High-performance polyamide thin-film composite nanofiltration membrane: Role of thermal treatment

2018 ◽  
Vol 435 ◽  
pp. 415-423 ◽  
Author(s):  
Baicang Liu ◽  
Shuai Wang ◽  
Pingju Zhao ◽  
Heng Liang ◽  
Wen Zhang ◽  
...  
Keyword(s):  
Thin Film ◽  
Thermal Treatment ◽  
High Performance ◽  
Nanofiltration Membrane ◽  
Film Composite ◽  
Thin Film Composite

scholarly journals Fabrication of High-Performance Thin-Film Composite Nanofiltration Membrane by Dynamic Calcium-Carboxyl Intra-Bridging during Post-Treatment

Membranes ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 137
Author(s):  
Hongyi Han ◽  
Ruobin Dai ◽  
Zhiwei Wang
Keyword(s):  
Thin Film ◽  
Water Purification ◽  
High Performance ◽  
Rejection Rate ◽  
Post Treatment ◽  
Nanofiltration Membrane ◽  
Film Composite ◽  
Thin Film Composite ◽  
Post Modification

Widespread applications of nanofiltration (NF) and reverse osmosis (RO)-based processes for water purification and desalination call for high-performance thin-film composite (TFC) membranes. In this work, a novel and facile modification method was proposed to fabricate high-performance thin-film composite nanofiltration membrane by introducing Ca2+ in the heat post-treatment. The introduction of Ca2+ induced in situ Ca2+-carboxyl intra-bridging, leading to the embedment of Ca2+ in the polyamide (PA) layer. This post modification enhanced the hydrophilicity and surface charge of NF membranes compared to the pristine membrane. More interestingly, the modified membrane had more nodules and exhibited rougher morphology. Such changes brought by the addition of Ca2+ enabled the significant increase of water permeability (increasing from 17.9 L·m−2·h−1·bar−1 to 29.8 L·m−2·h−1·bar−1) while maintaining a high selectivity (Na2SO4 rejection rate of 98.0%). Furthermore, the intra-bridging between calcium and carboxyl imparted the NF membranes with evident antifouling properties, exhibiting milder permeability decline of 4.2% (compared to 16.7% of NF-control) during filtration of sodium alginate solution. The results highlight the potential of using Ca2+-carboxyl intra-bridging post-treatment to fabricate high-performance TFC membranes for water purification and desalination.

A facile and economic route assisted by trace tannic acid to construct a high-performance thin film composite NF membrane for desalination

2021 ◽  
Author(s):  
Na Zhang ◽  
Xiangju Song ◽  
Yiqiang Chen ◽  
Bin Jiang ◽  
Luhong Zhang ◽  
...  
Keyword(s):  
Thin Film ◽  
Tannic Acid ◽  
Trace Amount ◽  
High Performance ◽  
Nanofiltration Membrane ◽  
Film Composite ◽  
Thin Film Composite

A trace amount of green tannic acid assisted in the construction of thin film composite nanofiltration membrane for desalination.

Improved separation and antifouling properties of thin-film composite nanofiltration membrane by the incorporation of cGO

2017 ◽  
Vol 407 ◽  
pp. 260-275 ◽  
Author(s):  
Hongbin Li ◽  
Wenying Shi ◽  
Qiyun Du ◽  
Rong Zhou ◽  
Haixia Zhang ◽  
...  
Keyword(s):  
Thin Film ◽  
Nanofiltration Membrane ◽  
Film Composite ◽  
Thin Film Composite
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