Reduction of formic acid to methanol under hydrothermal conditions in the presence of Cu and Zn

2012 ◽  
Vol 114 ◽  
pp. 658-662 ◽  
Author(s):  
Jianke Liu ◽  
Xu Zeng ◽  
Min Cheng ◽  
Jun Yun ◽  
Qiuju Li ◽  
...  
Keyword(s):  
Formic Acid ◽  
Hydrothermal Conditions ◽  
Cu And Zn

Manganese oxide as an alternative to vanadium-based catalysts for effective conversion of glucose to formic acid in water

2021 ◽  
Author(s):  
Jialu Li ◽  
Richard Lee Smith Jr. ◽  
Siyu Xu ◽  
De Li ◽  
Jirui Yang ◽  
...  
Keyword(s):  
Formic Acid ◽  
Manganese Oxide ◽  
Hydrothermal Conditions ◽  
Reaction Systems ◽  
Vanadium Based Catalysts

MnOx catalysts were synthesized under hydrothermal conditions for converting glucose to formic acid (FA) in water with the objective to develop vanadium-free reaction systems. An FA yield of 81.1% was...

Low-temperature and highly efficient conversion of saccharides into formic acid under hydrothermal conditions

AIChE Journal ◽  
2016 ◽  
Vol 62 (10) ◽  
pp. 3657-3663 ◽  
Author(s):  
Jun Yun ◽  
Guodong Yao ◽  
Fangming Jin ◽  
Heng Zhong ◽  
Atsushi Kishita ◽  
...  
Keyword(s):  
Low Temperature ◽  
Formic Acid ◽  
Hydrothermal Conditions ◽  
Efficient Conversion ◽  
Highly Efficient

Catalytic conversion of NaHCO3 into formic acid in mild hydrothermal conditions for CO2 utilization

2009 ◽  
Vol 148 (3-4) ◽  
pp. 405-410 ◽  
Author(s):  
Bing Wu ◽  
Ying Gao ◽  
Fangming Jin ◽  
Jianglin Cao ◽  
Yingxun Du ◽  
...  
Keyword(s):  
Formic Acid ◽  
Catalytic Conversion ◽  
Co2 Utilization ◽  
Hydrothermal Conditions

scholarly journals Formation of Formic Acid from Glucose with Simultaneous Conversion of Ag2O to Ag under Mild Hydrothermal Conditions

ACS Omega ◽  
2021 ◽  
Vol 6 (17) ◽  
pp. 11260-11265
Author(s):  
Runtian He ◽  
Teng Ma ◽  
Jiong Cheng ◽  
Binbin Jin ◽  
Jing Xu
Keyword(s):  
Formic Acid ◽  
Hydrothermal Conditions

scholarly journals Formation of Formic Acid from Glucose with Simultaneous Conversion of Ag2O to Ag under Mild Hydrothermal Conditions

2021 ◽  
Author(s):  
Runtian He ◽  
Jing Xu ◽  
Teng Ma ◽  
Jiong Cheng ◽  
Binbin Jin
Keyword(s):  
Formic Acid ◽  
Value Added ◽  
Low Carbon ◽  
Chemical Production ◽  
Hydrothermal Conditions ◽  
Simultaneous Reduction ◽  
Renewable Biomass ◽  
Novel Approach ◽  
Biomass Resources ◽  
Hydrogen Carrier

<p>Formation of formic acid from renewable biomass resources is of great interest since formic acid is a widely used platform chemical and has recently been regarded as an important liquid hydrogen carrier. Herein, a novel approach is reported for the conversion of glucose, the constituent carbohydrate from cellulose fraction of biomass, to formic acid under mild hydrothermal conditions with simultaneous reduction of Ag<sub>2</sub>O to Ag. Results showed that glucose was selectively converted to formic acid with an optimum yield of 40.7% at a mild reaction temperature of 135 for 30 min. In addition, Ag<sub>2</sub>O was used as a solid oxidant for the glucose oxidation, which avoids the use of traditionally dangerous liquid oxidant H<sub>2</sub>O<sub>2</sub>. Furthermore, complete conversion of Ag<sub>2</sub>O to Ag can be achieved. This study not only developed a new method for value-added chemical production from renewable biomass but also explored an alternative low-carbon and energy-saving route for silver extraction and recovery.</p>

scholarly journals Formation of Formic Acid from Glucose with Simultaneous Conversion of Ag2O to Ag under Mild Hydrothermal Conditions

2021 ◽  
Author(s):  
Runtian He ◽  
Jing Xu ◽  
Teng Ma ◽  
Jiong Cheng ◽  
Binbin Jin
Keyword(s):  
Formic Acid ◽  
Value Added ◽  
Low Carbon ◽  
Chemical Production ◽  
Hydrothermal Conditions ◽  
Simultaneous Reduction ◽  
Renewable Biomass ◽  
Novel Approach ◽  
Biomass Resources ◽  
Hydrogen Carrier

<p>Formation of formic acid from renewable biomass resources is of great interest since formic acid is a widely used platform chemical and has recently been regarded as an important liquid hydrogen carrier. Herein, a novel approach is reported for the conversion of glucose, the constituent carbohydrate from cellulose fraction of biomass, to formic acid under mild hydrothermal conditions with simultaneous reduction of Ag<sub>2</sub>O to Ag. Results showed that glucose was selectively converted to formic acid with an optimum yield of 40.7% at a mild reaction temperature of 135 for 30 min. In addition, Ag<sub>2</sub>O was used as a solid oxidant for the glucose oxidation, which avoids the use of traditionally dangerous liquid oxidant H<sub>2</sub>O<sub>2</sub>. Furthermore, complete conversion of Ag<sub>2</sub>O to Ag can be achieved. This study not only developed a new method for value-added chemical production from renewable biomass but also explored an alternative low-carbon and energy-saving route for silver extraction and recovery.</p>

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