Electrocatalytic performance evaluation of cobalt hydroxide and cobalt oxide thin films for oxygen evolution reaction

2018 ◽  
Vol 427 ◽  
pp. 253-259 ◽  
Author(s):  
P.T. Babar ◽  
A.C. Lokhande ◽  
B.S. Pawar ◽  
M.G. Gang ◽  
Eunjin Jo ◽  
...  
Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 657
Author(s):  
Geul Han Kim ◽  
Yoo Sei Park ◽  
Juchan Yang ◽  
Myeong Je Jang ◽  
Jaehoon Jeong ◽  
...  

Developing high performance, highly stable, and low-cost electrodes for the oxygen evolution reaction (OER) is challenging in water electrolysis technology. However, Ir- and Ru-based OER catalysts with high OER efficiency are difficult to commercialize as precious metal-based catalysts. Therefore, the study of OER catalysts, which are replaced by non-precious metals and have high activity and stability, are necessary. In this study, a copper–cobalt oxide nanosheet (CCO) electrode was synthesized by the electrodeposition of copper–cobalt hydroxide (CCOH) on Ni foam followed by annealing. The CCOH was annealed at various temperatures, and the structure changed to that of CCO at temperatures above 250 °C. In addition, it was observed that the nanosheets agglomerated when annealed at 300 °C. The CCO electrode annealed at 250 °C had a high surface area and efficient electron conduction pathways as a result of the direct growth on the Ni foam. Thus, the prepared CCO electrode exhibited enhanced OER activity (1.6 V at 261 mA/cm2) compared to those of CCOH (1.6 V at 144 mA/cm2), Co3O4 (1.6 V at 39 mA/cm2), and commercial IrO2 (1.6 V at 14 mA/cm2) electrodes. The optimized catalyst also showed high activity and stability under high pH conditions, demonstrating its potential as a low cost, highly efficient OER electrode material.


2019 ◽  
Vol 3 (7) ◽  
pp. 1713-1719 ◽  
Author(s):  
Dattatray S. Dhawale ◽  
Pradnya Bodhankar ◽  
Neharani Sonawane ◽  
Pradip B. Sarawade

Oxygen evolution reaction (OER) in water splitting is one of the most critical and more demanding half-reactions in electrochemical devices; therefore, the design of highly efficient and nonprecious metal-based electrocatalysts is required.


2017 ◽  
Vol 4 (10) ◽  
pp. 2480-2485 ◽  
Author(s):  
Jakob Kibsgaard ◽  
Thomas R. Hellstern ◽  
Shin-Jung Choi ◽  
Benjamin N. Reinecke ◽  
Thomas F. Jaramillo

2016 ◽  
Vol 128 (12) ◽  
pp. 1879-1885 ◽  
Author(s):  
HAN XIA ◽  
ZHEN PENG ◽  
CUNCAI L ◽  
YAOXING ZHAO ◽  
JINHUI HAO ◽  
...  

2016 ◽  
Vol 52 (80) ◽  
pp. 11947-11950 ◽  
Author(s):  
Bita Bayatsarmadi ◽  
Yao Zheng ◽  
Carlo Spartaco Casari ◽  
Valeria Russo ◽  
Shi-Zhang Qiao

A robust porous N-carbon supported cobalt (oxide) film has been developed by pulsed laser deposition as a highly efficient OER electrode.


2021 ◽  
Vol 127 (7) ◽  
Author(s):  
Ayse Kucukarslan ◽  
Esra Kus ◽  
Emrah Sarica ◽  
Idris Akyuz ◽  
Vildan Bilgin ◽  
...  

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