Host (aluminum incorporated mesocellulous silica foam (Al-MCF))-guest (tungsten polyoxometalate) nanocomposite material: an efficient and reusable catalyst for selective oxidation of sulfides to sulfoxides and sulfones

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The A-type sandwich POMs of [(HOSnIVOH)3(PW9O34)2]12– (P2W18Sn3) and [(OCeIVO)3(PW9O34)2]12– (P2W18Ce3) were immobilized for the first time into the porous MIL-101 MOF. Their catalytic activities were examined in the oxidation of sulfides to sulfones at room temperature.


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