Preparation, characterization and catalytic activity studies of CeO2–K diesel soot oxidation catalysts loaded on porous Al2O3 substrate using water-immiscible solvent

2007 ◽  
Vol 8 (11) ◽  
pp. 1675-1680 ◽  
Author(s):  
Yongheng Zhang ◽  
Yuhua Qin ◽  
Xiaoting Zou
Catalysts ◽  
2019 ◽  
Vol 9 (8) ◽  
pp. 684 ◽  
Author(s):  
James Zokoe ◽  
Xiaoxiang Feng ◽  
Changsheng Su ◽  
Paul J. McGinn

The hydrothermal stability of K-Ca-Si-O glass soot oxidation catalysts has been improved by substitution of Ce and Zr for Ca. This work demonstrates that glasses can be tailored to withstand the challenging diesel exhaust hydrothermal environment by considering the field strengths and partial molar free energies of the hydration reactions (ΔGi) of the cation species in the glass. The result is a glass that shows less formation of precipitates after 2 h hydrothermal exposure in air with 7% H2O at temperatures ranging from 300–700 °C. A K-Ca-Si-O glass with a soot T50 (the temperature when 50% of the soot is oxidized) of 394 °C was found to degrade to 468 °C after a 2 h, 700 °C hydrothermal exposure, whereas the improved K-Ce-Zr-Si-O glass only changed from 407 °C to 427 °C after the same treatment.


2007 ◽  
Vol 336-338 ◽  
pp. 1995-1998
Author(s):  
Yong Heng Zhang ◽  
Jian Zhong Xue

The catalysts based on V/K/Ca and V/Ks/Ce systems for diesel soot catalytic oxidation were synthesized onto the porous alumina substrates. Both catalyst systems showed a good catalytic oxidation activity. The V/K/Ca system exhibited the lowest oxidation onset temperature (OOT) of about 359oC with a composition of V/K/Ca =1:1:0.1 where the V and Ca and/or K elements could form a kind of amorphous phase that determined the catalytic activity. The V/Ks/Ce system displayed the lowest OOT of about 350oC with a composition of V/Ks/Ce = 1:2:0.1 where the K2SO4 and K5V2O3(SO4)4 phases could contribute most to the catalytic activity.


2018 ◽  
Vol 54 (6) ◽  
pp. 4495-4510 ◽  
Author(s):  
Lijie Ai ◽  
Zhongpeng Wang ◽  
Yibo Gao ◽  
Chenchen Cui ◽  
Baoqin Wang ◽  
...  

2017 ◽  
Vol 7 (14) ◽  
pp. 3045-3055 ◽  
Author(s):  
Deboshree Mukherjee ◽  
Perala Venkataswamy ◽  
Damma Devaiah ◽  
Agolu Rangaswamy ◽  
Benjaram M. Reddy

The influence of an anatase-TiO2support on the diesel soot oxidation catalytic activity of manganese doped ceria is investigated.


2015 ◽  
Vol 5 (7) ◽  
pp. 3496-3500 ◽  
Author(s):  
Putla Sudarsanam ◽  
Brendan Hillary ◽  
Dumbre K. Deepa ◽  
Mohamad Hassan Amin ◽  
Baithy Mallesham ◽  
...  

Co3O4 promoted CeO2 nanocubes exhibit a remarkable catalytic activity for soot oxidation, attributed to the superior reducible nature of CeO2 and the preferential exposure of CeO2 (100) and Co3O4 (110) facets.


2007 ◽  
Vol 8 (12) ◽  
pp. 2110-2114 ◽  
Author(s):  
Xiaodong Wu ◽  
Qing Liang ◽  
Duan Weng ◽  
Zhenxiang Lu

2012 ◽  
Vol 33 (4-6) ◽  
pp. 970-976 ◽  
Author(s):  
Wenjuan SHAN ◽  
Lihua YANG ◽  
Na MA ◽  
Jiali YANG

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