Deactivation behavior of CrOy/Al2O3-ZrO2 catalysts in the dehydrogenation of propane to propylene by lattice oxygen

2017 ◽  
Vol 97 ◽  
pp. 37-41 ◽  
Author(s):  
Tae Hyeop Kim ◽  
Min Yeong Gim ◽  
Ji Hwan Song ◽  
Won Choon Choi ◽  
Yong-Ki Park ◽  
...  
Keyword(s):  
Lattice Oxygen

scholarly journals Correction: Activating the lattice oxygen in (Bi0.5Co0.5)2O3 by vacancy modulation for efficient electrochemical water oxidation

2021 ◽  
Vol 9 (8) ◽  
pp. 5111-5112
Author(s):  
Huan Liu ◽  
Xiaoning Li ◽  
Cailing Peng ◽  
Liuyang Zhu ◽  
Yuanxi Zhang ◽  
...  
Keyword(s):  
Water Oxidation ◽  
Lattice Oxygen

Correction for ‘Activating the lattice oxygen in (Bi0.5Co0.5)2O3 by vacancy modulation for efficient electrochemical water oxidation’ by Huan Liu et al., J. Mater. Chem. A, 2020, 8, 13150–13159, DOI: 10.1039/D0TA03411H.

Kinetics of Oxidative Cracking of n‐Hexane to Light Olefins using Lattice Oxygen of a VO x /SrO‐γAl 2 O 3 Catalyst

2021 ◽  
Author(s):  
Hussein K. Amusa ◽  
Sagir Adamu ◽  
Abeer S. Arjah ◽  
Saad A. Al‐Bogami ◽  
Sameer Al‐Ghamdi ◽  
...  
Keyword(s):  
Lattice Oxygen ◽  
Light Olefins ◽  
Oxidative Cracking ◽  
Kinetics Of

scholarly journals Role of CO2 During Oxidative Dehydrogenation of Propane Over Bulk and Activated-Carbon Supported Cerium and Vanadium Based Catalysts

2021 ◽  
Author(s):  
Petar Djinović ◽  
Janez Zavašnik ◽  
Janvit Teržan ◽  
Ivan Jerman
Keyword(s):  
Catalytic Activity ◽  
Activated Carbon ◽  
Oxidative Dehydrogenation ◽  
Active Phase ◽  
Lattice Oxygen ◽  
Chemisorbed Oxygen ◽  
Catalytically Active ◽  
Temperature Programmed ◽  
Propane Cracking

AbstractCeO2, V2O5 and CeVO4 were synthesised as bulk oxides, or deposited over activated carbon, characterized by XRD, HRTEM, CO2-TPO, C3H8-TPR, DRIFTS and Raman techniques and tested in propane oxidative dehydrogenation using CO2. Complete oxidation of propane to CO and CO2 is favoured by lattice oxygen of CeO2. The temperature programmed experiments show the ~ 4 nm AC supported CeO2 crystallites become more susceptible to reduction by propane, but less prone to re-oxidation with CO2 compared to bulk CeO2. Catalytic activity of CeVO4/AC catalysts requires a 1–2 nm amorphous CeVO4 layer. During reaction, the amorphous CeVO4 layer crystallises and several atomic layers of carbon cover the CeVO4 surface, resulting in deactivation. During reaction, V2O5 is irreversibly reduced to V2O3. The lattice oxygen in bulk V2O5 favours catalytic activity and propene selectivity. Bulk V2O3 promotes only propane cracking with no propene selectivity. In VOx/AC materials, vanadium carbide is the catalytically active phase. Propane dehydrogenation over VC proceeds via chemisorbed oxygen species originating from the dissociated CO2. Graphic Abstract

Insights into the synergistic role of metal–lattice oxygen site pairs in four-centered C–H bond activation of methane: the case of CuO

2016 ◽  
Vol 6 (11) ◽  
pp. 3984-3996 ◽  
Author(s):  
Jithin John Varghese ◽  
Quang Thang Trinh ◽  
Samir H. Mushrif
Keyword(s):  
Activation Energy ◽  
Copper Oxide ◽  
Bond Activation ◽  
Lattice Oxygen ◽  
Oxide Surfaces ◽  
Energy Barriers ◽  
Metal Lattice ◽  
Oxygen Site ◽  
Site Pair

Of the three mechanisms for activation of methane on copper and copper oxide surfaces, the under-coordinated Cu–O site pair mediated mechanism on CuO surfaces has the lowest activation energy barriers.

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