Improving visible light driving degradation of norfloxacin over core-shell hierarchical BiOCl microspherical photocatalyst by synergistic effect of oxygen vacancy and nanostructure

2018 ◽  
Vol 453 ◽  
pp. 373-382 ◽  
Author(s):  
Jing Tian ◽  
Zhiwei Chen ◽  
Xiaoyan Deng ◽  
Quan Sun ◽  
Zhiyong Sun ◽  
...  
Nanoscale ◽  
2018 ◽  
Vol 10 (32) ◽  
pp. 15294-15302 ◽  
Author(s):  
Xiaoyong Wu ◽  
Kaiqi Li ◽  
Yuan Li ◽  
Gaoke Zhang

The visible light photocatalytic activity of an ultrathin Bi2O2(OH)xCl2−x solid solution with an exposed {001} facet was boosted by adjusting the concentrations of oxygen vacancy and OH in it.


2016 ◽  
Vol 3 (7) ◽  
pp. 934-943 ◽  
Author(s):  
Xiankun Shao ◽  
Benxia Li ◽  
Baoshan Zhang ◽  
Liangzhi Shao ◽  
Yongmeng Wu

Au@ZnO core–shell nanostructures exhibit enhanced photocatalysis under both simulated sunlight and monochromatic LED light due to the synergistic effect between the plasmonic Au-nanosphere cores and the semiconducting ZnO shells.


2020 ◽  
Vol 01 ◽  
Author(s):  
Bonamali Pal ◽  
Anila Monga ◽  
Aadil Bathla

Background:: Bimetallic nanocomposites have currently gained significant importance for enhanced catalytic applications relative to monometallic analogues. The synergistic interactions modified electronic and optical properties in the bimetallic (M1@M2) structural morphology e.g., core-shell /alloy nanostructures resulted in a better co-catalytic performance for TiO2 photocatalysis. Objective:: Hence, this article discusses the preparation, characterization, and co-catalytic activity of different bimetallic nanostructures namely, Cu@Zn, Pd@Au, Au@Ag, and Ag@Cu, etc. Method:: These bimetallic co-catalysts deposited on TiO2 possess the ability to absorb visible light due to surface plasmonic absorption and are also expected to display the new properties due to synergy between two distinct metals. As a result, they reveal the highest level of activity than the monometal deposited TiO2. Result:: Their optical absorption, emission, charge carrier dynamics, and surface structural morphology are explained for the improved photocatalytic activity of M1@M2 loaded TiO2 for the hydrogenation of certain organic compounds e.g., quinoline, crotonaldehyde, and 1,3-dinitrobenzene, etc. under UV/ visible light irradiation. Conclusion:: It revealed that the use of bimetallic core@shell co-catalyst for hydrogenation of important industrial organics by M1@M2-TiO2 nanocomposite demonstrates beneficial reactivity in many instances relative to conventional transition metal catalysts.


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