CO and ethanol oxidation over LaCoO3 planar model catalysts: Effect of the thickness

2011 ◽  
Vol 12 (14) ◽  
pp. 1344-1350 ◽  
Author(s):  
Patrick Herve Tchoua Ngamou ◽  
Katharina Kohse-Höinghaus ◽  
Naoufal Bahlawane
2004 ◽  
Vol 108 (46) ◽  
pp. 17905-17914 ◽  
Author(s):  
Armando Borgna ◽  
Bruce G. Anderson ◽  
Abdool M. Saib ◽  
Hendrik Bluhm ◽  
Michael Hävecker ◽  
...  

Langmuir ◽  
2003 ◽  
Vol 19 (2) ◽  
pp. 458-468 ◽  
Author(s):  
Christian Werdinius ◽  
Lars Österlund ◽  
Bengt Kasemo

2006 ◽  
Vol 153 (4) ◽  
pp. A724 ◽  
Author(s):  
Henrik Ekström ◽  
Per Hanarp ◽  
Marie Gustavsson ◽  
Erik Fridell ◽  
Anders Lundblad ◽  
...  

1972 ◽  
Vol 33 (3) ◽  
pp. 751-755 ◽  
Author(s):  
Mary K. Roach ◽  
Myrna Khan ◽  
Marguerite Knapp ◽  
W. N. Reese

2019 ◽  
Author(s):  
Moritz Wolf ◽  
Nico Fischer ◽  
Michael Claeys

<p>The inert nature of graphitic samples allows for characterisation of rather isolated supported nanoparticles in model catalysts, as long as sufficiently large inter-particle distances are obtained. However, the low surface area of graphite and the little interaction with nanoparticles result in a challenging application of conventional preparation routes in practice. In the present study, a set of graphitic carbon materials was characterised in order to identify potential support materials for the preparation of model catalyst systems. Various sizes of well-defined Co<sub>3</sub>O<sub>4</sub> nanoparticles were synthesised separately and supported onto exfoliated graphite powder, that is graphite after solvent-assisted exfoliation <i>via</i> ultrasonication resulting in thinner flakes with increased specific surface area. The developed model catalysts are ideally suited for sintering studies of isolated nano-sized cobaltous particles as the graphitic support material does not provide distinct metal-support interaction. Furthermore, the differently sized cobaltous particles in the various model systems render possible studies on structural dependencies of activity, selectivity, and deactivation in cobalt oxide or cobalt catalysed reactions.</p>


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