Study of structural and electrochemical properties of La2SrV2O9 perovskites prepared using ball-milling

2018 ◽  
Vol 449 ◽  
pp. 468-473 ◽  
Author(s):  
Gouthami Nallamuthu ◽  
Sakthivel Thangavel ◽  
Kiranpreethi Kirubakaran ◽  
Vinesh Vasudevan ◽  
Yuvaraj Sivalingam ◽  
...  
2015 ◽  
Vol 1775 ◽  
pp. 7-12 ◽  
Author(s):  
Anara Molkenova ◽  
Izumi Taniguchi

ABSTRACTSpray pyrolysis has been widely used to prepare homogeneous and uniform ceramic powders with high purity. In this study, we are proposing ultrasonic spray pyrolysis followed by heat treatment to produce SiOx/C composite powders, where sucrose was used as a carbon source. Furthermore, high energy ball milling of the as-prepared powders in the presence of acetylene black was conducted to activate its electrochemical properties by reducing the particle size and improving the functionalization of the SiOx composite particles. SiOx/C nanocomposite finally obtained at a sucrous concentration of 0.1 mol L-1 showed superior electrochemical properties, and the SiOx/C nanocomposite electrode delivered the first discharge and charge capacities of 1252 and 819 mAh g-1, respectively, with an initial columbic efficiency of 65% at a current density of 50 mAh g-1 in the potential range from 0.01 to 3 V versus Li/Li+.


2016 ◽  
Vol 724 ◽  
pp. 87-91 ◽  
Author(s):  
Chang Su Kim ◽  
Yong Hoon Cho ◽  
Kyoung Soo Park ◽  
Soon Ki Jeong ◽  
Yang Soo Kim

We investigated the electrochemical properties of carbon-coated niobium dioxide (NbO2) as a negative electrode material for lithium-ion batteries. Carbon-coated NbO2 powders were synthesized by ball-milling using carbon nanotubes as the carbon source. The carbon-coated NbO2 samples were of smaller particle size compared to the pristine NbO2 samples. The carbon layers were coated non-uniformly on the NbO2 surface. The X-ray diffraction patterns confirmed that the inter-layer distances increased after carbon coating by ball-milling. This lead to decreased charge-transfer resistance, confirmed by electrochemical impedance spectroscopy, allowing electrons and lithium-ions to quickly transfer between the active material and electrolyte. Electrochemical performance, including capacity and initial coulombic efficiency, was therefore improved by carbon coating by ball-milling.


2009 ◽  
Vol 470 (1-2) ◽  
pp. 544-547 ◽  
Author(s):  
Guofeng Yan ◽  
Haisheng Fang ◽  
Huijuan Zhao ◽  
Guangshe Li ◽  
Yong Yang ◽  
...  

2018 ◽  
Vol 18 (9) ◽  
pp. 6431-6436 ◽  
Author(s):  
Gyu-Bong Cho ◽  
Hea-Bin Park ◽  
Jae-Seung Jeong ◽  
Myung-Rang Chae ◽  
Yeon-Min Im ◽  
...  

2019 ◽  
Vol 16 (24) ◽  
pp. 213-220 ◽  
Author(s):  
Claudine Hamel ◽  
Thierry Brousse ◽  
Daniel Bélanger ◽  
Daniel Guay

2019 ◽  
Vol 803 ◽  
pp. 109-114
Author(s):  
Ha Jin Lee ◽  
Du Yeol Kim ◽  
Soon Ki Jeong

This study investigates the electrochemical properties of ball-milled copper hexacyanoferrate (CuHCF), a Prussian blue analogue, as a cathode material in aqueous calcium-ion batteries (CIBs). X-ray diffraction analysis confirmed that the ball milling process did not destroy the crystal structure of the CuHCF active material. The general grain size and crystal surface of the synthesized CuHCF active materials were confirmed from the scanning electron microscopy (SEM) images. The electrochemical test results revealed that prolonged ball milling improved the charge/discharge capacity in the initial cycle. After 200 cycles, structural collapse of the CuHCF electrode occurred, as observed by SEM.


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