Promotion effect of palladium on Co3O4 incorporated within mesoporous MCM-41 silica for CO Oxidation

2017 ◽  
Vol 402 ◽  
pp. 99-107 ◽  
Author(s):  
Hassan M.A. Hassan ◽  
Mohamed A. Betiha ◽  
Reda F.M. Elshaarawy ◽  
M. Samy El-Shall
Keyword(s):  
2005 ◽  
pp. 1441-1443 ◽  
Author(s):  
Ágnes Szegedi ◽  
Mihály Hegedűs ◽  
József L. Margitfalvi ◽  
Imre Kiricsi

2019 ◽  
Vol 127 (1) ◽  
pp. 425-436 ◽  
Author(s):  
Guihua Yang ◽  
Yuming Yu ◽  
Muhammad Usman Tahir ◽  
Shakiaz Ahmad ◽  
Xintai Su ◽  
...  
Keyword(s):  

2013 ◽  
Vol 139 (1) ◽  
pp. 125-133 ◽  
Author(s):  
O.A. González Vargas ◽  
J.A. de los Reyes Heredia ◽  
A. Montesinos Castellanos ◽  
L.F. Chen ◽  
J.A. Wang

Catalysts ◽  
2021 ◽  
Vol 12 (1) ◽  
pp. 4
Author(s):  
Tong Zhang ◽  
Wenge Qiu ◽  
Hongtai Zhu ◽  
Xinlei Ding ◽  
Rui Wu ◽  
...  

Developing a catalyst with high SO2 and H2O resistance to achieve high-performance CO oxidation for specific industrial applications is highly desirable. Here, three catalysts were prepared using cerium titanium composite oxide (CeTi), molybdophosphate with Keggin structure-modified CeTi (Keg-CeTi), and molybdophosphate without Keggin structure-modified CeTi (MoP-CeTi) as supports, and their sulfur and water resistance in CO oxidation were tested. The characterization of XRD, BET, SO2/H2O-DRIFTS, XPS, TEM, SEM, NH3/SO2-TPD, H2-TPR, and ICP techniques revealed that the high SO2 and H2O resistance of Pt/Keg-CeTi in CO oxidation was related to its stronger surface acidity, better reduction of surface cerium and molybdenum species, and lower SO2 adsorption and transformation compared to Pt/CeTi and Pt/MoP-CeTi.


Author(s):  
O. A. González Vargas ◽  
J. A. de Los Reyes Heredia ◽  
V. A. Suarez-Toriello ◽  
Sean M. Anderson ◽  
L. F. Chen ◽  
...  

2016 ◽  
Vol 120 (2) ◽  
pp. 791-807 ◽  
Author(s):  
Hassan M. A. Hassan ◽  
Shaimaa K. Mohamed ◽  
Amr Awad Ibrahim ◽  
Mohamed A. Betiha ◽  
E. A. El-Sharkawy ◽  
...  

2017 ◽  
Vol 89 (4) ◽  
pp. 471-479
Author(s):  
Károly Lázár

Abstract Relocation of iron ions in microporous Fe-FER, (Al+Fe)-FER, Fe-MFI (FER: ferrierite, MFI: silicalite) and in mesoporous Fe-MCM-41 ferrisilicate (MCM: Mobile Crystalline Material) samples was followed during redox treatments primarily by tool of the in situ Mössbauer spectroscopy. Coexistence of various Fe3+ and Fe2+ species is demonstrated. In microporous Fe-FER and Fe-MFI existence of combined μ-oxo iron dimers, Fe3+FW-O-Fe2+EFW can be proposed. The presence of these dimers can easily be correlated with catalytic effect shown in certain oxidation processes. Structural rearrangement can also be revealed in mesoporous Fe-MCM-41 which result in improvement of catalytic performance in CO oxidation.


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