Reconstituting redox active centers of heme-containing proteins with biomineralized gold toward peroxidase mimics with strong intrinsic catalysis and electrocatalysis for H2O2 detection

2017 ◽  
Vol 87 ◽  
pp. 1036-1043 ◽  
Author(s):  
Liyan Zhang ◽  
Shuai Li ◽  
Minmin Dong ◽  
Yao Jiang ◽  
Ru Li ◽  
...  
Keyword(s):  
Active Centers ◽  
Redox Active ◽  
H2o2 Detection ◽  
Peroxidase Mimics

scholarly journals Spatial Organization of the Redox Active Centers in the Bovine Heart Ubiquinol-cytochrome c Oxidoreductase

1989 ◽  
Vol 264 (2) ◽  
pp. 735-744
Author(s):  
T Ohnishi ◽  
H Schägger ◽  
S W Meinhardt ◽  
R LoBrutto ◽  
T A Link ◽  
...  
Keyword(s):  
Cytochrome C ◽  
Spatial Organization ◽  
Active Centers ◽  
Bovine Heart ◽  
Redox Active

Dendritic Metalloporphyrin-Fullerene Conjugates: Changing the Microenvironment around Redox-Active Centers and its Impact on Charge-Transfer Reactions

2012 ◽  
Vol 18 (33) ◽  
pp. 10427-10435 ◽  
Author(s):  
Evangelos Krokos ◽  
Fabian Spänig ◽  
Michaela Ruppert ◽  
Andreas Hirsch ◽  
Dirk M. Guldi
Keyword(s):  
Charge Transfer ◽  
Transfer Reactions ◽  
Active Centers ◽  
Redox Active ◽  
Charge Transfer Reactions

scholarly journals Made-to-order porous electrodes for supercapacitors: MOFs embedded with redox-active centers as a case study

2020 ◽  
Vol 56 (12) ◽  
pp. 1883-1886 ◽  
Author(s):  
Arijit Mallick ◽  
Hanfeng Liang ◽  
Osama Shekhah ◽  
Jiangtao Jia ◽  
Georges Mouchaham ◽  
...  
Keyword(s):  
Porous Electrodes ◽  
Active Centers ◽  
Redox Active ◽  
Electrodes For Supercapacitors ◽  
The Way

These predesigned Zr-based MOFs could pave the way for many applications related to supercapacitors.

Different synthetic pathways of nanoparticle-cored dendrimers (NCDs): Effects on the properties and their application as redox active centers

2014 ◽  
Vol 52 (22) ◽  
pp. 3185-3197 ◽  
Author(s):  
Julieta I. Paez ◽  
Pablo Froimowicz ◽  
Katharina Landfester ◽  
Verónica Brunetti ◽  
Miriam Strumia
Keyword(s):  
Active Centers ◽  
Redox Active

Organometallic chemistry at the nanoscale. Dendrimers for redox processes and catalysis

2003 ◽  
Vol 75 (4) ◽  
pp. 461-481 ◽  
Author(s):  
D. Astruc
Keyword(s):  
Electron Transfer ◽  
Redox Catalysis ◽  
Active Centers ◽  
Transfer Processes ◽  
Redox Active ◽  
Ruthenium Carbonyl ◽  
Ruthenium Carbonyl Clusters ◽  
Nitrate And Nitrite ◽  
Electron Transfer Processes ◽  
Transfer Chain

An overview of the metal-mediated synthesis and use of nanosized metallodendrimers is given with emphasis on electron-transfer processes (molecular batteries consisting in dendrimers decorated with a large number of equivalent redox-active centers) and catalytic reactions (electron-transfer-chain catalytic synthesis of dendrimers decorated with ruthenium carbonyl clusters, redox catalysis of nitrate and nitrite electroreduction in water by star-shape hexanuclear catalysts).

Recent Applications of Rare Earth Complexes in Photoredox Catalysis for Organic Synthesis

2021 ◽  
Vol 25 ◽  
Author(s):  
Alexis Prieto ◽  
Florian Jaroschik
Keyword(s):  
Rare Earth ◽  
Lewis Acids ◽  
Rare Earth Complexes ◽  
Photoredox Catalysis ◽  
Organic Transformations ◽  
New Paradigm ◽  
Active Centers ◽  
Redox Active ◽  
Wide Range ◽  
Made In

: In recent years, photoredox catalysis has appeared as a new paradigm for forging a wide range of chemical bonds under mild conditions using abundant reagents. This approach allows many organic transformations through the generation of various radical species, enabling the valorization of non-traditional partners. A continuing interest has been devoted to the discovery of novel radical-generating procedures. Over the last ten years, strategies using rare-earth complexes as either redox-active centers or as redox-neutral Lewis acids have emerged. This review provides an overview of the recent accomplishments made in this field. It especially aims to demonstrate the utility of rare-earth complexes for ensuring photocatalytic transformations and to inspire future developments.

Manipulation of conjugation to stabilize N redox-active centers for the design of high-voltage organic battery cathode

2019 ◽  
Vol 16 ◽  
pp. 236-242 ◽  
Author(s):  
Gaole Dai ◽  
Xuelan Wang ◽  
Yumin Qian ◽  
Zhihui Niu ◽  
Xi Zhu ◽  
...  
Keyword(s):  
High Voltage ◽  
Active Centers ◽  
Redox Active
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