Restrictive nanoreactor for growth of transition metal oxides (MnO2, Co3O4, NiO) nanocrystal with enhanced catalytic oxidation activity

2015 ◽  
Vol 72 ◽  
pp. 165-169 ◽  
Author(s):  
Wenxiang Tang ◽  
Yuzhou Deng ◽  
Wenhui Li ◽  
Shuangde Li ◽  
Xiaofeng Wu ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Oxides ◽  
Catalytic Oxidation ◽  
Transition Metal Oxides ◽  
Oxidation Activity

Catalytic Oxidation of 1,2-Dichlorobenzene over Supported Transition Metal Oxides

2000 ◽  
Vol 193 (2) ◽  
pp. 264-272 ◽  
Author(s):  
Sundaram Krishnamoorthy ◽  
Juan A. Rivas ◽  
Michael D. Amiridis
Keyword(s):  
Transition Metal ◽  
Metal Oxides ◽  
Catalytic Oxidation ◽  
Transition Metal Oxides

Lattice-Refined Transition-Metal Oxides via Ball Milling for Boosted Catalytic Oxidation Performance

2019 ◽  
Vol 11 (40) ◽  
pp. 36666-36675 ◽  
Author(s):  
Jing He ◽  
Peiwen Wu ◽  
Linjie Lu ◽  
Hongping Li ◽  
Haiyan Ji ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Oxides ◽  
Ball Milling ◽  
Catalytic Oxidation ◽  
Transition Metal Oxides ◽  
Oxidation Performance

HREM Study of electron-induced surface radiation damage in ReO3

1991 ◽  
Vol 49 ◽  
pp. 636-637
Author(s):  
R. Ai ◽  
H.-J. Fan ◽  
L. D. Marks
Keyword(s):  
Transition Metal ◽  
Metal Ions ◽  
Metal Oxides ◽  
Electron Irradiation ◽  
Transition Metal Oxides ◽  
Carbon Film ◽  
Transition Metal Ions ◽  
Surface Radiation ◽  
Valence Transition ◽  
Electron Microscopes

It has been known for a long time that electron irradiation induces damage in maximal valence transition metal oxides such as TiO2, V2O5, and WO3, of which transition metal ions have an empty d-shell. This type of damage is excited by electronic transition and can be explained by the Knoteck-Feibelman mechanism (K-F mechanism). Although the K-F mechanism predicts that no damage should occur in transition metal oxides of which the transition metal ions have a partially filled d-shell, namely submaximal valence transition metal oxides, our recent study on ReO3 shows that submaximal valence transition metal oxides undergo damage during electron irradiation.ReO3 has a nearly cubic structure and contains a single unit in its cell: a = 3.73 Å, and α = 89°34'. TEM specimens were prepared by depositing dry powders onto a holey carbon film supported on a copper grid. Specimens were examined in Hitachi H-9000 and UHV H-9000 electron microscopes both operated at 300 keV accelerating voltage. The electron beam flux was maintained at about 10 A/cm2 during the observation.

Problems with oxygen analysis in the system MgO-Al2O3-SiO2 with the electron microprobe

1992 ◽  
Vol 50 (2) ◽  
pp. 1624-1625
Author(s):  
Michel Fialin ◽  
Guy Rémond
Keyword(s):  
Transition Metal ◽  
Metal Oxides ◽  
Transition Metal Oxides ◽  
Electrostatic Charge ◽  
Carbon Layer ◽  
Sample Holder ◽  
Rock Matrix ◽  
Electrical Discharges ◽  
Thin Carbon ◽  
Beam Instabilities

Oxygen-bearing minerals are generally strong insulators (e.g. silicates), or if not (e.g. transition metal oxides), they are included within a rock matrix which electrically isolates them from the sample holder contacts. In this respect, a thin carbon layer (150 Å in our laboratory) is evaporated on the sections in order to restore the conductivity. For silicates, overestimated oxygen concentrations are usually noted when transition metal oxides are used as standards. These trends corroborate the results of Bastin and Heijligers on MgO, Al2O3 and SiO2. According to our experiments, these errors are independent of the accelerating voltage used (fig.l).Owing to the low density of preexisting defects within the Al2O3 single-crystal, no significant charge buildup occurs under irradiation at low accelerating voltage (< 10keV). As a consequence, neither beam instabilities, due to electrical discharges within the excited volume, nor losses of energy for beam electrons before striking the sample, due to the presence of the electrostatic charge-induced potential, are noted : measurements from both coated and uncoated samples give comparable results which demonstrates that the carbon coating is not the cause of the observed errors.

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