Effect of Si/Al ratio on catalytic performance of hydrothermally aged Cu-SSZ-13 for the NH3-SCR of NO in simulated diesel exhaust

2017 ◽  
Vol 419 ◽  
pp. 382-392 ◽  
Author(s):  
Shuai Han ◽  
Jin Cheng ◽  
Changkun Zheng ◽  
Qing Ye ◽  
Shuiyuan Cheng ◽  
...  
2019 ◽  
Vol 276 ◽  
pp. 133-146 ◽  
Author(s):  
Shuai Han ◽  
Jin Cheng ◽  
Qing Ye ◽  
Shuiyuan Cheng ◽  
Tianfang Kang ◽  
...  

Catalysts ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 55
Author(s):  
Katarzyna Świrk ◽  
Ye Wang ◽  
Changwei Hu ◽  
Li Li ◽  
Patrick Da Costa ◽  
...  

Copper and iron promoted ZrO2 catalysts were prepared by one-pot synthesis using urea. The studied catalysts were characterized by XRD, N2 physisorption, XPS, temperature-programmed desorption of NH3 (NH3-TPD), and tested by the selective catalytic reduction by ammonia (NH3-SCR) of NO in the absence and presence of water vapor, under the experimental conditions representative of exhaust gases from stationary sources. The influence of SO2 on catalytic performance was also investigated. Among the studied catalysts, the Fe-Zr sample showed the most promising results in NH3-SCR, being active and highly selective to N2. The addition of SO2 markedly improved NO and NH3 conversions during NH3-SCR in the presence of H2O. The improvement in acidic surface properties is believed to be the cause.


2018 ◽  
Vol 8 (24) ◽  
pp. 6360-6374 ◽  
Author(s):  
Thanh Huyen Vuong ◽  
Stephan Bartling ◽  
Ursula Bentrup ◽  
Henrik Lund ◽  
Jabor Rabeah ◽  
...  

Inserting adjacent Mn3+/Mn2+ and VO3+/VO2+ redox couples in Ce1−xTixO2 improves catalytic performance.


RSC Advances ◽  
2015 ◽  
Vol 5 (10) ◽  
pp. 7597-7603 ◽  
Author(s):  
Yuesong Shen ◽  
Yun Su ◽  
Yifan Ma

The maximum activity is dependent on the number of Lewis acid sites, and the active temperature window is dependent on the acid strength.


2018 ◽  
Vol 8 (12) ◽  
pp. 2430 ◽  
Author(s):  
Xinbo Zhu ◽  
Yaolin Wang ◽  
Yu Huang ◽  
Yuxiang Cai

In this work, a series of Ce-W-Ti catalysts were synthesized using a solution combustion method for the selective catalytic reduction (SCR) of NO with NH3 at low temperatures. The reaction performance of NH3-SCR of NO was significantly improved over the Ce-W-Ti catalysts compared to Ce0.4Ti and W0.4Ti catalysts, while Ce0.2W0.2Ti showed the best activity among all the samples. The Ce0.2W0.2Ti catalyst exhibited over 90% removal of NO and 100% N2 selectivity in the temperature range of 250–400 °C at a gas hourly space velocity (GHSV) of 120,000 mL·g−1·h−1. The Ce-W-Ti catalysts were characterized using N2 adsorption-desorption, X-ray diffraction, X-ray photoelectron spectrometry and temperature programmed desorption of NH3 to establish the structure-activity relationships of the Ce-W-Ti catalysts. The excellent catalytic performance of the Ce0.2W0.2Ti catalyst could be associated with the larger specific surface area, highly dispersed Ce and W species, increased amount of surface adsorbed oxygen (Oads) and enhanced total acidity on the catalyst surfaces.


2016 ◽  
Vol 34 (10) ◽  
pp. 1010-1016 ◽  
Author(s):  
Bing HAN ◽  
Yuesong SHEN ◽  
Shemin ZHU ◽  
Youlin LIU ◽  
Shubao SHEN

2017 ◽  
Vol 32 (12) ◽  
pp. 2438-2445 ◽  
Author(s):  
Qijie Jin ◽  
Yuesong Shen ◽  
Shemin Zhu ◽  
Huiyuan Li ◽  
Yanbao Li

Abstract


2017 ◽  
Vol 23 (54) ◽  
pp. 13404-13414 ◽  
Author(s):  
Nuria Martín ◽  
Peter N. R. Vennestrøm ◽  
Joakim R. Thøgersen ◽  
Manuel Moliner ◽  
Avelino Corma

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