals Synthesis of maleic acid from biomass-derived furfural in the presence of KBr/graphitic carbon nitride (g-C3N4) catalyst and hydrogen peroxide

BioResources ◽  
2019 ◽  
Vol 14 (3) ◽  
pp. 5025-5044 ◽  
Author(s):  
Tao Yang ◽  
Wenzhi Li ◽  
Qinchuan Liu ◽  
Mingxue Su ◽  
Tingwei Zhang ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Liquid Phase ◽  
Maleic Acid ◽  
Carbon Nitride ◽  
Reaction System ◽  
Graphitic Carbon ◽  
Graphitic Carbon Nitride ◽  
Homogeneous Reaction ◽  
Potassium Salts ◽  
One Step

A one-step, liquid-phase hydrogen peroxide reaction system, which was heterogeneously catalyzed by KBr-doped graphitic carbon nitride (KBr/g-C3N4), was developed for the conversion of furfural to maleic acid (MA). At first, a 68.0% MA yield was achieved in a homogeneous reaction system catalyzed by KBr-KOH. Next, a series of K-doped g-C3N4 catalysts with various potassium salts (KBr, KCl, KNO3, and KOH) was synthesized and tested for the conversion of furfural to MA, 2-buten-1,4-olide (FRO), and succinic acid (SA). When comparing the various K-doped g-C3N4 catalysts, KBr/g-C3N4 enhanced MA selectivity, which resulted in complete furfural conversion and a 70.4% MA yield (at 100 °C for 180 min). Furthermore, a synergistic interaction was observed between KBr and the g-C3N4 support, which could explain why KBr/g-C3N4 had the highest MA selectivity.

Metal Doped-C3N4/Fe2O4: Efficient and Versatile Heterogenous Catalysts for Organic Transformations

2019 ◽  
Vol 23 (12) ◽  
pp. 1284-1306
Author(s):  
Vijai K. Rai ◽  
Fooleswar Verma ◽  
Suhasini Mahata ◽  
Smita R. Bhardiya ◽  
Manorama Singh ◽  
...  
Keyword(s):  
Ring Opening ◽  
Carbon Nitride ◽  
Addition Reaction ◽  
High Surface ◽  
Graphitic Carbon ◽  
Graphitic Carbon Nitride ◽  
Organic Transformations ◽  
Reduction Reactions ◽  
Activation Reaction ◽  
Metal Doped

The polymeric graphitic carbon nitride (g-C3N4) has been one of the interesting earth abundant elements. Though g-C3N4 finds application as a photocatalyst, its photocatalytic behaviour is limited because of low efficiency, mainly due to rapid charge recombination. To overcome this problem, several strategies have been developed including doping of metal/non-metal in the cavity of g-C3N4. Moreover, the CoFe2O4 NPs have been used in many organic transformations because of its high surface area and easy separation due to its magnetic nature. This review describes the role of cobalt ferrite as magnetic nanoparticles and metal-doped carbon nitride as efficient heterogeneous catalysts for new carbon-carbon and carbon-hetero atom bond formation followed by heterocyclization. Reactions which involved new catalysts for selective activation of readily available substrates has been reported herein. Since nanoparticles enhance the reactivity of catalyst due to higher catalytic area, they have been employed in various reactions such as addition reaction, C-H activation reaction, coupling reaction, cyclo-addition reaction, multi-component reaction, ring-opening reaction, oxidation reaction and reduction reactions etc. The driving force for choosing this topic is based-on huge number of good publications including different types of spinels/metal doped-/graphitic carbon nitride reported in the literature and due to interest of synthetic community in recent years. This review certainly will represent the present status in organic transformation and for exploring further their catalytic efficiency to new organic transformations involving C-H activation reaction through coupling, cyclo-addition, multi-component, ring-opening, oxidation and reduction reactions.

Sign in / Sign up

Export Citation Format

Share Document