scholarly journals Acceleration of uncertainty updating in the description of transport processes in heterogeneous materials

2012 ◽  
Vol 236 (18) ◽  
pp. 4862-4872 ◽  
Author(s):  
Anna Kučerová ◽  
Jan Sýkora ◽  
Bojana Rosić ◽  
Hermann G. Matthies
Materials ◽  
2021 ◽  
Vol 14 (16) ◽  
pp. 4624
Author(s):  
Pakdad Pourbozorgi Langroudi ◽  
Gesa Kapteina ◽  
Marcus Illguth

Laser-induced breakdown spectroscopy (LIBS) is a technique which enables the analysis of material components with precision and spatial resolution. Furthermore, the investigation method is comparatively fast which enables illustrating the distribution of elements within the examined material. This opens new possibilities for the investigation of very heterogeneous materials, such as concrete. Concrete consists of cement, water, and aggregates. As most of the transport processes take place exclusively in the hardened cement paste, relevant limit values linked to harmful element contents are specified in relation to the cement mass. When a concrete sample from an existing structure is examined, information on the concrete composition is usually not available. Therefore, assumptions have to be made to convert the element content analyzed in the sample based on the cement content in the sample. This inevitably leads to inaccuracies. Therefore, a method for distinction between cement paste and aggregates is required. Cement and aggregate components are chemically very close to each other and therefore, complex for classification. This is why the consideration of a single distinguishing feature is not sufficient. In this paper, a machine learning method is described and has been used to automate the distinction of the cement paste and aggregates of the LIBS data to receive reliable information of this technique. The presented approach could potentially be employed for many heterogeneous materials with the same complexity to quantify the arbitrary substances.


1984 ◽  
Vol 75 ◽  
pp. 597
Author(s):  
E. Grün ◽  
G.E. Morfill ◽  
T.V. Johnson ◽  
G.H. Schwehm

ABSTRACTSaturn's broad E ring, the narrow G ring and the structured and apparently time variable F ring(s), contain many micron and sub-micron sized particles, which make up the “visible” component. These rings (or ring systems) are in direct contact with magnetospheric plasma. Fluctuations in the plasma density and/or mean energy, due to magnetospheric and solar wind processes, may induce stochastic charge variations on the dust particles, which in turn lead to an orbit perturbation and spatial diffusion. It is suggested that the extent of the E ring and the braided, kinky structure of certain portions of the F rings as well as possible time variations are a result of plasma induced electromagnetic perturbations and drag forces. The G ring, in this scenario, requires some form of shepherding and should be akin to the F ring in structure. Sputtering of micron-sized dust particles in the E ring by magnetospheric ions yields lifetimes of 102to 104years. This effect as well as the plasma induced transport processes require an active source for the E ring, probably Enceladus.


1982 ◽  
Vol 43 (C9) ◽  
pp. C9-369-C9-380 ◽  
Author(s):  
A. R. Cooper ◽  
Jr
Keyword(s):  

2018 ◽  
Vol 106 (1) ◽  
pp. 107 ◽  
Author(s):  
Jean- Louis Crolet

All that was said so far about passivity and passivation was indeed based on electrochemical prejudgments, and all based on unverified postulates. However, due the authors’ fame and for lack of anything better, the great many contradictions were carefully ignored. However, when resuming from raw experimental facts and the present general knowledge, it now appears that passivation always begins by the precipitation of a metallic hydroxide gel. Therefore, all the protectiveness mechanisms already known for porous corrosion layers apply, so that this outstanding protectiveness is indeed governed by the chemistry of transport processes throughout the entrapped water. For Al type passivation, the base metal ions only have deep and complete electronic shells, which precludes any electronic conductivity. Then protectiveness can only arise from gel thickening and densification. For Fe type passivation, an incomplete shell of superficial 3d electrons allows an early metallic or semimetallic conductivity in the gel skeleton, at the onset of the very first perfectly ordered inorganic polymers (- MII-O-MIII-O-)n. Then all depends on the acquisition, maintenance or loss of a sufficient electrical conductivity in this Faraday cage. But for both types of passive layers, all the known features can be explained by the chemistry of transport processes, with neither exception nor contradiction.


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