Dielectric relaxation and ferroelectric phase transition in Sr4BiRTi4Nb6O30 (R=Sm, Eu) ceramics

2016 ◽  
Vol 16 (8) ◽  
pp. 843-849 ◽  
Author(s):  
Gebru Zerihun ◽  
Gaoshang Gong ◽  
Shuai Huang ◽  
Songliu Yuan
Keyword(s):  
Phase Transition ◽  
Dielectric Relaxation ◽  
Ferroelectric Phase Transition ◽  
Ferroelectric Phase

Dielectric relaxation in the weak ferroelectric Li2Ge7O15 near the ferroelectric phase transition

1998 ◽  
Vol 40 (12) ◽  
pp. 1994-1997
Author(s):  
A. Yu. Kudzin ◽  
M. D. Volnyanskii ◽  
M. P. Trubitsyn ◽  
I. A. Busoul
Keyword(s):  
Phase Transition ◽  
Dielectric Relaxation ◽  
Ferroelectric Phase Transition ◽  
Ferroelectric Phase

scholarly journals The origin of the lattice thermal conductivity enhancement at the ferroelectric phase transition in GeTe

2021 ◽  
Vol 7 (1) ◽  
Author(s):  
Đorđe Dangić ◽  
Olle Hellman ◽  
Stephen Fahy ◽  
Ivana Savić
Keyword(s):  
Phase Transition ◽  
Thermal Conductivity ◽  
Phase Transitions ◽  
Thermoelectric Materials ◽  
Ferroelectric Phase Transition ◽  
Lattice Thermal Conductivity ◽  
Ferroelectric Phase ◽  
Structural Phase ◽  
High Symmetry ◽  
Structural Phase Transitions

AbstractThe proximity to structural phase transitions in IV-VI thermoelectric materials is one of the main reasons for their large phonon anharmonicity and intrinsically low lattice thermal conductivity κ. However, the κ of GeTe increases at the ferroelectric phase transition near 700 K. Using first-principles calculations with the temperature dependent effective potential method, we show that this rise in κ is the consequence of negative thermal expansion in the rhombohedral phase and increase in the phonon lifetimes in the high-symmetry phase. Strong anharmonicity near the phase transition induces non-Lorentzian shapes of the phonon power spectra. To account for these effects, we implement a method of calculating κ based on the Green-Kubo approach and find that the Boltzmann transport equation underestimates κ near the phase transition. Our findings elucidate the influence of structural phase transitions on κ and provide guidance for design of better thermoelectric materials.

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